Citation: Chen-Hui LIU, Wei-Hui FANG, Yao KANG, Jian ZHANG. Synthetic Strategies, Diverse Structures and Properties of Copper Halide Cluster-based Materials[J]. Chinese Journal of Structural Chemistry, ;2020, 39(12): 2091-2101. doi: 10.14102/j.cnki.0254–5861.2011–3010 shu

Synthetic Strategies, Diverse Structures and Properties of Copper Halide Cluster-based Materials

Chen-Hui LIU ^{a, b} ,
Wei-Hui FANG ^b,, ,
Yao KANG ^b ,
Jian ZHANG ^b

a.
College of Chemical Engineering, Fuzhou University, Fuzhou 350116, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Wei-Hui FANG, fwh@fjirsm.ac.cn
Received Date: 26 October 2020
Accepted Date: 17 November 2020

Fund Project: the National Natural Science Foundation of China 21771181the National Natural Science Foundation of China 21973096Youth Innovation Promotion Association CAS 2017345

Figures(11)

Copper halide clusters have become one of the most prosperous cluster-based materials. They are not only widely used in the fields of photophysics and photochemistry, but also adsorption, catalysis, biology, etc. Herein, the recent progress in copper halide based chemistry is reviewed from three aspects. In the first place, we summarize the new synthesis strategies promoting the crystallization of copper halide cluster-based materials. Then, the structural diversity of the compounds is introduced according to the dimension of copper halogen clusters. Finally, we discuss the functionality of copper halide cluster-based materials including optical, catalytic and adsorption properties. In addition, perspectives on their potential applications are presented.
- copper halide clusters,
- synthetic strategies,
- structures,
- properties
1. [1]
  Khatua, S.; Goswami, S.; Biswas, S.; Tomar, K.; Jena, H. S.; Konar, S. A stable multi-responsive luminescent MOF for colorimetric detection of small molecules in selective and reversible manner. Chem. Mater. 2015, 27, 5349–5360. doi: 10.1021/acs.chemmater.5b01773
2. [2]
  Wang, X.; Tian, X.; Zhang, Q.; Sun, P.; Wu, J.; Zhou, H.; Jin, B.; Yang, J.; Zhang, S.; Wang, C.; Tao, X.; Jiang, M.; Tian, Y. Assembly, two-photon absorption, and bioimaging of living cells of a cuprous cluster. Chem. Mater. 2011, 24, 954–961.
3. [3]
  Hu, S.; Du, W.; Dai, J.; Wu, L.; Cui, C.; Fu, Z.; Wu, X. The syntheses and structures of two hexanuclear copper(Ⅱ) complexes with amino acids electronic supplementary information (ESI) available: packing diagrams for 1 and 2. J. Chem. Soc., Dalton Trans. 2001, 2963–2964.
4. [4]
  Liu, M. M.; Hou, J. J.; Qi, Z. K.; Duan, L. N.; Ji, W. J.; Han, C. Y.; Zhang, X. M. Tuning of valence states, bonding types, hierarchical structures, and physical properties in copper/halide/isonicotinate system. Inorg. Chem. 2014, 53, 4130–4143. doi: 10.1021/ic5001232
5. [5]
  Yu, M.; Liu, C.; Li, S.; Zhao, Y.; Lv, J.; Zhuo, Z.; Jiang, F.; Chen, L.; Yu, Y.; Hong, M. Constructing multi-cluster copper(Ⅰ) halides using conformationally flexible ligands. Chem. Commun. 2020, 56, 7233–7236. doi: 10.1039/D0CC02472D
6. [6]
  Zhu, Q.; Shen, C.; Tan, C.; Sheng, T.; Hu, S.; Wu, X. A one-dimensional coordination polymer constructed from planar pentanuclear copper(Ⅱ) clusters with a flexible tripodal ligand. Dalton Trans. 2012, 41, 9604–9606. doi: 10.1039/c2dt30912b
7. [7]
  Zhu, Q.; Tian, C.; Shen, C.; Sheng, T.; Hu, S.; Wu, X. A three-dimensional coordination polymer based on linear trinuclear copper(Ⅱ) clusters featuring a ferromagnetic exchange interaction. CrystEngComm. 2013, 15, 2120–2126 doi: 10.1039/c2ce26461g
8. [8]
  Jouaiti, A.; Geoffroy, M.; Bernardinelli, G. Mono- and Bi-dentate phosphaalkene ligands: structures of their copper(Ⅰ) chloride complexes. J. Chem. Soc. Dalton Trans. 1994, 1685–1688.
