Citation: CHEN Yue-Yao, XIA Jing-Jing, WEI Yun, XU Wei-Xin, MAO Xin-Ran, CHEN Yue-Fei, MIN Shun-Geng, XIONG Yan-Mei. 近红外光谱法无损检测平谷产大桃品质方法研究[J]. Chinese Journal of Analytical Chemistry, ;2023, 51(3): 454-462. doi: 10.19756/j.issn.0253-3820.221405 shu

近红外光谱法无损检测平谷产大桃品质方法研究

College of Science, China Agricultural University, Beijing 100193, China

Corresponding author: MIN Shun-Geng, XIONG Yan-Mei,
Received Date: 6 August 2022
Revised Date: 13 January 2023

Fund Project: Supported by the National Natural Science Foundation of China (No. 21023048) and the Project of Research and Application of Intelligent Agricultural Inspection Service (No. 2021110041000003).

利用近红外(Near infrared,NIR)漫反射光谱法结合化学计量学定量分析技术开展了平谷产大桃品质的无损检测研究。使用手持式近红外光谱仪采集7个不同品种平谷产大桃的近红外漫反射光谱,采用系统抽样法将其划分为验证集和验证集,结合Savitzky-Golay卷积平滑法(Savitzky-Golay Smoothing,S-G)、标准正态变换法(Standard normal variation,SNV)和多元散射校正法(Multivariate scattering correction,MSC)3种预处理方法以及偏最小二乘回归(Partial least square regression,PLSR)与随机森林(Random forest,RF)两种建模算法,分别建立了大桃中的糖度(Soluble solids content,SSC)、酸度、硬度和水分定量模型。结果表明,非线性RF模型优于线性PLSR模型,对于SSC,一阶导数光谱结合MSC预处理建立的RF模型效果最佳,验证集决定系数(Coefficient of determination,R²)和预测均方根误差(Root mean squared error prediction,RMSEP)分别为0.79和0.77° Brix;对于硬度,一阶导数光谱结合MSC预处理建立的RF模型效果最佳,验证集R²和RMSEP分别为0.90和0.55 N;对于酸度,一阶导数光谱结合MSC预处理建立的RF模型效果最佳,验证集R²和RMSEP分别为0.71和0.18;对于水分,一阶导数光谱结合MSC预处理建立的RF模型效果最佳,验证集R²和RMSEP分别为0.80和0.64%。本研究采用近红外光谱结合化学计量学算法建立的方法可实现平谷大桃品质的快速无损检测。
- Near infrared spectroscopy,
- Peach,
- Nondestructive testing,
- Random forest,
- Quality testing
1. [1]
  HUANG L, MENG L, ZHU N, WU D. Postharvest Biol. Technol., 2017, 133:104-112.
2. [2]
  GONÇALVES R G, COUTO J, ALMEIDA D P F. Sci. Hortic., 2016, 209:293-299.
3. [3]
  MINAS I S, TANOU G, MOLASSIOTIS A. Sci. Hortic., 2018, 235:307-322.
4. [4]
  ANTHONY B M, CHAPARRO J M, PRENNI J E, MINAS I S. Plant Physiol. Biochem., 2020, 157:416-431.
5. [5]
  VIEGAS T R, MATA A L M L, DUARTE M M L, LIMA K M G. Food Chem., 2016, 190:1-4.
6. [6]
  NCAMA K, OPARA U L, TESFAY S Z, FAWOLE O A, MAGWAZA L S. J. Food Eng., 2017, 193:86-94.
7. [7]
  BOTH A J, BENJAMIN L, FRANKLIN J, HOLROYD G, INCOLL L D, LEFSRUD M G, PITKIN G. Plant Methods, 2015, 11(1):43-60.
8. [8]
  GRASSI S, ALAMPRESE C. Curr. Opin. Food Sci., 2018, 22:17-21.
9. [9]
  MINAS I S, BLANCO-CIPOLLONE F, STERLE D. Food Chem., 2021, 335:127626.
10. [10]
  UWADAIRA Y, SEKIYAMA Y, IKEHATA A. Heliyon, 2018, 4(2):e00531.
11. [11]
  WANG J, WANG J, CHEN Z, HAN D. Postharvest Biol. Technol., 2017, 129:143-151.
12. [12]
  YU X, LU H, WU D. Postharvest Biol. Technol., 2018, 141:39-49.
13. [13]
  CORTÉS V, ORTIZ C, ALEIXOS N, BLASCO J, CUBERO S, TALENS P. Postharvest Biol. Technol., 2016, 118:148-158.
14. [14]
  MOHD ALI M, HASHIM N, BEJO S K, SHAMSUDIN R. Sci. Hortic., 2017, 225:689-699.
15. [15]
  LI B, COBO-MEDINA M, LECOURT J, HARRISON N, HARRISON R J, CROSS J V. Postharvest Biol. Technol., 2018, 141:8-15.
16. [16]
  ESCRIBANO S, BIASI W V, LERUD R, SLAUGHTER D C, MITCHAM E J. Postharvest Biol. Technol., 2017, 128:112-120.
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
  LOUW E D, THERON K I. Postharvest Biol. Technol., 2010, 58(3):176-184.
22. [22]
  BREIMAN L. Machine Learn., 2001, 45(1):5-32.
23. [23]
  WEI K, WANG Q, TENG G, XU X, ZHAO Z, CHEN G. Appl. Sci., 2022, 12(10):4981.
24. [24]
  FENG T, ZHANG X, LI M, CHEN T, JIAO L, XU Y, TANG H, ZHANG T, LI H. Anal. Methods, 2021, 13(30):3424-3432.
25. [25]
  WENG S, QIU M, DONG R, WANG F, HUANG L, ZHANG D, ZHAO J. Spectrochim. Acta, Part A, 2018, 200:20-25.
26. [26]
  LI M, XU Y, MEN J, YAN C, LI H. Spectrochim. Acta, Part A, 2021, 251:119430.
