Citation: Yue-Jiao ZHANG, Petar M RADJENOVIC, Jian-Feng LI. Shell-isolated Nanoparticle-enhanced Raman Spectroscopy towards In-Situ Investigating of Interfacial Structure[J]. Chinese Journal of Structural Chemistry, ;2020, 39(8): 1372-1376. doi: 10.14102/j.cnki.0254–5861.2011–2918 shu

Shell-isolated Nanoparticle-enhanced Raman Spectroscopy towards In-Situ Investigating of Interfacial Structure

College of Energy, State Key Laboratory for Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

Corresponding author: Jian-Feng LI, li@xmu.edu.cn
Received Date: 23 June 2020
Accepted Date: 15 July 2020

Fund Project: the National Natural Science Foundation of China 21925404the National Natural Science Foundation of China 21775127Science and Technology Planning Project of Fujian Province 2019Y4001

Figures(3)

Since the discovery of surface-enhanced Raman spectroscopy (SERS), it has been rapidly applied to the in situ study of electrochemical interfaces. Shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS) stands out as one of the most powerful tools for the in situ study of interfacial structures, especially on well-defined single crystal surface. This perspective paper focuses on the study of interfacial structures with the SHINERS technique, including the electronic structure of heterogeneous metal surfaces, and the detection of molecules absorbed on the surface, as well as intermediate species, during electrochemical reactions. Finally, we present an outlook on future research and development of SHINERS for studying interfacial structures.
- SHINERS,
- single-crystal electrode,
- spectroelectrochemistry,
- interface structure,
- in-situ
1. [1]
  Hoshi, N.; Suzuki, T.; Hori, Y. Step density dependence of CO₂ reduction rate on Pt(S)-[n(111) × (111)] single crystal electrodes. Electrochim. Acta 1996, 41, 1647–1653. doi: 10.1016/0013-4686(95)00418-1
2. [2]
  Maciá, M. D.; Campiña, J. M.; Herrero, E.; Feliu, J. M. On the kinetics of oxygen reduction on platinum stepped surfaces in acidic media. J. Electroanal. Chem. 2004, 564, 141–150. doi: 10.1016/j.jelechem.2003.09.035
3. [3]
  Schouten, K. J. P.; Qin, Z.; Pérez Gallent, E.; Koper, M. T. M. Two pathways for the formation of ethylene in CO reduction on single-crystal copper electrodes. J. Am. Chem. Soc. 2012, 134, 9864–9867. doi: 10.1021/ja302668n
4. [4]
  Gong, J.; Bao, X. Fundamental insights into interfacial catalysis. Chem. Soc. Rev. 2017, 46, 1770–1771. doi: 10.1039/C7CS90022H
5. [5]
  Fleischmann, M.; Hendra, P. J.; McQuillan, A. J. Raman spectra of pyridine adsorbed at a silver electrode. Chem. Phys. Lett. 1974, 26, 163–166. doi: 10.1016/0009-2614(74)85388-1
6. [6]
  Jeanmaire, D. L.; Van Duyne, R. P. Surface Raman spectroelectrochemistry. J. Electroanal. Chem. 1977, 84, 1–20. doi: 10.1016/S0022-0728(77)80224-6
7. [7]
  Li, J. F.; Zhang, Y. J.; Ding, S. Y.; Panneerselvam, R.; Tian, Z. Q. Core-shell nanoparticle-enhanced Raman spectroscopy. Chem. Rev. 2017, 117, 5002–5069. doi: 10.1021/acs.chemrev.6b00596