9. [9]
  Brooks, N. R.; Blake, A. J.; Champness, N. R.; Cooke, P. A.; Hubberstey, P.; Proserpio, D. M.; Wilson, C.; Schröder, M. Discrete molecular and extended polymeric copper(Ⅰ) halide complexes of tetradentate thioether macrocycles. J. Chem. Soc., Dalton Trans. 2001, 456–465.
10. [10]
  Wang, R. H.; Hong, M. C.; Luo, J. H.; Cao, R.; Weng, J. B. The first two novel metallomacrocycles constructed from cubane-like Cu₄I₄ cluster units and ditopic diamines. Eur. J. Inorg. Chem. 2002, 3097–3100.
11. [11]
  Bi, M.; Li, G.; Hua, J.; Liu, Y.; Liu, X.; Hu, Y.; Shi, Z.; Feng, S. Two isomers with FSC topology constructed from Cu₆I₆(DABCO)₄ and Cu₈I₈(DABCO)₆ building blocks. Cryst. Growth Des. 2007, 7, 2066–2070. doi: 10.1021/cg0700824
12. [12]
  Barbieri, A.; Accorsi, G.; Armaroli, N. Luminescent complexes beyond the platinum group: the d¹⁰ avenue. Chem. Commun. 2008, 2185–2193.
13. [13]
  Ford, P. C.; Cariati, E.; Bourassa, J. Photoluminescence properties of multinuclear copper(Ⅰ) compounds. Chem. Resv. 1999, 99, 3625−3647.
14. [14]
  Yam, V. W. W.; Lo, K. K. W. Luminescent polynuclear d¹⁰ metal complexes. Chem. Soc. Rev. 1999, 28, 323–334. doi: 10.1039/a804249g
15. [15]
  Hardt, H. D.; Pierr, A. Fluorescence thermochromism of pyridine copper iodides and copper iodide. Z. Anorg. Allg. Chem. 1973, 107–112.
16. [16]
  Ford, P. C.; Vogle, A. Photochemical and photophysical properties of tetranuclear and hexanuclear clusters of metals with d¹⁰ and s² electronic configurations. Chem. Resv. 1993, 26, 220–226. doi: 10.1021/ar00028a013
17. [17]
  Vitale, M.; Ford, P. C. Luminescent mixed ligand copper(Ⅰ) clusters (CuI)_n(L)_m (L = pyridine, piperidine): thermodynamic control of molecular and supramolecular species. Coord. Chem. Rev. 2001, 219, 3–16.
18. [18]
  Angelis, F. D.; Fantacci, S.; Sgamellotti, A.; Cariati, E.; Ugo, R.; Ford, P. C. Electronic transitions involved in the absorption spectrum and dual luminescence of tetranuclear cubane [Cu₄I₄(pyridine)₄] cluster: a density functional theory/time-dependent density functional theory investigation. Inorg. Chem. 2006, 45, 10576–10584. doi: 10.1021/ic061147f
19. [19]
  Blake, A. J.; Brooks, N. R.; Champness, N. R.; Hanton, L. R.; Hubberstey, P.; Schroder, M. Copper(Ⅰ) halide supramolecular networks linked by N-heterocyclic donor bridging ligands. Pure Appl. Chem. 1998, 70, 2351–2357. doi: 10.1351/pac199870122351
20. [20]
  Peng, R.; Li, M.; Li, D. Copper(Ⅰ) halides: a versatile family in coordination chemistry and crystal engineering. Coord. Chem. Rev. 2010, 254, 1–18. doi: 10.1016/j.ccr.2009.10.003
21. [21]
  Hu, S.; Tong, M. L. Rational design and construction of the first tetrahedral net with photoluminescent Cu₄I₄ cubane cluster as the tetrahedral node. Dalton Trans. 2005, 1165–1167.
