Citation: Yong ZHANG, Hong-Ni QIN, Bao-Long LI, Bing WU. Syntheses, Structures and Photocatalytic Degradation Properties of Two Copper(Ⅱ) Coordination Polymers with Flexible Bis(imidazole) Ligand[J]. Chinese Journal of Structural Chemistry, ;2021, 40(5): 595-602. doi: 10.14102/j.cnki.0254–5861.2011–2989 shu

Syntheses, Structures and Photocatalytic Degradation Properties of Two Copper(Ⅱ) Coordination Polymers with Flexible Bis(imidazole) Ligand

Yong ZHANG ^a ,
Hong-Ni QIN ^a ,
Bao-Long LI ^b,, ,
Bing WU ^b

a.
China Suzhou Industrial Park Institute of Services Outsourcing, Suzhou 215123, China
b.
State and Local Joint Engineering Laboratory for Functional Polymeric Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China

Corresponding author: Bao-Long LI, libaolong@suda.edu.cn
Received Date: 22 September 2020
Accepted Date: 25 November 2020

Fund Project: the Natural Science Foundation of Jiangsu Province BK20161212the Priority Academic Program Development of Jiangsu Higher Education Institutions, and the project of scientific and technological infrastructure of Suzhou SZS201905

Figures(7)

Two copper(Ⅱ) coordination polymers {[Cu(bib)(nip)]·1.5H₂O}_n (1) and [Cu₂(bib)(glu)₂]_n (2) (bib = 1, 4-bis(2-methyl-imidazol-1-yl)butane, H₂nip = 5-nitroisophthalic acid, H₂glu = glutaric acid) were synthesized by the hydrothermal method and characterized by single-crystal X-ray diffraction, elemental analyses, IR and solid-state diffuse-reflection spectra. 1 forms a 2D network with the point symbol of (4⁴·6²) and 2D → 2D polythreaded network. 2 constructs the 6-connected 3D network based on the [Cu₂(COO)₂] dimer with the point symbol of (4⁴·6¹⁰·8). The energy band gaps (E_g) of 1 and 2 were 2.453 and 2.162 eV, respectively. 1 and 2 present high photocatalytic activity for the degradation of methylene blue under visible light irradiation.
- coordination polymer,
- structure,
- 3D network,
- photocatalysis,
- 1, 4-bis(2-methyl-imidazol-1-yl)butane
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