Citation: Zhi-Qiang WANG, Xun PAN, Yan-Lei LU, Ying-Yu LI, Yu-Ping YANG, Xiu-Lan XIN, Qiong-Hua JIN. Crystal Structures, Terahertz Spectra and Dye Adsorption Performance of Three Lanthanide-bisphosphonate Complexes Containing Keggin Polyoxometalates[J]. Chinese Journal of Structural Chemistry, ;2021, 40(5): 615-624. doi: 10.14102/j.cnki.0254–5861.2011–2987 shu

Crystal Structures, Terahertz Spectra and Dye Adsorption Performance of Three Lanthanide-bisphosphonate Complexes Containing Keggin Polyoxometalates

Zhi-Qiang WANG ^{a, b} ,
Xun PAN ^a ,
Yan-Lei LU ^a ,
Ying-Yu LI ^a ,
Yu-Ping YANG ^c ,
Xiu-Lan XIN ^a ,
Qiong-Hua JIN ^{a, b,,}

a.
Department of Chemistry, Capital Normal University, Beijing 100048, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
School of Science, Minzu University of China, Beijing 100081, China

Corresponding author: Qiong-Hua JIN, jinqh@cnu.edu.cn
Received Date: 21 September 2020
Accepted Date: 25 February 2021

Figures(9)

Three lanthanide complexes [LnL₃(H₂O)]PMo₁₂O₄₀·CH₃CN (Ln = Dy³⁺ for 1, Ln = Ho³⁺ for 2, Ln = Lu³⁺ for 3, L = tetraethyl ethylenediphosphonate) have been synthesized, and characterized by single-crystal X-ray diffraction, elemental analysis, IR, PXRD, thermogravimetric analysis and terahertz time-domain spectroscopy (THz-TDS). Structural analysis results show that they have the same coordination mode and similar steric structures. Complexes 1~3 all crystallize in the monoclinic crystal system with space group P2₁/c. The centered Ln(Ⅲ) obtained a seven-coordinated mononuclear structure by linking with three tetraethyl ethylenediphosphonates and one water molecule, resulting in a three-dimensional supramolecular structure through hydrogen bonding. The three complexes have good adsorption properties for rhodamine B (RhB) in powder state. Moreover, terahertz time-domain spectroscopy (THz-TDS) was applied to represent the structures of complexes and ligands, which will provide useful information for establishing bridge between THz and complex structure in coordination chemistry.
- lanthanide complexes,
- POMS,
- tetraethyl ethylenediphosphonate,
- structure,
- terahertz time-domain spectroscopy (THz-TDS)
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