Citation: Can HE, Tian-Pu SHENG, Feng-Rong DAI, Zhong-Ning CHEN. Sulfonylcalix[4]arene-based Coordination Supercontainers[J]. Chinese Journal of Structural Chemistry, ;2020, 39(12): 2077-2084. doi: 10.14102/j.cnki.0254–5861.2011–3029 shu

Sulfonylcalix[4]arene-based Coordination Supercontainers

a.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Feng-Rong DAI, dfr@fjirsm.ac.cn
Received Date: 3 November 2020
Accepted Date: 16 November 2020

Fund Project: the National Natural Science Foundation of China 21673239the National Natural Science Foundation of China 21501179

Figures(8)

Sulfonylcalix[4]arenes-based coordination containers, namely metal-organic supercontainers (MOSCs), are a new class of coordination containers constructed from the self-assembly of divalent metal ions, suitable carboxylate linkers, and sulfonylcalix[4]arenes container precursor. MOSCs feature both endo cavity surrounded by carboxylate linkers and exo cavities originated from the upper rim of sulfonylcalix[4]arenes. The molecular topologies and endo cavity of MOSCs are tuneable via judicious design of carboxylate linkers, while the modulation of endo cavity are accessible by chemical modification on the para substituent group of the sulfonylcalix[4]arenes. In this paper, recent advances and typical examples of design and functionalization of MOSCs are presented.
- coordination container,
- sulfonylcalix[4]arene,
- metal-organic supercontainer,
- self-assembly
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