Citation: CHEN Xiang-Yu, CAI Zhao-Qing, PAN Yu-Bai, WANG Zheng. Solution Cathode Glow Discharge Atomic Emission Spectrometry in Hydrogen-Helium Atmosphere for On-line Determination of Chromium in Sewage[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(8): 1252-1259. doi: 10.19756/j.issn.0253-3820.221145 shu

Solution Cathode Glow Discharge Atomic Emission Spectrometry in Hydrogen-Helium Atmosphere for On-line Determination of Chromium in Sewage

1.
College of Mathematics and Physics, Shanghai Normal University, Shanghai 200234, China;
2.
Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China

Corresponding author: WANG Zheng, wangzheng@mail.sic.ac.cn
Received Date: 23 March 2022
Revised Date: 27 April 2022

Fund Project: Supported by the National Natural Science Foundation of China (No.E27GJ616), the Instrument Development Project of the Chinese Academy of Sciences (No.YZ201539) and the Shanghai Technical Platform for Testing and Characterization on Inorganic Materials (No.19DZ2290700).

Solution cathode glow discharge atomic emission spectrometry (SCGD-AES) has many advantages such as low power consumption, small size and simple operation. It is an ideal choice for on-line analysis of field samples. However, the low power consumption leads torelatively limited excitation capacity, which limits the detection performance of high excitation potential elements, such as chromium. In this study, a method for determination of chromium (Cr) content in sewage by solution cathode glow discharge atomic emission spectrometry operated in hydrogen-helium mixed atmosphere was established. It was found that the excitation conditions of SCGD-AES could be improved in hydrogen-helium mixed atmosphere (H₂ content of 3%). The experimental parameters such as gas flow rate, electrolyte type and flow rate, discharge voltage and spacing were optimized. The results showed that the limit of detection (LOD) of Cr was improved from 650 μg/L (discharging in air) to 106 μg/L with great repeatability (RSD=1.3%, 10 mg/L, n=11). The determination results of Cr in brown rice flour reference material (GBW(E)100619) and actual industrial sewage by this method were consistent with those obtained by inductively coupled plasma-optical emission spectroscopy (ICP-OES)and the recoveries were 92.4%-104.0%, indicating that this method had superb application prospect in determination of Cr in water samples.
- Solution cathode glow discharge,
- Atomic emission spectroscopy,
- Hydrogen-helium discharge atmosphere,
- Sewage,
- Chromium
1. [1]
2. [2]
3. [3]
  RATHI B S, KUMAR P S, VO D V N. Sci. Total Environ., 2021, 797:149134.
4. [4]
  BERRYMAN E J, PAKTUNC D. J. Hazard. Mater., 2022, 422:126873.
5. [5]
  NOVAK M, MARTINKOVA E, CHRASTNY V, STEPANOVA M, SEBEK O, ANDRONIKOV A, CURIK J, VESELOVSKY F, PRECHOVA E, HOUSKOVA M, BUZEK F, FARKAS J, KOMAREK A. Catena, 2017, 158:371-380.
6. [6]
  DAS P K, DAS B P, DASH P. Environ. Chem. Lett., 2021, 19(2):1369-1381.
7. [7]