8. [8]
  Wu, D. Y.; Li, J. F.; Ren, B.; Tian, Z. Q. Electrochemical surface-enhanced Raman spectroscopy of nanostructures. Chem. Soc. Rev. 2008, 37, 1025–1041. doi: 10.1039/b707872m
9. [9]
  Lal, S.; Grady, N. K.; Kundu, J.; Levin, C. S.; Lassiter, J. B.; Halas, N. J. Tailoring plasmonic substrates for surface enhanced spectroscopies. Chem. Soc. Rev. 2008, 37, 898–911. doi: 10.1039/b705969h
10. [10]
  Lei, J.; Ju, H. Signal amplification using functional nanomaterials for biosensing. Chem. Soc. Rev. 2012, 41, 2122–2134. doi: 10.1039/c1cs15274b
11. [11]
  Wang, Y.; Yan, B.; Chen, L. Tags: novel optical nanoprobes for bioanalysis. Chem. Rev. 2013, 113, 1391–1428. doi: 10.1021/cr300120g
12. [12]
  Lane, L. A.; Qian, X. M.; Nie, S. M. SERS nanoparticles in medicine: from label-free detection to spectroscopic tagging. Chem. Rev. 2015, 115, 10489–10529. doi: 10.1021/acs.chemrev.5b00265
13. [13]
  Tian, Z. Q.; Ren, B.; Li, J. F.; Yang, Z. L. Expanding generality of surface-enhanced Raman spectroscopy with borrowing SERS activity strategy. Chem. Commun. 2007, 3514–3534.
14. [14]
  Li, J. F.; Huang, Y. F.; Ding, Y.; Yang, Z. L.; Li, S. B.; Zhou, X. S.; Fan, F. R.; Zhang, W.; Zhou, Z. Y.; Wu, D. Y.; Ren, B.; Wang, Z. L.; Tian, Z. Q. Shell-isolated nanoparticle-enhanced Raman spectroscopy. Nature 2010, 464, 392–395. doi: 10.1038/nature08907
15. [15]
  Zhang, H.; Duan, S.; Radjenovic, P. M.; Tian, Z. Q.; Li, J. F. Core-shell nanostructure-enhanced Raman spectroscopy for surface catalysis. Acc. Chem. Res. 2020, 53, 729–739. doi: 10.1021/acs.accounts.9b00545
16. [16]
  Fang, P. P.; Lu, X. H.; Liu, H.; Tong, Y. X. Applications of shell-isolated nanoparticles in surface-enhanced Raman spectroscopy and fluorescence. Trac-Trend. Anal. Chem. 2015, 66, 103–117. doi: 10.1016/j.trac.2014.11.015
17. [17]
  Greeley, J.; Jaramillo, T. F.; Bonde, J.; Chorkendorff, I.; Nørskov, J. K. Computational high-throughput screening of electrocatalytic materials for hydrogen evolution. Nat. Mater. 2006, 5, 909–913. doi: 10.1038/nmat1752
18. [18]
  Housmans, T. H. M.; Wonders, A. H.; Koper, M. T. M. Structure sensitivity of methanol electrooxidation pathways on platinum: an on-line electrochemical mass spectrometry study. J. Phys. Chem. B 2006, 110, 10021–10031. doi: 10.1021/jp055949s
19. [19]
  Christensen, C. H.; Nørskov, J. K. A molecular view of heterogeneous catalysis. J. Chem. Phys. 2008, 128, 182503. doi: 10.1063/1.2839299
20. [20]
  Zhang, Y. J.; Li, S. B.; Duan, S.; Lu, B. A.; Yang, J.; Panneerselvam, R.; Li, C. Y.; Fang, P. P.; Zhou, Z. Y.; Phillips, D. L.; Li, J. F.; Tian, Z. Q. Probing the electronic structure of heterogeneous metal interfaces by transition metal shelled gold nanoparticle-enhanced Raman spectroscopy. J. Phys. Chem. C 2016, 120, 20684–20691. doi: 10.1021/acs.jpcc.6b01879
21. [21]
