Citation: Xiao-Jing LIU, E LIU, Zhuang-Yu LI, Fang-Fang JIAN. Synthesis, Crystal Structure and Property Studies on a Bipyridine Adduct of Nickel Xanthogenate[J]. Chinese Journal of Structural Chemistry, ;2021, 40(5): 588-594. doi: 10.14102/j.cnki.0254–5861.2011–2986 shu

Synthesis, Crystal Structure and Property Studies on a Bipyridine Adduct of Nickel Xanthogenate

Xiao-Jing LIU ^a ,
E LIU ^{a, b} ,
Zhuang-Yu LI ^a ,
Fang-Fang JIAN ^{a, c,,}

a.
School of Chemical Engineering and Pharmaceutics, Henan University of Science and Technology, Luoyang 471000, China
b.
School of Materials Science and Engineering & Center for Molecular Engineering and Applied Chemistry, Anhui University of Technology, Maanshan 243002, China
c.
Heke University Renewable Energy Co. LTD, Luoyang 471000, China

Corresponding author: Fang-Fang JIAN, ffj2013@163.com
Received Date: 21 September 2020
Accepted Date: 25 November 2020

Figures(8)

A new coordination polymer containing mixed ligands, namely [Ni(S₂COiBu)₂(DBPMF)·(CHCl₃)]_∞ (DBPMF = 2, 7-dibromo-9, 9-(4-pyridylmethyl)fluorine), has been synthesized and structurally characterized by elemental analysis and single-crystal X-ray diffractions. X-ray structural analysis reveals that each Ni atom is coordinated by two isobutyl xanthogenate molecules and two nitrogen atoms from two DBPMF ligands to form octahedral coordination geometry. DBPMF acts as a bridge to form a coordination polymer. Fluorescence property of this coordination polymer displays a broad emission band at λ = 413 nm. Thermal analysis shows that the solvent molecule CHCl₃ can be stabilized in the crystal structure until 140 ℃.
- DBPMF,
- coordination polymer,
- xantghogenate,
- crystal structure,
- fluorescence
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