Citation: Jian-Hao CUI, Wen-Ting ZHANG, Hui-Dong ZHENG, Hao-Hong LI. Haloplumbate Nanochains Templated by Quaternary Phosphorus: Good Water Stabilities, Thermochromic Luminescence and Photocurrent Responses[J]. Chinese Journal of Structural Chemistry, ;2021, 40(6): 775-784. doi: 10.14102/j.cnki.0254–5861.2011–3009 shu

Haloplumbate Nanochains Templated by Quaternary Phosphorus: Good Water Stabilities, Thermochromic Luminescence and Photocurrent Responses

Jian-Hao CUI ^a ,
Wen-Ting ZHANG ^b ,
Hui-Dong ZHENG ^{a, c,,} ,
Hao-Hong LI ^{b, c,,}

a.
College of Chemical Engineering, Fuzhou University, Fuzhou 350108, China
b.
College of Chemistry, Fuzhou University, Fuzhou 350108, China
c.
Fujian Engineering Research Center of Advanced Manufacturing Technology for Fine Chemicals, Fuzhou University, Fuzhou 350108, China

Corresponding author: Hui-Dong ZHENG, youngman@fzu.edu.cn Hao-Hong LI, lihh@fzu.edu.cn
Received Date: 26 January 2020
Accepted Date: 28 February 2020

Fund Project: the National Natural Science Foundation of China 22078065

Figures(8)