  Stamenkovic, V. R.; Fowler, B.; Mun, B. S.; Wang, G.; Ross, P. N.; Lucas, C. A.; Marković, N. M. Improved oxygen reduction activity on Pt₃Ni(111) via increased surface site availability. Science 2007, 315, 493–497. doi: 10.1126/science.1135941
22. [22]
  Li, J. F.; Zhang, Y. J.; Rudnev, A. V.; Anema, J. R.; Li, S. B.; Hong, W. J.; Rajapandiyan, P.; Lipkowski, J.; Wandlowski, T.; Tian, Z. Q. Electrochemical shell-isolated nanoparticle-enhanced Raman spectroscopy: correlating structural information and adsorption processes of pyridine at the Au(hkl) single crystal/solution interface. J. Am. Chem. Soc. 2015, 137, 2400–2408. doi: 10.1021/ja513263j
23. [23]
  Wen, B. Y.; Jin, X.; Li, Y.; Wang, Y. H.; Li, C. Y.; Liang, M. M.; Panneerselvam, R.; Xu, Q. C.; Wu, D. Y.; Yang, Z. L.; Li, J. F.; Tian, Z. Q. Shell-isolated nanoparticle-enhanced Raman spectroscopy study of the adsorption behaviour of DNA bases on Au(111) electrode surfaces. Analyst 2016, 141, 3731–3736. doi: 10.1039/C6AN00180G
24. [24]
  Zhang, S. P.; Lin, J. S.; Lin, R. K.; Radjenovic, P. M.; Yang, W. M.; Xu, J.; Dong, J. C.; Yang, Z. L.; Hang, W.; Tian, Z. Q.; Li, J. F. In situ Raman study of the photoinduced behavior of dye molecules on TiO₂(hkl) single crystal surfaces. Chem. Sci. 2020, 11, 6431–6435. doi: 10.1039/D0SC00588F
25. [25]
  Nørskov, J. K.; Rossmeisl, J.; Logadottir, A.; Lindqvist, L.; Kitchin, J. R.; Bligaard, T.; Jónsson, H. Origin of the overpotential for oxygen reduction at a fuel-cell cathode. J. Phys. Chem. B 2004, 108, 17886–17892. doi: 10.1021/jp047349j
26. [26]
  Ledezma-Yanez, I.; Wallace, W. D. Z.; Sebastián-Pascual, P.; Climent, V.; Feliu, J. M.; Koper, M. T. M. Interfacial water reorganization as a pH-dependent descriptor of the hydrogen evolution rate on platinum electrodes. Nat. Energy 2017, 2, 17031. doi: 10.1038/nenergy.2017.31
27. [27]
  Li, C. Y.; Le, J. B.; Wang, Y. H.; Chen, S.; Yang, Z. L.; Li, J. F.; Cheng, J.; Tian, Z. Q. In situ probing electrified interfacial water structures at atomically flat surfaces. Nat. Mater. 2019, 18, 697–701. doi: 10.1038/s41563-019-0356-x
28. [28]
  Wang, J.; Dong, J. C.; Yang, J.; Wang, Y.; Zhang, C. J.; Xu, M. M.; Mao, B. W.; Yao, J. L.; Li, J. F.; Tian, Z. Q. In situ SERS and SHINERS study of electrochemical hydrogenation of p-ethynylaniline in nonaqueous solvents. Electrochem. Commun. 2017, 78, 16–20. doi: 10.1016/j.elecom.2017.03.015
29. [29]
  Dong, J. C.; Zhang, X. G.; Briega-Martos, V.; Jin, X.; Yang, J.; Chen, S.; Yang, Z. L.; Wu, D. Y.; Feliu, J. M.; Williams, C. T.; Tian, Z. Q.; Li, J. F. In situ Raman spectroscopic evidence for oxygen reduction reaction intermediates at platinum single-crystal surfaces. Nat. Energy 2018, 4, 60–67. doi: 10.1038/s41560-018-0292-z
30. [30]
  Bodappa, N.; Su, M.; Zhao, Y.; Le, J. B.; Yang, W. M.; Radjenovic, P.; Dong, J. C.; Cheng, J.; Tian, Z. Q.; Li, J. F. Early stages of electrochemical oxidation of Cu(111) and polycrystalline Cu surfaces revealed by in situ Raman spectroscopy. J. Am. Chem. Soc. 2019, 141, 12192–12196. doi: 10.1021/jacs.9b04638
