Citation: Xue-Min WU, Min-Min LIU, Hong-Xu GUO, Shao-Ming YING, Zhang-Xu CHEN. Polyoxovanadate-based MOFs Microsphere Constructed from 3-D Discrete Nano-sheets as Supercapacitor[J]. Chinese Journal of Structural Chemistry, ;2021, 40(8): 994-998. doi: 10.14102/j.cnki.0254–5861.2011–3053 shu

Polyoxovanadate-based MOFs Microsphere Constructed from 3-D Discrete Nano-sheets as Supercapacitor

a.
College of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou, Fujian 363000, China
b.
Fujian Provincial Key Laboratory of Featured Materials in Biochemical Industry, Ningde Normal University, Ningde, Fujian 352100, China
c.
Fujian Provincial Key Laboratory of Ecology-Toxicological Effects & Control for Emerging Contaminants, Putian University, Putian, Fujian 351100, China

Corresponding author: Hong-Xu GUO, guohx@mnnu.edu.cn
Received Date: 3 December 2020
Accepted Date: 7 April 2021

Fund Project: the Natural Science Foundation of Fujian Province 2020J01803Fujian Provincial Key Laboratory of Featured Materials in Biochemical Industry FJKL_FBCM202004the Fujian Provincial Key Laboratory of Ecotoxicological Effects and Control of New Pollutants PY19001

Figures(5)

A novel polyoxovanadate-based MOFs microsphere, [Ni(phen)V₂O₇]·H₂O (phen = 1, 10phenanthroline), constructed from 3-D discrete nano-sheets has been prepared and characterized by XRD, FT-IR, SEM and TEM. Electrochemical properties as supercapacitor of the as-prepared sample, such as CV, EIS, GCD and the cycle life test have also been studied. The as-prepared MOF (V, Ni) showed a high specific capacitance of 178.09 F⋅g^-1 at 1 A⋅g^-1 as well as good cycling stability and coulombic efficiency. This work proved that the novel MOFs based on polyoxovanadate hybrid material may serve as a promising electrode material for high-performance supercapacitor.
- MOFs microsphere,
- polyoxovanadate,
- discrete nano-sheets,
- supercapacitor
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沈阳化工大学材料科学与工程学院沈阳 110142