Citation: Zeng-Hui LI, Liang HE, Yu-Jun GUO, Ming-Bu LUO, Qi-Pu LIN. A Stable Luminescent MOF Constructed by Bis-(4-pyridyl)thiazolo[5, 4-d]thiazole Containing Multi-electron Donor-acceptor Core[J]. Chinese Journal of Structural Chemistry, ;2021, 40(5): 610-614. doi: 10.14102/j.cnki.0254–5861.2011–2992 shu

A Stable Luminescent MOF Constructed by Bis-(4-pyridyl)thiazolo[5, 4-d]thiazole Containing Multi-electron Donor-acceptor Core

Zeng-Hui LI ^{a, b} ,
Liang HE ^{a, b} ,
Yu-Jun GUO ^{a, c} ,
Ming-Bu LUO ^{a, b} ,
Qi-Pu LIN ^a,,

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China

Corresponding author: Qi-Pu LIN, linqipu@fjirsm.ac.cn
Received Date: 24 September 2020
Accepted Date: 10 December 2020

Fund Project: the Strategic Priority Research Program of Chinese Academy of Sciences XDB20000000

Figures(3)

Constructed from 2, 5-bis(4-pyridyl) thiazolo[5, 4-d]thiazole (Py₂TTz), sulfate anions and metal ions Cd(II), a new 3D luminescent metal-organic framework (LMOF) with good water stability is synthesized under solvothermal condition. [Cd(Py₂TTz)(SO₄)]_n (Py₂TTz = 2, 5-bis(4-pyridyl) thiazolo[5, 4-d]thiazole). It crystallizes in tetragonal space group P42₁m with a = 6.830(3), b = 6.830(3), c = 17.676(12) Å, V = 824.5(8) Å³, Z = 4, M_r = 504.83, D_c = 2.033 g·cm^-3, F(000) = 496, GOOF = 1.088, the final R = 0.0434 and wR = 0.0948 for 6301 reflections with I > 2σ(I). Upon excitation at 370 nm, the emission peak of the compound appears at 455 nm, which has a slight redshift compared to the free ligand Py₂TTz. The compound has potential to be a luminescence sensing material.
- thiazolo-thiazole,
- X-ray crystallography,
- water-stability,
- luminescence
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