Two triphenylmethylphosphonium/haloplumbate hybrids, i.e., [(PPh₃Me)₂(Pb₂I₆)∙CH₃CN]_n (1) and [(PPh₃Me)(PbBr₃)]_n (2), have been prepared, in which the (PbX₃)_n^n- nanochains built from face-sharing PbX₆ octahedra are surrounded by organic templates to assemble the core-shell quantum well. Besides, C−H…π interactions among Ph₃PMe⁺ cations can also be detected, which give rise to the 2-D organic layer of 1 and 1-D chain for 2. The good water stabilities could be induced by the strong C−H…π interactions, which can deter the hydrolysis reaction. The energy band gaps of this work mainly derive from the charge transfer of organic components, but their luminescence stems from the inorganic (PbX₃)_n^n- nanochains with co-existence of free excitons and self-trapped excitons. At temperature lower than 117 K, strong quantum confinement will rule out the free excitons, and self-trapped excitons will dominate, resulting in red-shift luminescence. Moreover, effective and repeatable photocurrent responses can be found in these hybrids.
- organic-inorganic hybrid,
- haloplumbate,
- quaternary phosphorus,
- photoluminescence,
- photocurrent response
1. [1]
  Wang, G. E.; Sun, C.; Wang, M. S.; Guo, G. C. Semiconducting crystalline inorganic-organic hybrid metal halide nanochains. Nanoscale 2020, 12, 4771–4789. doi: 10.1039/C9NR10164K
2. [2]
  Zong, Y.; Wang, N.; Zhang, L.; Ju, M. G.; Zeng, X. C.; Sun, X. W.; Zhou, Y.; Padture, N. P. Homogenous alloys of formamidinium lead triiodide and cesium tin triiodide for efficient ideal-bandgap perovskite solar cells. Angew. Chem. Int. Ed. 2017, 56, 12658−12662. doi: 10.1002/anie.201705965
3. [3]
  Bekenstein, Y.; Koscher, B. A.; Eaton, S. W.; Yang, P.; Alivisatos, A. P. Highly luminescent colloidal nanoplates of perovskite cesium lead halide and their oriented assemblies. J. Am. Chem. Soc. 2015, 137, 16008−16011. doi: 10.1021/jacs.5b11199
4. [4]
  Wang, Y. K.; Wu, Y. L.; Lin, X. Y.; Wang, D. H.; Zhang, W. T.; Song, K. Y.; Li, H. H.; Chen, Z. R. Halobismuthate/diphenyliodonium hybrids stabilized by secondary hypervalent I(Ⅲ)…X interactions: structures, optical studies and thermochromisms. J. Mole. Struct. 2018, 1151, 81−87. doi: 10.1016/j.molstruc.2017.09.033
5. [5]
  Peng, W.; Chen, Z. R.; Li, H. H. Tetrameric (Bi₄I₁₆)^4- iodobismuthate templated by 1, ω-bis(isoquinoline)alkane cation: structure, photoluminescence and enhanced thermochromism. Chin. J. Struct. Chem. 2019, 38, 1485−1493.
6. [6]
  Wang, D. H.; Lin, X. Y.; Wang, Y. K.; Zhang, W. T.; Song, K. Y.; Lin, H.; Li, H. H.; Chen, Z. R. A new iodiplumbate-based hybird constructed from asymmetric viologen and polyiodides: structure, properties and photocatalytic activity for the degradation of organic dye. Chin. J. Struct. Chem. 2017, 36, 2000−2006.
7. [7]
  Ramasamy, P.; Lim, D. H.; Kim, B.; Lee, S. H.; Lee, M. S.; Lee, J. S. All-inorganic cesium lead halide perovskite nanocrystals for photodetector applications. Chem. Commun. 2016, 52, 2067−2070. doi: 10.1039/C5CC08643D
8. [8]
  Zeng, X. H.; He, X.; Chen, J. Y.; Zhang, J. W.; Li, H. H.; Chen, Z. R. Polymeric iodoplumbate templated by photochemically active coordination cation [Ru(phen)₃]²⁺: structure and properties of a bimetallic inorganic-organic hybrid. J. Clust. Sci. 2014, 25, 979–988. doi: 10.1007/s10876-013-0681-1
9. [9]
  Wu, L. M.; Wu, X. T.; Chen, L. Structural overview and structure-property relationships of iodoplumbate and iodobismuthate. Chem. Rev. 2009, 253, 2787−2804.
10. [10]
  Zhang, G.; Yin, J.; Song, X.; Fei, H. A moisture-stable organosulfonate-based metal-organic framework with intrinsic self-trapped white-light emission. Chem. Commun. 2020, 56, 1325−1328. doi: 10.1039/C9CC09486E
