Citation: CHEN Peng, LI Rong, CHEN Bin. Adsorption of Ferric Ion on Multidentate Ligand Functionalized Silica Gel[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(2): 300-309. doi: 10.19756/j.issn.0253-3820.201492 shu

Adsorption of Ferric Ion on Multidentate Ligand Functionalized Silica Gel

School of Chemical Engineering,Northwest University, Xi'an 710069, China

Corresponding author: LI Rong, CHEN Bin,
Received Date: 14 August 2020
Revised Date: 24 June 2021

Fund Project: Supported by the National Natural Science Foundation of China (No.21376191), the Natural Science Foundation of Shaanxi Province, China (No.2011JM2013), the Service Local Special Project of Shaanxi Province Education Department (No.14JF027) and the Industrialization Cultivation Item of Shaanxi Province Educational Department (No.2013jc23)

The self-made silica gels functionalized with various multidentate ligands were used as adsorbents to explore the effects of ligand dentate numbers on the adsorption of common heavy metal ions in wastewater. Silica gel modified with pentadentate ligand iminodisuccinic acid displayed the highest adsorption capacity of 14.4 mg/g for Fe³⁺. The adsorption kinetics and thermodynamics of this adsorbent were studied, and the influences of concentration of Fe³⁺, temperature, rotation speed and coexisting ions on the adsorption were investigated. The experiment results showed that the adsorbent had a relatively fast initial adsorption behavior for Fe³⁺, and the pseudo-second-order model could better describe the adsorption kinetics of the adsorbent. Freundlich isotherm model was more suitable for describing equilibrium data, and the adsorption process was exothermic and non-spontaneous. Increasing the concentration and temperature could improve the adsorption capacity of Fe³⁺ on IDS-Silica, while increasing speed could shorten time to reach adsorption equilibrium. Other interfering ions had no effects on adsorption of Fe³⁺ except for Cu²⁺. Furthermore, IDS-Silica had good repeatability for adsorption of Fe³⁺. This work provided a new and efficient adsorption material for removing Fe³⁺ in wastewater, and also provided a theoretical reference for developing chelating adsorption material modified with pentadentate ligand iminodisuccinic acid.
- Multidentate ligand,
- Ferric ion,
- Adsorption kinetics,
- Adsorption thermodynamics,
- Reusability,
- Iminodisuccinic acid
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