Citation: De-Xiang ZHANG, Yao LI, Lan-Xin PENG, Hai-Pu LI, Ying YANG. Synthesis and Characterization of Organoboryl Germanium(Ⅱ) Oxides Containing Ge–O–B and Ge–O–B–O–Ge Cores[J]. Chinese Journal of Structural Chemistry, ;2021, 40(6): 811-820. doi: 10.14102/j.cnki.0254–5861.2011–3042 shu

Synthesis and Characterization of Organoboryl Germanium(Ⅱ) Oxides Containing Ge–O–B and Ge–O–B–O–Ge Cores

De-Xiang ZHANG ^a ,
Yao LI ^a ,
Lan-Xin PENG ^a ,
Hai-Pu LI ^{a, b} ,
Ying YANG ^a,,

a.
School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
b.
Key Laboratory of Hunan Province for Water Environment and Agriculture Product Safety, Changsha 410083, China

Corresponding author: Ying YANG, yangy@csu.edu.cn
Received Date: 17 November 2020
Accepted Date: 13 January 2021

Fund Project: the National Natural Science Foundation of China 21771194

Figures(8)

Organoboryl germanium(Ⅱ) oxides were synthesized from the 1, 4-addition reaction of L′Ge (L′ = HC[C(CH₂)N(Ar)]C(Me)N(Ar), Ar = 2, 6-iPr₂C₆H₃) with selected monosubstituted arylboronic acids RB(OH)₂ (R = 2, 6-Me₂C₆H₃, 2, 4, 6-Me₃C₆H₂, 1-Naph) at the molar ratios of 1:1 and 2:1. The mononuclear products RB(OH)OGeL (L = CH[C(Me)N(Ar)]₂, Ar = 2, 6-iPr₂C₆H₃; R = 2, 6-Me₂C₆H₃ (1), 2, 4, 6-Me₃C₆H₂ (2), 1-Naph (3)) containing the Ge–O–B core were obtained smoothly through the 1:1 reaction. However, the reaction of L′Ge with 2, 6-Me₂C₆H₃B(OH)₂ in a 2:1 ratio gave only the mononuclear product (1) instead of the expected binuclear one. What's more, a new borate compound [(2, 6-Me₂C₆H₃)₄B₅O₆]^-[H: C]⁺ (4) (: C = C[N(iPr)C(Me)]₂) was concomitantly formed when the in situ prepared L′Ge was used as the precursor. In contrast, the use of 2, 4, 6-Me₃C₆H₂B(OH)₂ or 1-NaphB(OH)₂ as the organoboryl source in the similar reaction led to the formation and isolation of the binuclear products RB(OGeL)₂ (R = 2, 4, 6-Me₃C₆H₂ (5), 1-Naph (6)) containing the Ge–O–B–O–Ge core in a straight way. Compounds 1~6 were determined by single-crystal X-ray diffraction analysis.
- organic boronic acid,
- germylene,
- synthesis,
- crystal structure
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