Citation: Su-Qin ZHAO, Jin-Zhong GU. Syntheses, Structures and Catalytic Properties of Two Mn(Ⅱ) and Cd(Ⅱ) Coordination Polymers through in Situ Ligand Reaction[J]. Chinese Journal of Structural Chemistry, ;2021, 40(6): 785-796. doi: 10.14102/j.cnki.0254–5861.2011–3052 shu

Syntheses, Structures and Catalytic Properties of Two Mn(Ⅱ) and Cd(Ⅱ) Coordination Polymers through in Situ Ligand Reaction

Su-Qin ZHAO ^a,, ,
Jin-Zhong GU ^b,,

a.
College of Physics and Electronic Information Engineering, Qinghai University for Nationalities, Xining 810007, China
b.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: Su-Qin ZHAO, qhzhsq@sina.com Jin-Zhong GU, gujzh@lzu.edu.cn
Received Date: 3 December 2020
Accepted Date: 8 February 2021

Fund Project: the Science and Technology Plan of Qinghai Province 2020-ZJ-705

Figures(15)

Two coordination polymers, namely [Mn(μ-Hcpia)(bipy)(H₂O)₂]_n (1) and [Cd₃(μ₃-Hcpia)₂(μ-Hbiim)₂(μ-H₂biim)(H₂O)₂]_n (2), have been constructed hydrothermally using H₂cbia (H₂cbia = 5-(4΄-cyanobenzoxy)isophthalic acid), bipy (bipy = 4, 4΄-bipyridine), H₂biim (H₂biim = 2, 2΄-biimidazole), and manganese or cadmium chlorides at 160 ℃. Interestingly, the H₃cpia (H₃cpia = 5-(4΄-carboxylphenoxy)isophthalic acid) ligand was generated by in situ hydrolysis of cyano group in H₂cbia. The products were isolated as stable crystalline solids and were characterized by IR spectra, elemental analyses, thermogravimetric analyses (TGA), and single-crystal X-ray diffraction analyses. Both compounds crystallize in the triclinic system, space group P\begin{document}$ \overline 1 $\end{document}. Compound 1 discloses a 1D linear chain of the 2C1 topological type. Adjacent chains are assembled into a 2D supramolecular sheet through O–H…O/N hydrogen bonds. Compound 2 features a 3D framework with a 3, 4, 4T25 topology. The luminescent and catalytic properties of two compounds were investigated. Compound 1 exhibits a superior catalytic activity in the cyanosilylation at room temperature.
- coordination polymer,
- tricarboxylic acid,
- luminescent properties,
- catalytic properties,
- in situ reaction
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