22. [22]
  Feng, H.; Zhou, X. P.; Wu, T.; Li, D.; Yin, Y. G.; Ng, S. W. Hydrothermal synthesis of copper complexes of 4΄-pyridyl terpyridine: from discrete monomer to zigzag chain polymer. Inorg. Chim. Acta 2006, 359, 4027–4035. doi: 10.1016/j.ica.2006.04.035
23. [23]
  Kreno, L. E.; Leong, K.; Farha, O. K.; Allendorf, M.; Van Duyne, R. P.; Hupp, J. T. Metal-organic framework materials as chemical sensors. Chem. Rev. 2012, 112, 1105–1125. doi: 10.1021/cr200324t
24. [24]
  Zheng, S. T.; Yang, G. Y. Recent advances in paramagnetic-TM-substituted polyoxometalates (TM = Mn, Fe, Co, Ni, Cu). Chem. Soc. Rev. 2012, 41, 7623–7646. doi: 10.1039/c2cs35133a
25. [25]
  Gu, Z. G.; Zhan, C.; Zhang, J.; Bu, X. Chiral chemistry of metal-camphorate frameworks. Chem. Soc. Rev. 2016, 45, 3122–3144. doi: 10.1039/C6CS00051G
26. [26]
  Wang, C.; Liu, C.; Tian, H. R.; Li, L. J.; Sun, Z. M. Designed cluster assembly of multidimensional titanium coordination polymers: syntheses, crystal structure and properties. Chem. -Eur. J. 2018, 24, 2952–2961. doi: 10.1002/chem.201705013
27. [27]
  Zeng, G.; Xing, S.; Wang, X.; Yang, Y.; Xiao, Y.; Li, Z.; Li, G.; Shi, Z.; Feng, S. Synthesis, structures and luminescence properties of 3d-4f heterometallic-organic frameworks (HMOFs) constructed from different copper halide clusters. CrystEngComm. 2016, 18, 4336–4342. doi: 10.1039/C5CE02544C
28. [28]
  Fang, W. H.; Zhang, L.; Zhang, J. Synthetic strategies, diverse structures and tuneable properties of polyoxo-titanium clusters. Chem. Soc. Rev. 2018, 47, 404–421. doi: 10.1039/C7CS00511C
29. [29]
  Liu, J. H.; Zhang, J.; Zhao, D.; Lin, L. D.; Sun, Y. Q.; Li, X. X.; Zheng, S. T. The incorporation of heterovalent copper-oxo and copper-halide clusters for the fabrication of three porous cluster organic frameworks: syntheses, structures and iodine adsorption/release study. CrystEngComm. 2020, 22, 821–828. doi: 10.1039/C9CE01745C
30. [30]
  Zhang, J.; Bu, J. T.; Chen, S.; Wu, T.; Zheng, S.; Chen, Y.; Nieto, R. A.; Feng, P.; Bu, X. Urothermal synthesis of crystalline porous materials. Angew. Chem. Int. Ed. 2010, 49, 8876–8879. doi: 10.1002/anie.201003900
31. [31]
  Lin, L. D.; Li, Z.; Zhao, D.; Liu, J. H.; Li, X. X.; Zheng, S. T. Development of a new Lindqvist-like Fe₆ cluster secondary building unit for MOFs. Chem. Commun. 2019, 55, 10729–10732. doi: 10.1039/C9CC04999A
32. [32]
  Liu, W.; Fang, Y.; Wei, G. Z.; Teat, S. J.; Xiong, K.; Hu, Z.; Lustig, W. P.; Li, J. A family of highly efficient CuI-based lighting phosphors prepared by a systematic, bottom-up synthetic approach. J. Am. Chem. Soc. 2015, 137, 9400–9408. doi: 10.1021/jacs.5b04840
33. [33]
  Fu, W. F.; Gan, X.; Che, C. M.; Cao, Q. Y.; Zhou, Z. Y.; Zhu, N. N. Cuprophilic interactions in luminescent copper(Ⅰ) clusters with bridging bis(dicyclohexylphosphino)methane and iodide ligands: spectroscopic and structural investigations. Chem. -Eur. J. 2004, 10, 2228–2236. doi: 10.1002/chem.200305657
34. [34]
  Chen, B. L.; Mok, K. F.; Ng, S. C. Synthesis, crystal structures and dynamic NMR studies of novel trinuclear copper(Ⅰ) halide complexes with 2, 5-bis[(diphenylphosphino)-methyl]thiophene. J. Chem. Soc., Dalton Trans. 1998, 2861–2866.
35. [35]
  Victoriano, L. I.; Garland, M. T.; Vega, A.; Lopez, C. Syntheses, properties, crystal and molecular structure of a novel neutral pentanuclear copper(Ⅰ) iodide species. Copper(Ⅰ) complexes with tetraethylthiuram monosulfide. J. Chem. Soc., Dalton Trans. 1998, 1127–1131.
