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Citation: YU Weng-Ting,  LUO Ming-Biao. Characteristics and Mechanism Study of Arsenic Adsorption on Composite Material of Zr-based Metal Organic Framework and Fe2O3[J]. Chinese Journal of Analytical Chemistry, ;2023, 51(6): 1003-1012. doi: 10.19756/j.issn.0253-3820.221186 shu

Characteristics and Mechanism Study of Arsenic Adsorption on Composite Material of Zr-based Metal Organic Framework and Fe2O3

  • 1.

    School of Water Resources and Environment, China University of Geosciences(Beijing), Beijing 100083, China;

  • 2.

    School of Biology, Chemistry and Material Science, East China University of Technology, Nanchang 330013, China

  • Corresponding author: YU Weng-Ting, wtyu@cugb.edu.cn
  • Received Date: 8 April 2022
    Revised Date: 9 October 2022

    Fund Project: Supported by the National Natural Science Foundation of China (No. 21761001).

  • UiO-66(OH)@Fe2O3 synthesized by hydrothermal method was used for adsorption of As(Ⅲ) and As(V). results showed that the optimal pH value for As (Ⅲ) removal by UiO-66(OH)@Fe2O3 was pH=11, the equilibrium adsorption time was 180 min, and the maximum adsorption amount was 140.0 mg/g. At this time, the main form of As(Ⅲ) removal was H2AsO3-. Meanwhile, the optimal pH value for As(V) removal by UiO-66(OH)@Fe2O3 was pH=9, the equilibrium adsorption time was 90 min, and the maximum adsorption amount was 260.0 mg/g. At this pH value, the main form of As(V) removal was HAsO42-. The adsorption kinetics, thermodynamic, co-existing ions and repeatability of UiO-66(OH)@Fe2O3 were also investigated. It was shown that the adsorption fitted well with pseudo second-order kinetic model and Langmuir isotherm, and the ΔG° was less than zero under different temperatures, indicating that the entire adsorption process belongs to spontaneous monolayer chemical adsorption. Except PO43-, other co-existing ions had little effects on adsorption. The adsorbed material was eluted with 0.25 mol/L Na2SO4. Through five times of adsorption and desorption experiments, it was shown that the removal rate of As(Ⅲ) and As(V) were more than 60% and 80%, respectively. The characterization results of X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS) showed that the adsorption of arsenic by this adsorbent was mainly a chemical process, including the formation of Zr—O—As and the co-precipitation of ferric hydroxide produced by Fe2O3 hydrolysis. The prepared UiO-66(OH)@Fe2O3 had good adsorption activity for removing arsenic in different forms, and provided a theoretical reference for the development of composite materials with zirconium-based frame materials as the basic materials.
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