Citation: HAN Yu-Jie, DAI Zhi-Peng, ZHENG Xiao-Fang, GUO Yu-Jing. Institute of Environmental Science, Shanxi University, Taiyuan 030006, China[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(2): 206-216. doi: 10.19756/j.issn.0253-3820.210610 shu

Institute of Environmental Science, Shanxi University, Taiyuan 030006, China

Institute of Environmental Science, Shanxi University, Taiyuan 030006, China

Corresponding author: GUO Yu-Jing, guoyj@sxu.edu.cn
Received Date: 6 July 2021
Revised Date: 24 September 2021

Fund Project: Supported by the National Natural Science Foundation of China (No.21775095)

A core-shell structured polydopamine (PDA) functionalized LaCo_0.21Ni_1.59O₃ composite (PDA@LaCo_0.21Ni_1.59O₃) was synthesized, which combined the excellent electrocatalytic properties of LaCo_0.₂₁Ni_1.59O₃ and the abundant amino functional groups of PDA. On the basis of this, a novel electrochemical sensing platform for detection of heavy metal ions was constructed by modifying the composite on the glassy carbon electrode (PDA@LaCo_0.21Ni_1.59O₃/GCE). Under optimized conditions, the sensing platform showed wide linear range and low detection limit for Cu²⁺, Hg²⁺ and Pb²⁺ ions (The linear ranges were 0.05－10.0, 0.005－5.0 and 0.5－2.0 μmol/L, and the detection limits were 67.70, 8.68 and 52.0 nmol/L for Cu²⁺, Hg²⁺ and Pb²⁺ ions, respectively). The constructed sensing platform could be used for simultaneous detection of Cu²⁺, Hg²⁺ and Pb²⁺. This method provided a new strategy for the detection of heavy metals in water environment.
- Polydopamine,
- Pervoskite,
- Copper(Ⅱ) ion,
- Mecury(Ⅱ) ion,
- Lead(Ⅱ) ion,
- Electrochemical detection
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