36. [36]
  Xue, X.; Wang, X. S.; Xiong, R. G.; You, X. Z.; Abrahams, B. F.; Che, C. M.; Ju, H. X. A cluster rearrangement of an open cubane (Cu₄Br₄) to a prismane (Cu₆Br₆) in a copper(Ⅰ)-olefin network. Angew. Chem. Int. Ed. 2002, 41, 2944–2946. doi: 10.1002/1521-3773(20020816)41:16<2944::AID-ANIE2944>3.0.CO;2-Z
37. [37]
  Amoore, J. J. M.; Hanton, L. R.; Spicer, M. D. Banded ribbons of Cu₆I₆ hexamers and multimodal thioether pyrazine ligands linked by self-complementary N⋅⋅⋅H–C synthons. Dalton Trans. 2003, 1056–1058.
38. [38]
  Ohi, H.; Tachi, Y.; Kunimoto, T.; Itoh, S. Structure and photoluminescence property of two-dimensional coordination polymer complexes involving Cu^I6X₆ (X = Cl, Br, I) hexagon prism cluster supported by a tripodal tripyridine ligand with 1, 3, 5-triethylbenzene spacer. Dalton Trans. 2005, 3146–3147.
39. [39]
  Cariati, E.; Roberto, D.; Ugo, R.; Ford, P. C.; Galli, S.; Sironi, A. New structural motifs, unusual quenching of the emission, and second harmonic generation of copper(Ⅰ) iodide polymeric or oligomeric adducts with para-substituted pyridines or trans-stilbazoles. Inorg. Chem. 2005, 44, 4077–4085. doi: 10.1021/ic050143s
40. [40]
  Lobana, T. S.; Kaur, P.; Nishioka, T. Synthesis of an unprecedented bicapped adamantoid [Cu₆(µ₂-I)(µ₃-I)₄(µ₄-I)(m-tolyl₃P)₄(CH₃CN)₂] cluster. Inorg. Chem. 2004, 43, 3766−3767. doi: 10.1021/ic049903+
41. [41]
  Pike, R. D.; Borne, B. D.; Maeyer, J. T.; Rheingold, A. L. 1, 3, 5-Triazine templated self-assembly of a hexameric copper(Ⅰ) chloride triphenyl phosphite core. Inorg. Chem. 2002, 41, 631−633. doi: 10.1021/ic015605q
42. [42]
  Cecconi, F.; Ghilardi, C. A.; Midoliini, S.; Orlandini, A. A heterometallic 'super-sandwich' containing a novel hexagonal Cu₆ unit at the centre: synthesis and X-ray structure determination of [{MeC(CH₂PPh₂)₃}CoP₃](CuBr)₆[P₃Co{(Ph₂PCH₂)₃CMe)]·2CH₂CI₂. J. Chem. Soc., Chem. Commun. 1982, 229–230.
43. [43]
  Chong, J. H.; MacLachlan, M. J. Robust non-interpenetrating coordination frameworks from new shape-persistent building blocks. Inorg. Chem. 2006, 45, 1442−1444. doi: 10.1021/ic052123w
44. [44]
  Wu, T.; Li, M.; Li, D.; Huang, X. C. Anionic Cunin cluster-based architectures induced by in situ generated N-alkylated cationic triazolium salts. Cryst. Growth Des. 2008, 8, 568–574. doi: 10.1021/cg070639f
45. [45]
  Solntsev, P. V.; Sieler, J.; Krautscheid, H.; Domasevitch, K. V. Fused pyridazines: rigid multidentates for designing and fine-tuning the structure of hybrid organic/inorganic frameworks. Dalton Trans. 2004, 1153–1158.
