Citation: Ying-Qun YANG, Yun-Fei KUANG, Xiao-Ming ZHU. Synthesis and Fluorescent and Magnetic Properties of a New Europium Complex Eu(C₂₀H₁₄O₃N)₃(2, 2'-bipy)(H₂O)·H₂O[J]. Chinese Journal of Structural Chemistry, ;2021, 40(4): 507-511. doi: 10.14102/j.cnki.0254–5861.2011–2969 shu

Synthesis and Fluorescent and Magnetic Properties of a New Europium Complex Eu(C₂₀H₁₄O₃N)₃(2, 2'-bipy)(H₂O)·H₂O

Ying-Qun YANG ^{a, b,,} ,
Yun-Fei KUANG ^{a, b} ,
Xiao-Ming ZHU ^{a, b,,}

a.
Key Laboratory of Functional Metal-organic Compounds of Hunan Province & Key Laboratory of Functional Organometallic Materials of Hunan Province College, Hengyang 421008, China
b.
Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China

Corresponding author: Ying-Qun YANG, yingqunyq@163.com Xiao-Ming ZHU, zxmhnhy@163.com
Received Date: 24 August 2020
Accepted Date: 10 October 2020

Fund Project: the Foundation of Key Laboratory of Functional Metal-organic Compounds of Hunan Province MO20K05

Figures(4)

A new europium(Ⅲ) complex Eu(C₂₀H₁₄O₃N)₃(2, 2'-bipy)(H₂O)·H₂O has been synthesized with 2-diphenylanine carbonyl benzoic acid and 2, 2'-bipyridine as ligands. Crystal data for the complex are as follows: triclinic, space group P\begin{document}$ \overline 1 $\end{document}, a = 11.3334(5), b = 16.0883(7), c = 17.0116(8) Å, α = 70.411(4)º, β = 82.435(4)º, γ = 85.095(4)º, V = 2894.0(2) Å³, D_c = 1.484 g/cm³, Z = 2, μ = 1.15 mm^-1, F(000) = 1320 and the final R= 0.0447 and wR = 0.0578. The Eu(Ⅲ) ion is coordinated by nine atoms to give a monocapped square antiprism coordination geometry. The complex shows two intense fluorescence emission bands arising from the transitions of Eu³⁺: ⁵D₀ → ⁷F₁ (592 nm) and ⁵D₀ → ⁷F₂ (616 nm), respectively. Also reported is the magnetic property of the complex. The complex exhibits antiferromagnetism in the temperature range of 300~2 K.
- europium(Ⅲ) complex,
- crystal structure,
- fluorescent and magnetic properties
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Synthesis and Fluorescent and Magnetic Properties of a New Europium Complex Eu(C20H14O3N)3(2, 2'-bipy)(H2O)·H2O

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Fluorescent and Magnetic Properties of a New Europium Complex Eu(C₂₀H₁₄O₃N)₃(2, 2'-bipy)(H₂O)·H₂O