31. [31]
  Wang, Y. H.; Wei, J.; Radjenovic, P.; Tian, Z. Q.; Li, J. F. In situ analysis of surface catalytic reactions using shell-isolated nanoparticle-enhanced Raman spectroscopy. Anal. Chem. 2019, 91, 1675–1685. doi: 10.1021/acs.analchem.8b05499
32. [32]
  Dong, J. C.; Su, M.; Briega-Martos, V.; Li, L.; Le, J. B.; Radjenovic, P.; Zhou, X. S.; Feliu, J. M.; Tian, Z. Q.; Li, J. F. Direct in situ Raman spectroscopic evidence of oxygen reduction reaction intermediates at high-index Pt(hkl) surfaces. J. Am. Chem. Soc. 2020, 142, 715–719. doi: 10.1021/jacs.9b12803
1. [1]
  Wenli Xu , Yingzhao Zhang , Rui Wang , Chenyang Liu , Jialin Liu , Xiangyu Huo , Xinying Liu , He Zhang , Jianxu Ding . In-situ passivating surface defects of ultra-thin MAPbBr3 perovskite single crystal films for high performance photodetectors. Chinese Journal of Structural Chemistry, 2025, 44(1): 100454-100454. doi: 10.1016/j.cjsc.2024.100454
2. [2]
  Yaping Wang , Pengcheng Yuan , Zeyuan Xu , Xiong-Xiong Liu , Shengfa Feng , Mufan Cao , Chen Cao , Xiaoqiang Wang , Long Pan , Zheng-Ming Sun . Ti₃C₂T_x MXene in-situ transformed Li₂TiO₃ interface layer enabling 4.5 V-LiCoO₂/sulfide all-solid-state lithium batteries with superior rate capability and cyclability. Chinese Chemical Letters, 2024, 35(6): 108776-. doi: 10.1016/j.cclet.2023.108776
3. [3]
  Zhipeng Wan , Hao Xu , Peng Wu . Selective oxidation using in-situ generated hydrogen peroxide over titanosilicates. Chinese Journal of Structural Chemistry, 2024, 43(6): 100298-100298. doi: 10.1016/j.cjsc.2024.100298
4. [4]
  Guan-Nan Xing , Di-Ye Wei , Hua Zhang , Zhong-Qun Tian , Jian-Feng Li . Pd-based nanocatalysts for oxygen reduction reaction: Preparation, performance, and in-situ characterization. Chinese Journal of Structural Chemistry, 2023, 42(11): 100021-100021. doi: 10.1016/j.cjsc.2023.100021
5. [5]
  Peng Jia , Yunna Guo , Dongliang Chen , Xuedong Zhang , Jingming Yao , Jianguo Lu , Liqiang Zhang . In-situ imaging electrocatalysis in a solid-state Li-O₂ battery with CuSe nanosheets as air cathode. Chinese Chemical Letters, 2024, 35(5): 108624-. doi: 10.1016/j.cclet.2023.108624
6. [6]
  Abiduweili Sikandaier , Yukun Zhu , Dongjiang Yang . In-situ decorated cobalt phosphide cocatalyst on Hittorf's phosphorus triggering efficient photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2024, 43(2): 100242-100242. doi: 10.1016/j.cjsc.2024.100242
7. [7]
  Yan-Li Li , Zhi-Ming Li , Kai-Kai Wang , Xiao-Long He . Beyond 1,4-addition of in-situ generated (aza-)quinone methides and indole imine methides. Chinese Chemical Letters, 2024, 35(7): 109322-. doi: 10.1016/j.cclet.2023.109322
8. [8]
  Wenhao Feng , Chunli Liu , Zheng Liu , Huan Pang . In-situ growth of N-doped graphene-like carbon/MOF nanocomposites for high-performance supercapacitor. Chinese Chemical Letters, 2024, 35(12): 109552-. doi: 10.1016/j.cclet.2024.109552
9. [9]
