Citation: Hua CAI, Na LI, Yan LI, Dong-Min AN. Solvothermal Synthesis and Characterization of Two Cd(II) Coordination Polymers with Isomeric Multi-carboxylate Ligands[J]. Chinese Journal of Structural Chemistry, ;2021, 40(5): 637-645. doi: 10.14102/j.cnki.0254–5861.2011–2995 shu

Solvothermal Synthesis and Characterization of Two Cd(II) Coordination Polymers with Isomeric Multi-carboxylate Ligands

College of Science, Civil Aviation University of China, Tianjin 300300, China

Corresponding author: Hua CAI, caihua-1109@163.com
Received Date: 27 September 2020
Accepted Date: 5 January 2021

Fund Project: Scientific Research Project of Tianjin Education Commission 2018KJ250National Natural Science Foundation of China 21501196

Figures(7)

In this work two isomeric semi-rigid multi-carboxylate ligands 3, 5-bi(3-carboxyphenoxy)benzoic acid (3-H₃BCP), 3, 5-bi(4-carboxyphenoxy)benzoic acid (4-H₃BCP) and two rigid ligands (bis-triazole 4-(4-(4H-1, 2, 4-triazol-4-yl)phenyl)-4H-1, 2, 4-triazole (L¹), 2-(1H-pyrazol-3-yl)pyrazine (L²)) have been employed to react with Cd(II) salts under similar solvothermal reactions. Two novel Cd(II) mixed-ligand coordination polymers, namely, {[Cd₃(3-BCP)₂(L¹)]·3H₂O}_n (1) and [Cd(4-HBCP)(L²)]_n (2), have been isolated. 1 displays a rare 2D cluster-based network while 2 displays a 3D supramolecular network through weak interactions. Solid-state luminescent properties and thermal analyses of 1 and 2 also have been determined, indicating strong fluorescent emissions and good thermal stabilities. Different coordination modes of two semi-rigid multi-carboxylate ligands and L¹ and L² also have been briefly discussed, which also reveal the great potential in the construction of these novel mixed-ligand luminescent frameworks with diverse structural motifs and unique functional properties.
- isomeric,
- semirigid multicarboxylate,
- photoluminescent properties
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