Citation: Jing SUN, Hai-Xiong LIU, Tian-Fu LIU. Synthesis, Crystal Structure and Characterization of a New Hydrogen-bonded Organic Framework[J]. Chinese Journal of Structural Chemistry, ;2021, 40(8): 1082-1087. doi: 10.14102/j.cnki.0254–5861.2011–3113 shu

Synthesis, Crystal Structure and Characterization of a New Hydrogen-bonded Organic Framework

a.
Jinshan College, Fujian Agriculture and Forestry University, Fuzhou 350002, China
b.
School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China
c.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Hai-Xiong LIU, cgliuhx@126.com Tian-Fu LIU, tfliu@fjirsm.ac.cn
Received Date: 22 January 2021
Accepted Date: 3 March 2021

Fund Project: Fujian Young and Middle-aged Teachers' Educational Research Project JT180842

Figures(5)

The hydrogen-bonded organic framework (PFC-32), constructed by tetrahydroxyquinone (THQN) and diethylamine (DEA), was readily prepared via hydrothermal synthesis in DEF (N, N-diethylformamide). PFC-32 was characterized by PXRD, IR, UV-Vis, TGA and photoluminescence (PL). Single crystal analysis reveals that PFC-32 shows a three-dimensional (3D) framework, where the THQN anions are coplanar and separated by DEA cations. PFC-32 displays intrinsic photoluminescence property owing to the alleviation of the aggregation-caused quenching (ACQ) effect caused by π-π stacking.
- tetrahydroyquinone,
- diethylamine,
- hydrogen-bonded organic framework
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