Citation: Wen-Yu TIAN, Jin-Feng CHU. Four Complexes of Mn(Ⅱ), Co(Ⅱ), Ni(Ⅱ) and Cu(Ⅱ) Based on 2-Morpholine-4-yl-4, 6-di-pyrazol-1-yl-1, 3, 5-triazine[J]. Chinese Journal of Structural Chemistry, ;2021, 40(6): 729-738. doi: 10.14102/j.cnki.0254–5861.2011–3033 shu

Four Complexes of Mn(Ⅱ), Co(Ⅱ), Ni(Ⅱ) and Cu(Ⅱ) Based on 2-Morpholine-4-yl-4, 6-di-pyrazol-1-yl-1, 3, 5-triazine

Wen-Yu TIAN ,
Jin-Feng CHU ^,

State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: Jin-Feng CHU, chujf@mail.buct.edu.cn
Received Date: 9 November 2020
Accepted Date: 30 December 2020

Figures(11)

Three azide bridged complexes, namely, [Mn₂L₂(N₃)₄(H₂O)₂] (1), [Co₂L₂(N₃)₄]·(H₂O)₃ (2) and [Ni₂L₂(N₃)₃(H₂O)]N₃·(H₂O)₄ (3) (L = 2-morpholine-4-yl-4, 6-di-pyrazol-1-yl-1, 3, 5-triazine), were synthesized by the reaction of L ligand, sodium azide with Mn(Ⅱ), Co(Ⅱ) and Ni(Ⅱ) chlorides. The copper(Ⅱ) chloride combined with thiocyanate and L ligand to form a mononuclear complex [CuL(CH₃OH)(SCN)(NCS)] (4). Complexes 1~4 were characterized by IR, elemental analysis and X-ray crystallographic analysis. It was worth noting that two Mn(Ⅱ) atoms were connected by the end-to-end mode in 1, while Co(Ⅱ) and Ni(Ⅱ) atoms were connected by the end-on mode in 2 and 3. In complex 4, the central copper atom was coordinated with a sulfur atom and a nitrogen atom of the two thiocyanate ligands, respectively. Hydrogen bonds, π-π stacking interactions, thermogravimetric analysis and fluorescence properties of 1~4 were studied.
- azide bridged complexes,
- supramolecular,
- crystal structure,
- thiocyanate
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