Citation: MING Run-Mian, ZHANG Cai-Ling, XIE Liang-Bo, SHANG Deng-Hui, LI Yi. Colorimetric Detection of Co²⁺ Based on Ligand Effect Enhancement for Homogeneous Activation of Peroxymonosulfate[J]. Chinese Journal of Analytical Chemistry, ;2021, 49(9): 1515-1522. doi: 10.19756/j.issn.0253-3820.210480 shu

Colorimetric Detection of Co²⁺ Based on Ligand Effect Enhancement for Homogeneous Activation of Peroxymonosulfate

School of Science, Tianjin University, Tianjin 300072, China

Corresponding author: LI Yi, liyi@tju.edu.cn
Received Date: 5 May 2021
Revised Date: 28 May 2021

Fund Project: Supported by the National Natural Science Foundation of China (No.21874099) and the Natural Science Foundation of Tianjin City of China (No.20YFZCSN01070).

Cobalt ion (Co²⁺) plays an important role in human body. But high concentration of Co²⁺ can cause a series of diseases. Peroxymonosulfate (PMS) is an oxidant with an asymmetric structure, and a certain concentration of Co²⁺ can catalyze the activation of PMS to produce active free radicals. Studies have shown that there is ligand effect between Co²⁺ and Ac^-. The introduction of electron donor Ac^- into Co²⁺-PMS accelerates electron transfer, so the catalytic activity of Co²⁺ towards PMS is enhanced and more sulfate radical (SO₄^·-) and hydroxyl radical (·OH) are produced, which results in corresponding enhancement of the ability of 3,3',5,5'-tetramethylbenzidine (TMB) oxidation. Based on the homogeneous catalytic activity of Co²⁺ on PMS and the enhanced coordination effect of Ac^-, a novel, catalyst free, green and efficient colorimetric detection method for Co²⁺ was designed in this work. When the concentrations of NaAc, TMB and PMS were 1.0, 0.4 and 0.3 mmol/L, respectively, and the temperature was set at 25℃, the method was specific for the detection of Co²⁺ and had good anti-interference ability for 20 kinds of interfering ions. The concentration of Co²⁺ in the concentration range of 0.5-3.0 μmol/L showed a good linear relationship with the absorbance of the system at 652 nm (A_{652 nm}), and the detection limit (S/N=3) was calculated to be 29 nmol/L. Compared with other detection methods for Co²⁺, this method established a fast, efficient and green platform for Co²⁺ detection without synthetic materials, large instruments and complex operation procedures.
- Peroxymonosulfate,
- Cobalt ion,
- Colorimetric detection,
- Ligand effect
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Colorimetric Detection of Co2+ Based on Ligand Effect Enhancement for Homogeneous Activation of Peroxymonosulfate

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Colorimetric Detection of Co²⁺ Based on Ligand Effect Enhancement for Homogeneous Activation of Peroxymonosulfate