Citation: Ning XIAO, Lei HAN, Yi-Hang WEN, Le-Jia WANG, Xun-Wen XIAO. Syntheses, Structures and Photocurrent Response Properties of Two Crystals Based on Tetrathiafulvalene Derivatives[J]. Chinese Journal of Structural Chemistry, ;2021, 40(6): 759-766. doi: 10.14102/j.cnki.0254–5861.2011–3011 shu

Syntheses, Structures and Photocurrent Response Properties of Two Crystals Based on Tetrathiafulvalene Derivatives

Ning XIAO ^{a, c} ,
Lei HAN ^a ,
Yi-Hang WEN ^b,, ,
Le-Jia WANG ^c ,
Xun-Wen XIAO ^c

a.
School of Material Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
b.
Zhejiang Key Laboratory for Reactive Chemistry On Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China
c.
School of Material and Chemical Engineering, Ningbo University of Technology, Ningbo 315211, China

Corresponding author: Yi-Hang WEN, wyh@zjnu.edu.cn
Received Date: 26 October 2020
Accepted Date: 8 December 2020

Fund Project: the Natural Science Foundation of Zhejiang Province LY18B020016Ningbo Science and Technology Innovation 2025 2018B10033

Figures(7)

In this paper, two compounds [Zn₂²⁺(2, 6-bis(4΄-pyridyl)-TTF)(TPA)₂^2-] (1) and [Cd²⁺(2, 6(7)-bis(4΄-pyridyl)-TTF)(TPA)^2-(H₂O)₂] (TTF = tetrathiafulvalene, TPA = terephthalic acid) (2) were synthesized by using solvothermal method and characterized by single-crystal X-ray. The purity of the two compounds was confirmed by their PXRD data. We also tested the photocurrent responses of these two compounds, and found they could generate photocurrent signal when exposed to light, but the photocurrent intensity of compound 2 is significantly greater than that of 1. From the crystal structure analysis, the possible reason for this phenomenon is that 2 has a more compact ligand arrangement than 1, leading to a higher carrier density and easier excitation.
- 2,6(7)-bis(4'-pyridyl)-tetrathiafulvalene,
- crystal structure,
- interpenetrating,
- photocurrent responses
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