  DAYAN A D, PAINE A J. Hum. Exp. Toxicol, 2001, 20(9):439-451.
8. [8]
  SUN H, BROCATO J, COSTA M. Curr. Environ. Health Rep., 2015, 2(3):295-303.
9. [9]
  BUTERS J, BIEDERMANN T. J. Invest. Dermatol., 2017, 137(2):274-277.
10. [10]
  GARCIA M, AGUIRRE M A, CANALS A. J. Anal. At. Spectrom., 2020, 35(2):265-272.
11. [11]
  MASONE J, BRENNAN R, RUSSELL G, HETTIPATHIRANA T. Spectroscopy, 2020, 35(9):48-49.
12. [12]
  ZHU Q Y, ZHAO L Y, SHENG D, CHEN Y J, HU X, LIAN H Z, MAO L, CUI X B. Talanta, 2019, 195:173-180.
13. [13]
14. [14]
  LIU Y C, ZOU J, LUO B, YU H R, ZHAO Z G, XIA H. Microchem. J., 2021, 169:106547.
15. [15]
  JIANG X M, CHEN Y, ZHENG C B, HOU X D. Anal. Chem., 2014, 86(11):5220-5224.
16. [16]
  MENG F Y, YUAN X, LI X M, LIU Y, DUAN Y X. Appl. Spectrosc. Rev., 2014, 49(7):533-549.
17. [17]
18. [18]
19. [19]
  WILLIAMS C B, AMAIS R S, FONTOURA B M, JONES B T, NOBREGA J A, DONATI G L. TrAC, Trends Anal. Chem., 2019, 116:151-157.
20. [20]
  YANG C, HE D, ZHU Z L, PENG H, LIU Z F, WEN G J, BAI J H, ZHENG H T, HU S H, WANG Y X. Anal. Chem., 2017, 89(6):3694-3701.
21. [21]
  NIU G H, KNODEL A, BURHENN S, BRANDT S, FRANZKE J. Anal. Chim. Acta, 2021, 1147:211-239.
22. [22]
  WEBB M R, ANDRADE F J, HIEFTJE G M. Anal. Chem., 2007, 79(20):7899-7905.
23. [23]
  WEBB M R, ANDRADE F J, HIEFTJE G M. Anal. Chem., 2007, 79(20):7807-7812.
24. [24]
  GREDA K, JAMROZ P, POHL P. J. Anal. At. Spectrom., 2013, 28(8):1233-1241.
25. [25]
  YU J, YANG S X, SUN D X, LU Q F, ZHENG J D, ZHANG X M, WANG X. Microchem. J., 2016, 128:325-330.
26. [26]
  ZU W C, WANG Y, YANG X T, LIU C. Talanta, 2017, 173:88-93.
27. [27]
  ZHENG P C, LUO Y J, WANG J M, HU Q, YANG Y, MAO X F, LAI C H. J. Anal. At. Spectrom., 2021, 36(6):1228-1234.
28. [28]
  ZHAO M Y, PENG X X, YANG B C, WANG Z. J. Anal. At. Spectrom., 2020, 35(6):1148-1155.
29. [29]
30. [30]
  CHENG J Q, LI Q, ZHAO M Y, WANG Z. Anal. Chim. Acta, 2019, 1077:107-115.
31. [31]
  GREDA K, JAMROZ P, DZIMITROWICZ A, POHL P. J. Anal. At. Spectrom., 2015, 30(1):154-161.
32. [32]
  GREDA K, POHL P. Food Chem., 2022, 371:131178.
33. [33]
  PENG X X, GUO X H, GE F, WANG Z. J. Anal. At. Spectrom., 2019, 34(2):394-400.
34. [34]
  WANG Z, SCHWARTZ A J, RAY S J, HIEFTJE G M. J. Anal. At. Spectrom., 2013, 28(2):234-240.
35. [35]
  WANG Z, GAI R Y, ZHOU L, ZHANG Z. J. Anal. At. Spectrom., 2014, 29(11):2042-2049.
36. [36]
  GREDA K, SWIDERSKI K, JAMROZ P, POHL P. Microchem. J., 2017, 130:7-13.
37. [37]
  MEZEI P, CSERFALVI T, KIM H J, MOTTALEB M A. Analyst, 2001, 126(5):712-714.
38. [38]
  MANJUSHA R, REDDY M A, SHEKHAR R, JAIKUMAR S. J. Anal. At. Spectrom., 2013, 28(12):1932-1939.
39. [39]
  GREDA K, JAMROZ P, POHL P. Talanta, 2013, 108:74-82.
40. [40]
  GREDA K, JAMROZ P, POHL P. J. Anal. At. Spectrom., 2013, 28(8):1233-1241.
41. [41]
  GORSKA M, POHL P. Talanta, 2021, 226:12155.
42. [42]
  YANG C, CHENG G, CHENG S Q, LIU X, LIU Y, ZHENG H T, HU S H, ZHU Z L. Anal. Chem., 2021, 93(49):16393-16400.
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沈阳化工大学材料科学与工程学院沈阳 110142