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Citation: Xiao-Yu ZHONG, En-Qiang WU, Sheng-Dong YANG, Hao-Hang WANG, Xiao-Xin LIN, Yao-Guo SHEN. Optical Properties and Thermal Stability of a Cubic Sulfate Rb2Ca2(SO4)3[J]. Chinese Journal of Structural Chemistry, ;2021, 40(7): 949-954. doi: 10.14102/j.cnki.0254–5861.2011–3047 shu

Optical Properties and Thermal Stability of a Cubic Sulfate Rb2Ca2(SO4)3

  • College of Physics & Electronic Information Engineering, Minjiang University, Fuzhou 350108, China

  • Corresponding author: Yao-Guo SHEN, shenyg@mju.edu.cn
    • Zhong Xiao-Yu and Wu En-Qiang contributed equally to this work
  • Received Date: 23 November 2020
    Accepted Date: 4 January 2021

    Fund Project: the Doctoral Fund MJY19014Natural Science Foundation of Fujian Province 2019J01762President's Fund 103952020020

Figures(6)

  • In this paper, a non-centrosymmetric compound of Rb2Ca2(SO4)3 has been synthesized by a high temperature solid-state reaction and high temperature melting method. Single-crystal X-ray diffraction analysis shows that Rb2Ca2(SO4)3 crystallizes in the cubic space group of P213, and its cell parameters are a = b = c = 10.5569(6) Å, Z = 4 and V = 1176.55(12) Å3, respectively. In the crystal structure, SO4 tetrahedra and CaO6 octahedra are connected with each other by a corner-sharing mode to construct the three-dimensional framework of Rb2Ca2(SO4)3. Optical measurements show that the title compound has a short ultraviolet absorption edge and a moderate second-harmonic generation response. The optical origin is illustrated by the electron band structure calculation. In addition, thermal stability is also studied by virtue of differential thermal/thermogravimetric analysis and powder XRD technique.
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