Citation: ZHANG Ze-Kun, JING Xiao-Sheng, XU Hao, LI Zhao-Chen, YAN Wei. Advances in Design and Reaction Mechanism of Copper-based Catalysts for Electrocatalytic Carbon Dioxide Reduction[J]. Chinese Journal of Analytical Chemistry, ;2023, 51(3): 316-330. doi: 10.19756/j.issn.0253-3820.221456 shu

Advances in Design and Reaction Mechanism of Copper-based Catalysts for Electrocatalytic Carbon Dioxide Reduction

ZHANG Ze-Kun ¹ ,
JING Xiao-Sheng ¹ ,
XU Hao ^1,2,, ,
LI Zhao-Chen ³ ,
YAN Wei ^1,2

1.
Department of Environmental Science and Engineering, Xi'an Jiaotong University, Xi'an 710049, China;
2.
Research Institute of Xi'an Jiaotong University, Hangzhou 311200, China;
3.
China United Northwest Institute for Engineering Design & Research Co., Ltd., Xi'an 710077, China

Corresponding author: XU Hao, xuhao@xjtu.edu.cn
Received Date: 15 September 2022
Revised Date: 8 December 2022

Fund Project: Supported by the National Natural Science Foundation of China (No. 52270078), the Natural Science Basic Research Plan in Shaanxi Province of China (No. 2021JM-012), the Welfare Technology Research Plan of Zhejiang Province (No. LZY21E080003) and the Fundamental Research Funds for the Central Universities (No. xjh012020037).

Converting carbon dioxide (CO₂) to high-energy chemicals through electrocatalytic CO₂ reduction reaction (CO₂RR) is a powerful way to solve the greenhouse effect and realize the anthropogenic carbon cycle. Compared with other metal catalysts, copper (Cu)-based catalysts have attracted much attention due to the ability to generate multi-carbon products. However, it has poor selectivity for the products. Hence, efforts have been made in recent years to investigate the mechanism and influencing factors of C—C coupling in the reaction process of Cu-based catalysts, and to carry out targeted structural design and experimental synthesis of Cu-based catalysts. This paper first summarized the basic principles of electrocatalytic CO₂RR. Then, the five key factors (electrocatalytic reactor, pH, pressure, temperature, CO₂ flow rate and concentration) affecting electrocatalytic CO₂RR were summarized. Next, related strategies (alloying, nanostructure modification, heteroatom doping, hydrophilic/hydrophobic and Single atom catalysts) for modification of Cu-based catalysts were reviewed. Finally, the current opportunities and challenges for the preparation of Cu-based catalysts for electrocatalytic CO₂RR were prospected, in order to provide valuable insights and ideas for future research in related fields.
- Electrocatalytic carbon dioxide reduction,
- Copper-based catalysts,
- Carbon-carbon coupling,
- Electrocatalytic activity,
- Faraday efficiency
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沈阳化工大学材料科学与工程学院沈阳 110142