46. [46]
  Di Nicola, C.; Koutsantonis, G. A.; Pettinari, C.; Skelton, B. W.; Somers, N.; White, A. H. The structural definition of some novel adducts of stoichiometry CuX: dpex: MeCN (2: 1: 1)_(n), X = (pseudo-) halogen, dpp_x = Ph₂E(CH₂)_xEPh₂, E = P, As, Sb. Inorg. Chim. Acta 2006, 359, 2159–2169. doi: 10.1016/j.ica.2005.12.019
47. [47]
  Kang, Y.; Wang, F.; Zhang, J.; Bu, X. Luminescent MTN-type cluster-organic framework with 2.6 nm cages. J. Am. Chem. Soc. 2012, 134, 17881–17884. doi: 10.1021/ja308801n
48. [48]
  Shan, X. C.; Jiang, F. L.; Yuan, D. Q.; Zhang, H. B.; Wu, M. Y.; Chen, L.; Wei, J.; Zhang, S. Q.; Jie, P.; Hong, M. C. A multi-metal-cluster MOF with Cu₄I₄ and Cu₆S₆ as functional groups exhibiting dual emission with both thermochromic and near-IR character. Chem. Sci. 2013, 4, 1484–1489. doi: 10.1039/c3sc21995j
49. [49]
  Zhang, Y.; He, X.; Zhang, J.; Feng, P. CuI cluster-based organic frameworks with unusual 4- and 5-connected topologies. Cryst. Growth Des. 2011, 11, 29–32. doi: 10.1021/cg101321u
50. [50]
  Fang, W. H.; Wang, J. F.; Zhang, L.; Zhang, J. Titanium-oxo cluster based precise assembly for multidimensional materials. Chem. Mater. 2017, 29, 2681–2684. doi: 10.1021/acs.chemmater.7b00324
51. [51]
  Wang, X. L.; Qin, C.; Wang, E. B.; Su, Z. M.; Li, Y. G.; Xu, L. Self-assembly of nanometer-scale [Cu₂₄I₁₀L₁₂]¹⁴⁺ cages and ball-shaped Keggin clusters into a (4, 12)-connected 3D framework with photoluminescent and electrochemical properties. Angew. Chem. Int. Ed. 2006, 45, 7411–7414. doi: 10.1002/anie.200603250
52. [52]
  Li, M.; Li, Z.; Li, D. Unprecedented cationic copper(Ⅰ)-iodide aggregates trapped in "click" formation of anionic-tetrazolate-based coordination polymers. Chem. Commun. 2008, 7, 3390–3392.
53. [53]
  Hard, H.; Mahdjour-Hassan-Abadi, F. [Cu₅I₇]^2- - an isopolyanion with cyclic face-to-face linking of CuI₄ tetrahedra. Angew. Chem. Int. Ed. 1984, 23, 378–379. doi: 10.1002/anie.198403781
54. [54]
  Mahdjour-Hassan-Abadi, F.; Hartl, H.; Fuchs, J. [Cu₆I₁₁]^5- - a polyanion with trigonal-prismatic arrangement of six metal atoms. Angew. Chem. Int. Ed. 1984, 23, 514–515. doi: 10.1002/anie.198405141
55. [55]
  Su, C. Y.; Cai, Y. P.; Chen, C. L.; Lissner, F.; Kang, B. S.; Kaim, W. Self-assembly of trigonal-prismatic metallocages encapsulating BF₄^- or CuI₃^2- as anionic guests: structures and mechanism of formation. Angew. Chem. Int. Ed. 2002, 41, 3370–3375.
56. [56]
  Rath, N. P.; Holt, E. M. Copper(Ⅰ) iodide complexes of novel structure: [Cu₄I₆][Cu₈I₁₃]K₇(12-crown-4)₆, [Cu₄I₆]K₂(15-crown-5)₂, and [Cu₃I₄]K(dibenzo-24-crown-8). J. Chem. Soc., Chem. Commun. 1985, 665–667.
57. [57]
  Rusanova, J. A.; Domasevitch, K. V.; Vassilyeva, O. Y.; Kokozay, V. N.; Rusanov, E. B.; Nedelko, S. G.; Chukova, O. V.; Ahrens, B.; Raithby, P. R. New luminescent copper(Ⅰ) halide complexes containing Rb⁺ complexes of 18-crown-6 as counter ions prepared from zerovalent copper. J. Chem. Soc., Dalton Trans. 2000, 2175–2182.
58. [58]
  Fang, W. H.; Zhang, L.; Zhang, J. Assembly of titanium-oxo cations with copper-halide anions to form supersalt-type cluster-based materials. Chem. Commun. 2017, 53, 3949–3951. doi: 10.1039/C7CC01443K
59. [59]
  HQkansson, M.; Jagner, S. Preparation and structural characterization of Cu(CO)CI. Inorg. Chem. 1990, 29, 5241–5244. doi: 10.1021/ic00351a021
60. [60]
  Blake, A. J.; Brooks, N. R.; Champness, N. R.; Cooke, P. A.; Deveson, A. M.; Fenske, D.; Hubberstey, P.; Li, W. S.; Schröder, M. Controlling copper(Ⅰ) halide framework formation using N-donor bridging ligand symmetry: use of 1, 3, 5-triazine to construct architectures with threefold symmetry. J. Chem. Soc., Dalton Trans. 1999, 2103–2110.
