金属有机凝胶的应用研究进展

引用本文: 吕福慧, 李琛琛, 李悦, 崔琳, 罗细亮. 金属有机凝胶的应用研究进展[J]. 分析化学, 2023, 51(2): 160-171. doi: 10.19756/j.issn.0253-3820.221312 shu

Citation: LYU Fu-Hui, LI Chen-Chen, LI Yue, CUI Lin, LUO Xi-Liang. Advance in Applications of Metal-organic Gel[J]. Chinese Journal of Analytical Chemistry, 2023, 51(2): 160-171. doi: 10.19756/j.issn.0253-3820.221312 shu

金属有机凝胶的应用研究进展

吕福慧 ^1, ,
李琛琛 ^{1,
,} ,
李悦 ^2,3, ,
崔琳 ^{2,
,} ,
罗细亮 ^{1,
,}

1.
青岛科技大学化学与分子工程学院, 青岛 266042;
2.
山东师范大学化学化工与材料科学学院, 济南 250014;
3.
东北大学理学院化学系, 沈阳 110819

通讯作者: 李琛琛,E-mail:lichenchen@qust.edu.cn; 崔琳,E-mail:zpbzcl@126.com; 罗细亮,E-mail:xiliangluo@qust.edu.cn

基金项目:
国家自然科学基金项目(Nos.21605096,21974080)、山东省泰山学者建设工程项目(No.20110829)和山东省自然科学基金项目(No.ZR2021QB151)资助。

摘要: 金属有机凝胶（Metal-organic gels，MOGs）是一类以金属离子和有机配体通过非共价作用桥联形成的凝胶材料。与制备耗时的金属有机框架（Metal-organic frameworks，MOFs）相比，MOGs可在温和条件下通过配位自组装、氢键作用、π-π堆积和范德华力形成多孔超分子结构，具有制备简单、比表面积大、热稳定性好、结构可调谐及金属位点丰富等优点，在传感和分析检测领域应用广泛，同时在催化、吸附、储能、电致变色器件等领域的应用也具有独特的优势。本文对近年来MOGs在上述领域中的研究和应用进展进行了评述，分析了其面临的挑战，并对其未来的发展趋势和应用前景进行了展望。

关键词:

金属有机凝胶
/ 传感
/ 催化
/ 应用
/ 评述

English

Advance in Applications of Metal-organic Gel

LYU Fu-Hui ^1, ,
LI Chen-Chen ^{1,
,} ,
LI Yue ^2,3, ,
CUI Lin ^{2,
,} ,
LUO Xi-Liang ^{1,
,}

1.
College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;
2.
College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, China;
3.
Department of Chemistry, College of Sciences, Northeastern University, Shenyang 110819, China

Corresponding author: LI Chen-Chen, ; CUI Lin, ; LUO Xi-Liang,

Received Date: 26 June 2022
Revised Date: 20 September 2022
Fund Project:
Supported by the National Natural Science Foundation of China (Nos. 21605096, 21974080), the Taishan Scholar Program of Shandong Province (No. ts20110829) and the Natural Science Foundation of Shandong Province, China (No. ZR2021QB151).

Abstract: Metal-organic gels (MOGs) are a kind of gel material formed by bridging metal ions and organic ligands via non covalent interactions. In comparison with metal-organic frameworks (MOFs) that require timeconsuming preparation, MOGs can be obtained by self-assembling through the coordination under mild conditions to form porous supramolecular structure via hydrogen bonding interactions, π-π stacking and van der Waals forces. MOGs possess good surface accessibility, high surface area, and multiple stimuli-responsive properties. Due to the easy preparation and large specific surface area, tunable structure, and abundant metal sites, MOGs are widely used in the fields of sensing and analysis, and also show unique advantages in the fields of catalysis, adsorption, energy storage and electrochromic devices. In this paper, the research and application progress of MOGs in the above fields in recent years is reviewed, and the challenges, future trends and application prospects are discussed.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

金属有机凝胶的应用研究进展

通讯作者: 李琛琛,E-mail:lichenchen@qust.edu.cn; 崔琳,E-mail:zpbzcl@126.com; 罗细亮,E-mail:xiliangluo@qust.edu.cn

English

Advance in Applications of Metal-organic Gel

Corresponding author: LI Chen-Chen, ; CUI Lin, ; LUO Xi-Liang,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

金属有机凝胶的应用研究进展

通讯作者: 李琛琛,E-mail:lichenchen@qust.edu.cn; 崔琳,E-mail:zpbzcl@126.com; 罗细亮,E-mail:xiliangluo@qust.edu.cn

English

Advance in Applications of Metal-organic Gel

Corresponding author: LI Chen-Chen, ; CUI Lin, ; LUO Xi-Liang,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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