Citation: DAI Jian-Xiong, YANG Yan-Ting, YU Hao, DUAN Yi-Xiang. A Novel Plasma Jet Atomic Emission Spectrometer and Its Application in Rapid Detection of Elements in Rice[J]. Chinese Journal of Analytical Chemistry, ;2021, 49(10): 1686-1693. doi: 10.19756/j.issn.0253-3820.210490 shu

A Novel Plasma Jet Atomic Emission Spectrometer and Its Application in Rapid Detection of Elements in Rice

1.
College of Chemistry and Materials Science, Northwest University, Xi'an 710127, China;
2.
Chengdu West Miracle Instruments Co., Ltd. Chengdu 611930, China;
3.
Aliben Science & Technology Co., Ltd, Chengdu 610042, China;
4.
School of Mechanical Engineering, Sichuan University, Chengdu 610064, China

Corresponding author: DUAN Yi-Xiang, yduan@scu.edu.cn
Received Date: 8 May 2021
Revised Date: 28 June 2021

Fund Project: Supported by the Special Project of Major Scientific Instruments and Equipment in Sichuan Province, China (No.2019ZDZX0036) and the Key Research and Development Program of Shaanxi Province, China (No.2019ZDLSF01-03).

A novel direct analysis technology for solid samples using an atomic emission spectrometer based on microwave plasma called plasma jet atomic emission spectrometer (PJ-AES) was developed for the first time. In the work, PJ-AES was used for the rapid detection of cadmium (Cd), zinc (Zn), copper (Cu), iron (Fe), phosphorus (P), silicon (Si) and other inorganic elements in rice. The linear range, sensitivity, stability and other properties of the PJ-AES were systematically investigated. As a result, the linear range of heavy metal element Cd (228.80 nm) was 0.03-1.72 mg/kg, and the linear correlation coefficient (R²) was 0.998, the detection limit was 0.009 mg/kg. A total of 8 groups of rice standard samples with a Cd concentration of 0.22 mg/kg were detected, and the relative standard deviation (RSD) of the signal intensity at 228.80 nm (Cd) was 2.8%. Finally, the method was used for quantitative detection of Cd in real samples and the obtained results were compared with that of inductively coupled plasma mass spectrometry (ICP-MS). The results showed that the PJ-AES was suitable for rapid, accurate, qualitative and quantitative detection of Cd in rice. The development of this technology provided a new direct analysis and detection method for solid samples for atomic spectroscopy. This method showed many advantages such as fast analysis speed, simple sample processing, small size, low cost, and accurate detection.
- Microwave plasma,
- Atomic emission spectroscopy,
- Direct detection of solid samples,
- Fast inspection of grain
1. [1]
  KELSON J R, SHAMBERGER R. J. Clin. Chem., 2019, 24(2):240-244.
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
  OZBEK N, TINAS H, ATESPARE A E. Microchem. J., 2019, 144(1):474-478.
7. [7]
  SCHILD M, GUNDLACH-GRAHAM A, MENON A, JEVTIC J, PIKELJA V, TANNER M, HATTENDORF B, GVNTHER D. Anal. Chem., 2018, 90(22):13443-13450.
8. [8]
  HUANG M, HIRABAYASHI A, SHIRASAKI T, KOIZUMI H. Anal. Chem., 2000, 72(11):2463-2467.
9. [9]
  HANNA S N, JONES B T. Appl. Spectrosc. Rev., 2011, 46(8):624-635.
10. [10]
  RAJAPAKSA A, QI A, YEO L Y, COPPEL R, FRIEND J R. Lab. Chip, 2014, 14(11):1858-1865.
11. [11]
  DIAS L F, MIRANDA G R, SAINT'PIERRE T D, MAIA S M, FRESCURA V L A, CURTIUS A J. Spectrochim. Acta, Part B, 2005, 60(1):117-124.
12. [12]
13. [13]
  STANKOVA A, GILON N, DUTRUCH L, KANICKY V J. Anal. Atom. Spectrom., 2011, 26(2):443-449.
14. [14]
15. [15]
  ESKINA V, FILATOVA, D G, BARANOVSKAYA V B, KARPOV Y A. J. Anal. Chem., 2020, 75(5):563-568.
16. [16]
  WU Y, JIANG Z, HU B, DUAN J. Talanta, 2004, 63(3):585-592.
17. [17]
18. [18]
19. [19]
  NIU G, SHI Q, XU M, LAI H, LIN Q, LIU K, DUAN Y. Appl. Spectrosc., 2015, 69(10):1190-1198.
20. [20]
  SHENG L, ZHANG T, NIU G, KANG W, TANG H, DUAN Y, HUA L. J. Anal. Atom.Spectrom., 2015, 30(2):453-458.
21. [21]
22. [22]
  ZHAN X, ZHAO Z, YUAN X, WANG Q, LI D,XIE H, LI X, ZHOU M, DUAN Y. Anal. Chem., 2013, 85(9):4512-4519.
23. [23]