27. [27]
  INOBEME A, NAYAK V, MATHEW T J, OKONKWO S, EKWOBA L, AJAI A I, BERNARD E, INOBEME J, MARIAM AGBUGUI M, SINGH K R. J. Environ. Manage., 2022, 309:114653.
1. [1]
  Mengyao Shi , Kangle Su , Qingming Lu , Bin Zhang , Xiaowen Xu . Determination of Potassium Content in Tobacco Stem Ash by Flame Atomic Absorption Spectroscopy. University Chemistry, 2024, 39(10): 255-260. doi: 10.12461/PKU.DXHX202404105
2. [2]
  Di Yang , Jiayi Wei , Hong Zhai , Xin Wang , Taiming Sun , Haole Song , Haiyan Wang . Rapid Detection of SARS-CoV-2 Using an Innovative “Magic Strip”. University Chemistry, 2024, 39(4): 373-381. doi: 10.3866/PKU.DXHX202312023
3. [3]
  Qilong Fang , Yiqi Li , Jiangyihui Sheng , Quan Yuan , Jie Tan . Magical Pesticide Residue Detection Test Strips: Aptamer-based Lateral Flow Test Strips for Organophosphorus Pesticide Detection. University Chemistry, 2024, 39(5): 80-89. doi: 10.3866/PKU.DXHX202310004
4. [4]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
5. [5]
  Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 877-884. doi: 10.11862/CJIC.20230440
6. [6]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
7. [7]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
8. [8]
  Min Gu , Huiwen Xiong , Liling Liu , Jilie Kong , Xueen Fang . Rapid Quantitative Detection of Procalcitonin by Microfluidics: An Instrumental Analytical Chemistry Experiment. University Chemistry, 2024, 39(4): 87-93. doi: 10.3866/PKU.DXHX202310120
9. [9]
  Tongyu Zheng , Teng Li , Xiaoyu Han , Yupei Chai , Kexin Zhao , Quan Liu , Xiaohui Ji . A DIY pH Detection Agent Using Persimmon Extract for Acid-Base Discoloration Popularization Experiment. University Chemistry, 2024, 39(5): 27-36. doi: 10.3866/PKU.DXHX202309107
10. [10]
  Qin Tu , Anju Tao , Tongtong Ma , Jinyi Wang . Innovative Experimental Teaching of Escherichia coli Detection Based on Paper Chip. University Chemistry, 2024, 39(6): 271-277. doi: 10.3866/PKU.DXHX202309062
11. [11]
  Jinghan ZHANG , Guanying CHEN . Progress in the application of rare-earth-doped upconversion nanoprobes in biological detection. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2335-2355. doi: 10.11862/CJIC.20240249
12. [12]
  Jiahui CHEN , Tingting ZHENG , Xiuyun ZHANG , Wei LÜ . Research progress of near-infrared absorption inorganic nanomaterials in photothermal and photodynamic therapy of tumors. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2396-2414. doi: 10.11862/CJIC.20240106
13. [13]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
14. [14]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
15. [15]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
16. [16]
  Qi Wang , Yicong Gao , Feng Lu , Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141
17. [17]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
18. [18]
  Qin Hou , Jiayi Hou , Aiju Shi , Xingliang Xu , Yuanhong Zhang , Yijing Li , Juying Hou , Yanfang Wang . Preparation of Cuprous Iodide Coordination Polymer and Fluorescent Detection of Nitrite: A Comprehensive Chemical Design Experiment. University Chemistry, 2024, 39(8): 221-229. doi: 10.3866/PKU.DXHX202312056
19. [19]
  Liwei Wang , Guangran Ma , Li Wang , Fugang Xu . A Comprehensive Analytical Chemistry Experiment: Colorimetric Detection of Vitamin C Using Nanozyme and Smartphone. University Chemistry, 2024, 39(8): 255-262. doi: 10.3866/PKU.DXHX202312094
20. [20]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096

Get Citation

PDF

XML

Metrics

PDF Downloads(21)
Abstract views(881)
HTML views(78)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142