Citation: HAN Yan-Yan, GAO Xue-Qing, WANG Da-Wei, ZHUANG Xu-Ming, TIAN Chun-Yuan, FU Xiu-Li. Synthesis of Copper Nanoclusters and Its Application in Determination of Pyrophosphate[J]. Chinese Journal of Analytical Chemistry, ;2021, 49(8): 1300-1307. doi: 10.19756/j.issn.0253-3820.201742 shu

Synthesis of Copper Nanoclusters and Its Application in Determination of Pyrophosphate

1.
Yantai Vocational College, Yantai 264670, China;
2.
College of Chemistry and Chemical Engineering, Yantai University, Yantai 264005, China

Corresponding author: ZHUANG Xu-Ming, xmzhuang@iccas.ac.cn
Received Date: 7 December 2020
Revised Date: 22 February 2021

Fund Project: Supported by the National Natural Science Foundation of China (Nos.21778047, 21705139).

By using 3-mercaptopropionic acid (MPA) as a reductant and protective agent, fluorescent copper nanoclusters (MPA-CuNCs) were prepared by one-pot reaction method, and Cu²⁺@MPA-CuNCs was further synthesized based on that Cu²⁺ could induce aggregation-induced emission effect of MPA-CuNCs. The synthesized Cu²⁺@MPA-CuNCs nanocomposite was characterized by scanning electron microscopy, X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy, etc. The experimental results showed that Cu²⁺@MPA-CuNCs nanocomposite was successfully synthesized. Pyrophosphate can combine with Cu²⁺, which lead to the fluorescence quenching of Cu²⁺@MPA-CuNCs system. Based on this, a new fluorescent sensor was thus constructed for sensitive detection of pyrophosphate, with a good linear relationship in the concentration rang of 5-100 μmol/L. The limit of detection was 0.65 μmol/L (3σ). This method had high selectivity in detection of pyrophosphate.
- Copper nanoclusters,
- Nanocomposite,
- Pyrophosphate,
- Fluorescent sensor
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