Citation: ZHANG Yu-Zhuo, LIU Xin, CHEN Hong-Jun, WU Wen-Jie. Preparation of Ion Imprinting Material Based on Epoxy Resin for Adsorption of Lead Ion[J]. Chinese Journal of Analytical Chemistry, ;2023, 51(3): 412-420. doi: 10.19756/j.issn.0253-3820.221072 shu

Preparation of Ion Imprinting Material Based on Epoxy Resin for Adsorption of Lead Ion

1.
Hunan Provincial Key Laboratory of Fine Ceramics and Powder Materials, School of Materials and Environmental Engineering, Hunan University of Humanities, Science and Technology, Loudi 417000, China;
2.
College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China

Corresponding author: LIU Xin, hstliux@163.com
Received Date: 14 February 2022
Revised Date: 28 December 2022

Fund Project: Supported by the Hunan Provincial Undergraduate Innovation and Entrepreneurship Training Program (No. S202010553046) and the Hunan Provincial ″Double-class″ Discipline Construction Program (No. Xiang Jiao Tong [2018] 469).

The existence of low concentration of lead ion (Pb²⁺) in nature water has great harm to the environment and human body, so it is of great significance to remove Pb²⁺ from the environment. In this work, an porous ion imprinting adsorbent (IIP) based on epoxy resin was prepared by curing and polymerization of epoxy resin with Pb²⁺ as template ion, PEG-600 as porogen, and 1,6-hexanediamine as curing agent. The effects of pH value, initial Pb²⁺ concentration, adsorption temperature and adsorption time on adsorption of Pb²⁺ on IIPs were studied by static adsorption method. The IIP before and after adsorption was characterized by X-ray photoelectron spectroscopy (XPS), Fourier transform-infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). The results showed that when pH=4.5 and T=293 K, the adsorption capacity of Pb²⁺ reached 149.01 mg/g, the adsorption kinetics followed the quasi second-order kinetic model, and the isothermal curve conformed to the Langmuir adsorption model. It was found that the IIP had good adsorption capacity and reusability. The selectivity investigation showed that the adsorption of Pb²⁺ upon IIP was significantly greater than that of competitive ions. The prepared IIP material had certain advantages in the treatment of wastewater containing low concentration of Pb²⁺ and had a good application prospect.
- Imprinted polymer,
- Adsorption,
- Lead ion,
- Selectivity,
- Epoxy resin
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沈阳化工大学材料科学与工程学院沈阳 110142