Citation: Chang-Zheng TU, Yu-Ting YANG, Fan WANG, Jian-Ling WANG, Hong-Ju YIN, Fei-Xiang CHENG. Two Coordination Polymers Based on Pamoic Acid and (1,4-Bis(imidazol-1-yl)-butane: Synthesis, Structures and Properties[J]. Chinese Journal of Structural Chemistry, ;2021, 40(4): 473-481. doi: 10.14102/j.cnki.0254–5861.2011–2946 shu

Two Coordination Polymers Based on Pamoic Acid and (1,4-Bis(imidazol-1-yl)-butane: Synthesis, Structures and Properties

College of Chemistry and Environmental Science, Qujing Normal University, Qujing 655011, China

Corresponding author: Fei-Xiang CHENG, chengfx2019@163.com
Received Date: 27 July 2020
Accepted Date: 14 October 2020

Fund Project: the Shanghai Key Laboratory of Rare Earth Functional Materials, the project of teaching quality and teaching reform of Yunnan Province 2073010023the National Teaching Quality and Teaching Reform Project 201810684012the National Natural Science Foundation of China 81601602

Figures(10)

Two mixed-ligand compounds, namely [Mn₂(bimb)(PA)₂]_n (1) and [Zn(bimb)(PA)]_n (2) (H₂PA = pamoic acid, bimb = 1,4-bis(imidazol-1-yl)-butane) have been synthesized under the same solvothermal conditions. Compound 1 can be described as (4,4) topology based on the 4-connected [Mn₂(COO)₄] paddle-wheel units, which contains both rotaxane- and catenane-like motifs. For 2, the 2D wavy-like network interlocked with each other and resulted in a 2-fold interpenetrated 2D → 3D architecture. The structural differences of the two compounds are mainly due to the differences of metal ions and coordination modes of the PA^2- ligand. In addition, the magnetism and photoluminescent properties of them have also been explored.
- crystal structures,
- pamoic acid,
- luminescence,
- magnetic properties
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