61. [61]
  Hikansson, M.; Jagner, S. A complex between isoprene and copper(Ⅰ) chloride: synthesis and structural characterization. Organometallics 1991, 10, 1317–1319. doi: 10.1021/om00051a021
62. [62]
  Cheng, J. K.; Yao, Y. G.; Zhang, J.; Li, Z. J.; Cai, Z. W.; Zhang, X. Y.; Chen, Z. N.; Chen, Y. B.; Kang, Y.; Qin, Y. Y.; Wen, Y. H. A simultaneous redox, alkylation, self-assembly reaction under solvothermal conditions afforded a luminescent copper(Ⅰ) chain polymer constructed of Cu₃I₄^- and EtS-4-C₅H₄N⁺Et components (Et = CH₃CH₂). J. Am. Chem. Soc. 2004, 126, 7796–7797. doi: 10.1021/ja048624i
63. [63]
  Kang, Y.; Fang, W. H.; Zhang, L.; Zhang, J. A structure-directing method to prepare semiconductive zeolitic cluster-organic frameworks with Cu₃I₄ building units. Chem. Commun. 2015, 51, 8994–8997. doi: 10.1039/C5CC02598B
64. [64]
  Liu, J.; Tang, Y. H.; Wang, F.; Zhang, J. Syntheses of copper-iodine cluster-based frameworks for photocatalytic degradation of methylene blue. CrystEngComm. 2018, 20, 1232–1236. doi: 10.1039/C7CE02192E
65. [65]
  Hu, L. X.; Gao, M.; Wen, T.; Kang, Y.; Chen, S. Synthesis of Halide-modulated cuprous(Ⅰ) coordination polymers with mechanochromic and photocatalytic properties. Inorg. Chem. 2017, 56, 6507–6511. doi: 10.1021/acs.inorgchem.7b00598
66. [66]
  Horvbth, O. Photochemistry of copper complexes. Coord. Chem. Rev. 1994, 135, 303–325.
67. [67]
  Zhang, X.; Liu, W.; Wei, G. Z.; Banerjee, D.; Hu, Z.; Li, J. Systematic approach in designing rare-earth-free hybrid semiconductor phosphors for general lighting applications. J. Am. Chem. Soc. 2014, 136, 14230–14236. doi: 10.1021/ja507927a
68. [68]
  Tan, Y. X.; He, Y. P.; Zhang, J. Cluster-organic framework materials as heterogeneous catalysts for high efficient addition reaction of diethylzinc to aromatic aldehydes. Chem. Mater. 2012, 24, 4711–4716. doi: 10.1021/cm302953x
69. [69]
  Tan, Y. X.; He, Y. P.; Zhang, J. Pore partition effect on gas sorption properties of an anionic metal-organic framework with exposed Cu²⁺ coordination sites. Chem. Commun. 2011, 47, 10647–10649. doi: 10.1039/c1cc14118j
70. [70]
  Hu, L. X.; Wang, F.; Kang, Y.; Zhang, J. Structural design of zeolitic cluster organic frameworks from hexamethylentetramine and copper-halide clusters. Cryst. Growth Des. 2016, 16, 7139–7144. doi: 10.1021/acs.cgd.6b01364
71. [71]
  Wen, T.; Zhang, D. X.; Ding, Q. R.; Zhang, H. B.; Zhang, J. Two luminescent Cu(Ⅰ) coordination polymers based on the 1-(4-tetrazolephenyl)imidazole ligand for sensing of nitrobenzene. Inorg. Chem. Front. 2014, 1, 389–392. doi: 10.1039/c4qi00016a
72. [72]
  Liu, J.; Wang, F.; Liu, L. Y.; Zhang, J. Interpenetrated three-dimensional copper-iodine cluster-based framework with enantiopure porphyrin-like templates. Inorg. Chem. 2016, 55, 1358–1360. doi: 10.1021/acs.inorgchem.5b02692
73. [73]
  Shi, D.; Zheng, R.; Sun, M. J.; Cao, X.; Sun, C. X.; Cui, C. J.; Liu, C. S.; Zhao, J.; Du, M. Semiconductive copper(Ⅰ)-organic frameworks for efficient light-driven hydrogen generation without additional photosensitizers and cocatalysts. Angew. Chem. Int. Ed. 2017, 56, 14637–14641. doi: 10.1002/anie.201709869
1. [1]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
2. [2]
  Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
3. [3]
  Luyao Lu , Chen Zhu , Fei Li , Pu Wang , Xi Kang , Yong Pei , Manzhou Zhu . Ligand effects on geometric structures and catalytic activities of atomically precise copper nanoclusters. Chinese Journal of Structural Chemistry, 2024, 43(10): 100411-100411. doi: 10.1016/j.cjsc.2024.100411