11. [11]
  Lin, X. L.; Chen, B.; Huang, Y. R.; Song, K. Y.; Zhou, P. K.; Zong, L. L.; Li, H. H.; Chen, Z. R.; Rong, J. The achievement of intrinsic white-light-emitting by hybridization deformable haloplumbates with rigid luminescent naphthalene motif. Inorg. Chem. Front. 2020, 7, 4477–4487. doi: 10.1039/D0QI00995D
12. [12]
  Sun, C.; Xu, G.; Jiang, X. M.; Wang, G. E.; Guo, P. Y.; Wang, M. S.; Guo, G. C. Design strategy for improving optical and electrical properties and stability of lead-halide semiconductors. J. Am. Chem. Soc. 2018, 140, 2805–2811. doi: 10.1021/jacs.7b10101
13. [13]
  Alam, P.; Leung, N. L. C.; Liu, J. K.; Cheung, T. S.; Zhang, X. P.; He, Z. K.; Kwok, R. T. K.; Lam, J. W. Y.; Sung, H. H. Y.; Williams, I. D.; Chan, C. C. S.; Wong, K. S.; Peng, Q.; Tang, B. Z. Two are better than one: a design principle for ultralong-persistent luminescence of pure organics. Adv. Mater. 2020, 32, 2001026−7. doi: 10.1002/adma.202001026
14. [14]
  Zhang, W. T.; Liu, J. Z.; Liu, J. B.; Song, K. Y.; Li, Y.; Chen, Z. R.; Li, H. H.; Jian, R. Quaternary phosphorus-induced iodocuprate(Ⅰ)-based hybrids: water stabilities, tunable luminescences and photocurrent responses. Eur. J. Inorg. Chem. 2018, 38, 4234–4244.
15. [15]
  Czado, W.; Muller, U. Tetraphenylphosphonium-trichloroplumbat(Ⅱ), PPh₄PbCl₃ center dot CH₃CN. Z. Anorg. Allg. Chem. 1998, 624, 925−926. doi: 10.1002/(SICI)1521-3749(199806)624:6<925::AID-ZAAC925>3.0.CO;2-L
16. [16]
  Krautscheid, H.; Vielsack, F. Iodoplumbates with tetra- and penta-coordinated Pb²⁺ ions. Z. Anorg. Allg. Chem. 1999, 625, 562−566. doi: 10.1002/(SICI)1521-3749(199904)625:4<562::AID-ZAAC562>3.0.CO;2-Z
17. [17]
  Krautscheid, H.; Lekieffre, J. F.; Besinger, J. Iodoplumbates with polymeric anions-synthesis and crystal structures of [Na₃(OCMe₂)₁₂][Pb₄I₁₁(OCMe₂)], (Ph₄P)₂[Pb₅I₁₂], and (Ph₄P)₄[Pb₁₅I₃₄dmf₆]. Z. Anorg. Allg. Chem. 1996, 622, 1781−1787. doi: 10.1002/zaac.19966221024
18. [18]
  Klapotke, T. M.; Krumm, B.; Polborn, K.; Rienacker, C. M. Synthesis and characterization of bromo- and bromochloroplumbates(Ⅱ) crystal structures of [Ph₄E]₂[Pb₃Br₈] (E = P, As) and [Ph₄P][PbBrCl₂]CH₃CN. Z. Naturforsch. Teil B 2000, 55, 377−382. doi: 10.1515/znb-2000-0506
19. [19]
  Elessawi, M.; Wartchow, R.; Berthold, H. J. Crystal structure of triphenylmethylphosphonium triiodoplumbate, (P(C₆H₅)₃(CH₃))(PbI₃). Z. Kristallogr. 1997, 212, 163−164.
20. [20]
  Zhao, Y.; Feng, T.; Li, G.; Liu, F.; Dai, X.; Dong, Z.; Qiu, X. Synthesis and properties of novel polyimide fibers containing phosphorus groups in the side chain (DATPPO). RSC Adv. 2016, 6, 42482–42494. doi: 10.1039/C6RA02344D
21. [21]
  Lin, X. Y.; Zhao, L. M.; Wang, D. H.; Wang, Y. K.; Li, M.; Li, H. H.; Chen, Z. R. Structural diversities of squarate-based complexes: photocurrent responses and thermochromic behaviours enchanced by viologens. Inorg. Chem. Front. 2018, 5, 189−199.
22. [22]
  Wang, D. H.; Zhao, L. M.; Lin, X. Y.; Wang, Y. K.; Zhang, W. T.; Song, K. Y.; Li, H. H.; Chen, Z. R. Iodoargentate/iodobismuthate-based materials hybridized with lanthanide-containing metalloviologens: thermochromic behaviors and photocurrent responses. Inorg. Chem. Front. 2018, 5, 1162–1173. doi: 10.1039/C7QI00755H
23. [23]
  Sheldrick, G. M. SHELXS 97, Program for the Solution of Crystal Structures. University of Götingen, Germany 1997.
24. [24]
  Sheldrick, G. M. SHELXL 97, Program for the Refinement of Crystal Structures. University of Göttingen, Germany 1997.
25. [25]