  Changyuan Bao , Yunpeng Jiang , Haoyin Zhong , Huaizheng Ren , Junhui Wang , Binbin Liu , Qi Zhao , Fan Jin , Yan Meng Chong , Jianguo Sun , Fei Wang , Bo Wang , Ximeng Liu , Dianlong Wang , John Wang . Synergizing 3D-printed structure and sodiophilic interface enables highly efficient sodium metal anodes. Chinese Chemical Letters, 2024, 35(11): 109353-. doi: 10.1016/j.cclet.2023.109353
10. [10]
  Zhili Li , Qijun Wo , Dongdong Huang , Dezhong Zhou , Lei Guo , Yeqing Mao . Improving gene transfection efficiency of highly branched poly(β-amino ester)s through the in-situ conversion of inactive terminal groups. Chinese Chemical Letters, 2024, 35(8): 109737-. doi: 10.1016/j.cclet.2024.109737
11. [11]
  Hao Lv , Zhi Li , Peng Yin , Ping Wan , Mingshan Zhu . Recent progress on non-metallic carbon nitride for the photosynthesis of H₂O₂: Mechanism, modification and in-situ applications. Chinese Chemical Letters, 2025, 36(1): 110457-. doi: 10.1016/j.cclet.2024.110457
12. [12]
  Bin Feng , Tao Long , Ruotong Li , Yuan-Li Ding . Rationally constructing metallic Sn-ZnO heterostructure via in-situ Mn doping for high-rate Na-ion batteries. Chinese Chemical Letters, 2025, 36(2): 110273-. doi: 10.1016/j.cclet.2024.110273
13. [13]
  Yan-Jiang Li , Shu-Lei Chou , Yao Xiao . Detecting dynamic structural evolution based on in-situ high-energy X-ray diffraction technology for sodium layered oxide cathodes. Chinese Chemical Letters, 2025, 36(2): 110389-. doi: 10.1016/j.cclet.2024.110389
14. [14]
  Bei Li , Zhaoke Zheng . In situ monitoring of the spatial distribution of oxygen vacancies at the single-particle level. Chinese Journal of Structural Chemistry, 2024, 43(10): 100331-100331. doi: 10.1016/j.cjsc.2024.100331
15. [15]
  Maosen Xu , Pengfei Zhu , Qinghong Cai , Meichun Bu , Chenghua Zhang , Hong Wu , Youzhou He , Min Fu , Siqi Li , Xingyan Liu . In-situ fabrication of TiO₂/NH₂−MIL-125(Ti) via MOF-driven strategy to promote efficient interfacial effects for enhancing photocatalytic NO removal activity. Chinese Chemical Letters, 2024, 35(10): 109524-. doi: 10.1016/j.cclet.2024.109524
16. [16]
  Xiaofen GUAN , Yating LIU , Jia LI , Yiwen HU , Haiyuan DING , Yuanjing SHI , Zhiqiang WANG , Wenmin WANG . Synthesis, crystal structure, and DNA-binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2486-2496. doi: 10.11862/CJIC.20240122
17. [17]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
18. [18]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
19. [19]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
20. [20]
  Xi Tang , Chunlei Zhu , Yulu Yang , Shihan Qi , Mengqiu Cai , Abdullah N. Alodhayb , Jianmin Ma . Additive regulating Li⁺ solvation structure to construct dual LiF−rich electrode electrolyte interphases for sustaining 4.6 V Li||LiCoO₂ batteries. Chinese Chemical Letters, 2024, 35(12): 110014-. doi: 10.1016/j.cclet.2024.110014

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(267)
HTML views(12)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142