Citation: Hai-Hui CHEN, Xiu-Guang YI, Chang-Wang PAN, Ji-Wu WEN, Cong ZHANG. Hydrothermal Preparation and Photophysical Properties of a Ni(Ⅱ) Complex Containing Quinoline Derivative and Phen Ligands[J]. Chinese Journal of Structural Chemistry, ;2021, 40(4): 501-506. doi: 10.14102/j.cnki.0254–5861.2011–2951 shu

Hydrothermal Preparation and Photophysical Properties of a Ni(Ⅱ) Complex Containing Quinoline Derivative and Phen Ligands

School of Chemistry and Chemical Engineering, Jinggangshan University, Ji'an, Jiangxi 343009, China

Corresponding author: Xiu-Guang YI, jayxgggchem@163.com
Received Date: 3 August 2020
Accepted Date: 24 September 2020

Fund Project: the financial support of the National Natural Science Foundation 51363009Jiangxi Provincial Natural Science Foundation 20202BAB204003Jiangxi Provincial Department of Education's Item of Science and Technology GJJ190550Doctoral Research Startup Foundation of Jinggangshan University JZB1905

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A novel nickel complex [Ni₂L₂Phen₃]·3H₂O (HL = 3-hydroxy-2-methylquioline-4-carboxylic acid) has been synthesized by a hydrothermal approach and is structurally determined by single-crystal X-ray diffraction. The title complex crystallizes in triclinic space group P\begin{document}$ \overline 1 $\end{document}. Crystal data for the title complex: C₅₈H₄₄N₈Ni₂O₉, M_r = 1108.35, a = 11.8648(4), b = 12.7369(4), c = 17.0728(5) Å, α = 97.694(3), β = 96.702(2), γ = 99.566(3)°, V = 2495.66(14) Å³, Z = 2, T = 293(2) K, D_c = 1.475 g/cm³, μ(MoKα) = 0.824 mm^–1, F(000) = 1140, R = 0.0757, wR = 0.2129 and GOF = 1.017. The nickel ions are surrounded by five oxygen and six nitrogen atoms to yield two slightly distorted octahedral geometries. Solid-state photoluminescence spectrum reveals that it shows blue purple emission. Solid-state UV/Vis diffuse reflectance spectroscopy exhibits that it has an optical band gap of 1.702 eV.
- hydrothermal preparation,
- crystal structure,
- photophysical properties
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