Citation: Xiao-Feng WANG, Xin-Yu GUO, Tao LIU. Two Co(Ⅲ)-based Coordination Polymers Constructed from π-electron-rich Polycarboxylate Aryl Ether Ligand: Structural Insights and Photocatalytic Dye Degradation[J]. Chinese Journal of Structural Chemistry, ;2021, 40(6): 722-728. doi: 10.14102/j.cnki.0254–5861.2011–3046 shu

Two Co(Ⅲ)-based Coordination Polymers Constructed from π-electron-rich Polycarboxylate Aryl Ether Ligand: Structural Insights and Photocatalytic Dye Degradation

a.
School of Hydraulic and Electric Power, Heilongjiang University, Harbin 150080, China
b.
College of Science, Northeast Agricultural University, Harbin 150038, China

Corresponding author: Tao LIU, daliu_1978@126.com
Received Date: 23 November 2020
Accepted Date: 12 December 2020

Figures(5)

In the present study, two new Co(Ⅲ)-based coordination polymers (CPs) with chemical formulas of {[Co₃(μ₃-OH)(L)(H₂O)₃]·2H₂O}_n (1) and {[Co₃(μ₃-OH)(L)(H₂O)]·2DMF·3H₂O}_n (2) have been successfully prepared by the reaction of Co(NO₃)₂·6H₂O with π-electron-rich polycarboxylate aryl ether ligand 5, 5΄-((5-carboxy-1, 3-phenylene)bis(oxy))diisophthalic acid (H₅L) under different solvothermal reaction conditions. Both CPs have been studied via single-crystal X-day diffraction, powder X-ray diffraction (PXRD) and thermogravimetric analysis (TGA). The photophysical studies indicated that complex 2 with good water stability is a potential semiconductive material, which could be applied for the degradation of methylene blue (MB) under UV light irradiation and exhibit good stability and recyclability.
- coordination polymer,
- structural diversity,
- aryl ether ligand,
- dye degradation
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