Citation: Ling-Bin ZHU, Fei LI, Ming-Ling SUN, Ye-Yan QIN, Yuan-Gen YAO. Three New Isostructural Metal-organic Coordination Polymers from Triangular Pyridinedicarboxylate Ligand: Syntheses, Structures and Properties[J]. Chinese Journal of Structural Chemistry, ;2021, 40(8): 1031-1038. doi: 10.14102/j.cnki.0254–5861.2011–3078 shu

Three New Isostructural Metal-organic Coordination Polymers from Triangular Pyridinedicarboxylate Ligand: Syntheses, Structures and Properties

Ling-Bin ZHU ^{a, b} ,
Fei LI ^b ,
Ming-Ling SUN ^b ,
Ye-Yan QIN ^b ,
Yuan-Gen YAO ^b,,

a.
College of Chemistry and Material Science, Fujian Normal University, Fuzhou 350007, China
b.
Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Fujian Institute of Research on the Structure of Matter, Fuzhou 350002, China

Corresponding author: Yuan-Gen YAO, yyg@fjirsm.ac.cn
Received Date: 25 December 2020
Accepted Date: 5 February 2021

Fund Project: the National Natural Science Foundation of China 21703247the Science Foundation of Fujian Province 2018J05029the Science Foundation of Fujian Province 2019J05156the Science Foundation of Fujian Province 2019H0053

Figures(6)

Three new isostructural coordination polymers, namely, [Mg(cpna)(H₂O)₂]_n (1), [Mn(cpna)(H₂O)₂]_n (2) and [Co(cpna)(H₂O)₂]_n (3) (H₂cpna = 5-(3-carboxylphenyl)nicotic acid) are reported. They were synthesized by hydrothermal reactions of transition metal or alkaline earth metal chloride with 5-(3-carboxylphenyl)nicotic acid, respectively. Complexes 1~3 exhibit 2D layers with a 3, 3-connected topology with Schläfli symbol {4.8²}. Such layers including hexagonal rings and a quadrangular ring are further extended into an ordered 3D framework by hydrogen bonds between the cpna^2- ligands and water molecules. The rare complex 1 has excellent luminescence and can be used as luminescent materials, while 2 and 3 possess prominent magnetism with potential applications in magnetic materials.
- isostructural polymer,
- 2D layers,
- 3D framework,
- hydrogen bonds,
- luminescence,
- magnetism
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