4. [4]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
5. [5]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
6. [6]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
7. [7]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
8. [8]
  Shu-Ran Xu , Fang-Xing Xiao . Metal halide perovskites quantum dots: Synthesis, and modification strategies for solar CO2 conversion. Chinese Journal of Structural Chemistry, 2023, 42(12): 100173-100173. doi: 10.1016/j.cjsc.2023.100173
9. [9]
  Zhenyang Lin . A classification scheme for inorganic cluster compounds based on their electronic structures and bonding characteristics. Chinese Journal of Structural Chemistry, 2024, 43(5): 100254-100254. doi: 10.1016/j.cjsc.2024.100254
10. [10]
  Jiale Zheng , Mei Chen , Huadong Yuan , Jianmin Luo , Yao Wang , Jianwei Nai , Xinyong Tao , Yujing Liu . Electron-microscopical visualization on the interfacial and crystallographic structures of lithium metal anode. Chinese Chemical Letters, 2024, 35(6): 108812-. doi: 10.1016/j.cclet.2023.108812
11. [11]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
12. [12]
  Zhihao Gu , Jiabo Le , Hehe Wei , Zehui Sun , Mahmoud Elsayed Hafez , Wei Ma . Unveiling the intrinsic properties of single NiZnFeO_x entity for promoting electrocatalytic oxygen evolution. Chinese Chemical Letters, 2024, 35(4): 108849-. doi: 10.1016/j.cclet.2023.108849
13. [13]
  Wenzhong Zhang , Zirui Yan , Lingcheng Chen , Yi Xiao . Sn-fused perylene diimides: Synthesis, mechanism, and properties. Chinese Chemical Letters, 2024, 35(10): 109582-. doi: 10.1016/j.cclet.2024.109582
14. [14]
  Shehla Khalid , Muhammad Bilal , Nasir Rasool , Muhammad Imran . Photochemical reactions as synthetic tool for pharmaceutical industries. Chinese Chemical Letters, 2024, 35(9): 109498-. doi: 10.1016/j.cclet.2024.109498
15. [15]
  Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424
16. [16]
  Meihui Liu , Xinyuan Zhou , Xiao Li , Zhenjie Xue , Tie Wang . Pushing the frontiers: Chip-based detection based on micro- and nano-structures. Chinese Chemical Letters, 2024, 35(4): 108875-. doi: 10.1016/j.cclet.2023.108875
17. [17]
  Ruonan Guo , Heng Zhang , Changsheng Guo , Ningqing Lv , Beidou Xi , Jian Xu . Degradation of neonicotinoids with different molecular structures in heterogeneous peroxymonosulfate activation system through different oxidation pathways. Chinese Chemical Letters, 2024, 35(9): 109413-. doi: 10.1016/j.cclet.2023.109413
18. [18]
  Xinyi Cao , Yucheng Jin , Hailong Wang , Xu Ding , Xiaolin Liu , Baoqiu Yu , Xiaoning Zhan , Jianzhuang Jiang . A tetraaldehyde-derived porous organic cage and covalent organic frameworks: Syntheses, structures, and iodine vapor capture. Chinese Chemical Letters, 2024, 35(9): 109201-. doi: 10.1016/j.cclet.2023.109201
19. [19]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
20. [20]
  Ya Song , Mingxia Zhou , Zhu Chen , Huali Nie , Jiao-Jing Shao , Guangmin Zhou . Integrated interconnected porous and lamellar structures realized fast ion/electron conductivity in high-performance lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(6): 109200-. doi: 10.1016/j.cclet.2023.109200

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(242)
HTML views(29)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142