  Li, H. H.; Wang, Y. J.; Lian, Z. X.; Xu, Y. F.; Wang, M.; Huang, S. W.; Chen, Z. R. An additional structure and property study on polymeric haloplumbates(Ⅱ) with aromatic N-heterocyclic organic molecules. J. Mole. Struct. 2012, 1016, 118−125. doi: 10.1016/j.molstruc.2012.02.028
26. [26]
  Krautscheid, H.; Lode, C.; Vielsack, F.; Vollmer, H. Synthesis and crystal structures of iodoplumbate chains, ribbons and rods with new structural types. J. Chem. Soc. Dalton Trans. 2001, 7, 1099−1104.
27. [27]
  Liu, W.; Zhu, K.; Teat, S. J.; Dey, G.; Shen, Z. Q.; Wang, L.; O'Carroll, D. M.; Li, J. All-in-one: achieving robust, strongly luminescent and highly dispersible hybrid materials by combining ionic and coordinate bonds in molecular crystals. J. Am. Chem. Soc. 2017, 139, 9281–9290. doi: 10.1021/jacs.7b04550
28. [28]
  Huang, C. H.; Wen, M.; Wang, C. Y.; Lu, Y. F.; Huang, X. H.; Li, H. H.; Wu, S. T.; Zhuang, N. F.; Hu, X. L. A series of pure-blue-light emitting Cu(Ⅰ) complexes with thermally activated delayed fluorescence: structural, photophysical, and computational studies. Dalton Trans. 2017, 46, 1413–1419. doi: 10.1039/C6DT03965K
29. [29]
  Xu, L. J.; Wang, J. Y.; Zhu, X. F.; Zeng, X. C.; Chen, Z. N. Phosphorescent cationic Au₄Ag₂ alkynyl cluster complexes for efficient solution-processed organic light-emitting diodes. Adv. Funct. Mater. 2015, 25, 3033–3042. doi: 10.1002/adfm.201500060
30. [30]
  Schevciw, O.; White, W. B. The optical absorption edge of rare earth sesquisulfides and alkaline earth-rare earth sulfides. Mater. Res. Bull. 1983, 18, 1059−1062. doi: 10.1016/0025-5408(83)90147-2
31. [31]
  Baibarac, M.; Preda, N.; Mihut, L.; Baltog, I.; Lefrant, S.; Mevellec, J. Y. On the optical properties of micro-and nanometric size PbI₂ particles. J. Phys. Condens. Mat. 2004, 16, 2345−2356. doi: 10.1088/0953-8984/16/13/014
32. [32]
  Liu, B.; Xu, L.; Guo, G. C.; Huang, J. S. Three inorganic-organic hybrids of bismuth(Ⅲ) iodide complexes containing substituted 1, 2, 4-triazole organic components with characterization of diffuse reflectance spectra. J. Solid State Chem. 2006, 179, 1611−1617. doi: 10.1016/j.jssc.2006.02.011
33. [33]
  Zhang, Z. J.; Xiang, S. C.; Zhang, Y. F.; Wu, A. Q.; Cai, L. Z.; Guo, G. C.; Huang, J. S. A new type of hybrid magnetic semiconductor based upon polymeric iodoplumbate and metal-organic complexes as templates. Inorg. Chem. 2006, 45, 1972−1977. doi: 10.1021/ic051350v
34. [34]
  Yuan, Z.; Zhou, C.; Shu, Y.; Tian, Y.; Messier, J.; Wang, J.; Burgt, L.; Kountouriotis, K.; Xin, Y.; Holt, E.; Schanze, K. S.; Clark, R.; Siegrist, T.; Ma, B. One-dimensional organic lead halide perovskites with efficient bluish white-light emission. Nat. Commun. 2017, 8, 14051−7. doi: 10.1038/ncomms14051
35. [35]
  Lin, H.; Zhou, C. K.; Tian Y.; Besara, T.; Neu, J.; Siegrist, T.; Zhou, Y.; Bullock, J.; Schanze, K. S.; Ming, W. M.; Du, M. H.; Ma, B. W. Bulk assembly of organic metal halide nanotubes. Chem. Sci. 2017, 8, 8400–8404. doi: 10.1039/C7SC03675B
36. [36]
  He, Y.; Huang, Y. R.; Li, Y. L.; Li, H. H.; Chen, Z. R.; Jiang, R. Encapsulating halometallates into 3-D lanthanide-viologen frameworks: controllable emissions, reversible thermochromism, photocurrent responses and electrical bistability behaviors. Inorg. Chem. 2019, 58, 13862−13880. doi: 10.1021/acs.inorgchem.9b01740
37. [37]
  Sun, Y. G.; Ji, S. F.; Huo, P.; Yin, J. X.; Huang, Y. D.; Zhu, Q. Y.; Dai, J. Role of the coordination center in photocurrent behavior of a tetrathiafulvalene and metal complex dyad. Inorg. Chem. 2014, 53, 3078–3087. doi: 10.1021/ic402993y
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