  SHOW A A, YO M, NOMANBHAY S P L. Environ. Res., 2021, 197(15):111204.
24. [24]
25. [25]
  LI J, WANG J, LEI B, ZHANG T, TANG J, WANG Y, ZHAO W, DUAN Y. Adv.Sci., 2020, 7(6):1902616.
26. [26]
  LI J, LEI B, WANG J, XU B, RAN S, WANG Y, ZHANG T, TANG J, ZHAO W, DUAN Y. Commun. Phys., 2021, 4(1):64.
27. [27]
  ARNE B. Atom. Spectrosc., 2008, 63(9):917-928.
28. [28]
  KRZYSZTOF SWIDERSKI A D, PIOTR J, PAWEL P. J. Anal. Atom. Spectrom., 2018, 33(3):437-451.
29. [29]
30. [30]
1. [1]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
2. [2]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
3. [3]
  Tieping CAO , Yuejun LI , Dawei SUN . Surface plasmon resonance effect enhanced photocatalytic CO₂ reduction performance of S-scheme Bi₂S₃/TiO₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 903-912. doi: 10.11862/CJIC.20240366
4. [4]
  Mengyao Shi , Kangle Su , Qingming Lu , Bin Zhang , Xiaowen Xu . Determination of Potassium Content in Tobacco Stem Ash by Flame Atomic Absorption Spectroscopy. University Chemistry, 2024, 39(10): 255-260. doi: 10.12461/PKU.DXHX202404105
5. [5]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
6. [6]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn₂S₄ photocatalyst for H₂O₂ production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-0. doi: 10.1016/j.actphy.2025.100064
7. [7]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
8. [8]
  Li'na ZHONG , Jingling CHEN , Qinghua ZHAO . Synthesis of multi-responsive carbon quantum dots from green carbon sources for detection of iron ions and L-ascorbic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 709-718. doi: 10.11862/CJIC.20240280
9. [9]
  Jia-He Li , Yu-Ze Liu , Jia-Hui Ma , Qing-Xiao Tong , Jian-Ji Zhong , Jing-Xin Jian . 洛芬碱衍生物的合成、化学发光与重金属离子检测. University Chemistry, 2025, 40(6): 230-237. doi: 10.12461/PKU.DXHX202407080
10. [10]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-0. doi: 10.1016/j.actphy.2025.100054
11. [11]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
12. [12]
  Pingping LU , Shuguang ZHANG , Peipei ZHANG , Aiyun NI . Preparation of zinc sulfate open frameworks based probe materials and detection of Pb²⁺ and Fe³⁺ ions. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 959-968. doi: 10.11862/CJIC.20240411
13. [13]
  Zufeng Qiu , Jie Ouyang , Yiru Wang , Hengting Yang , Xin Liao , Chi Zhang , Xuanyao Jiang , Shunliu Deng , Zhiwei Lin . 综合运用分析仪器解析“盲盒”样品——未知物的剖析. University Chemistry, 2025, 40(6): 296-302. doi: 10.12461/PKU.DXHX202405167
14. [14]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
15. [15]
  Zijuan LI , Xuan LÜ , Jiaojiao CHEN , Haiyang ZHAO , Shuo SUN , Zhiwu ZHANG , Jianlong ZHANG , Yanling MA , Jie LI , Zixian FENG , Jiahui LIU . Synthesis of visual fluorescence emission CdSe nanocrystals based on ligand regulation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 308-320. doi: 10.11862/CJIC.20240138
16. [16]
  Yuena Yu , Fang Fang . Microwave-Assisted Synthesis of Safinamide Methanesulfonate. University Chemistry, 2024, 39(11): 210-216. doi: 10.3866/PKU.DXHX202401076
17. [17]
  Zhenhua Wang , Haoyang Feng , Xiaoyang Shao , Wenru Fan . Vitamins in Solid Propellants: Controlled Synthesis of Neutral Macromolecular Bonding Agents. University Chemistry, 2025, 40(4): 1-9. doi: 10.3866/PKU.DXHX202401007
18. [18]
  Changsheng An , Tao Liu . Decoding SEI chemistry at the lithium-metal potential. Acta Physico-Chimica Sinica, 2025, 41(9): 100101-. doi: 10.1016/j.actphy.2025.100101
19. [19]
  Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314
20. [20]
  Feng Han , Fuxian Wan , Ying Li , Congcong Zhang , Yuanhong Zhang , Chengxia Miao . Comprehensive Organic Chemistry Experiment: Phosphotungstic Acid-Catalyzed Direct Conversion of Triphenylmethanol for the Synthesis of Oxime Ethers. University Chemistry, 2025, 40(3): 342-348. doi: 10.12461/PKU.DXHX202405181

Get Citation

PDF

XML

Metrics

PDF Downloads(18)
Abstract views(734)
HTML views(77)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142