Citation: Bing-Kai ZHANG, Zeng-Zhu LI, Qiong LI, Zhan LIN, Jing LIU, Feng PAN. Insights into the H₂O/V₂O₅ Interface Structure for Optimizing Water-splitting[J]. Chinese Journal of Structural Chemistry, ;2020, 39(2): 189-199. doi: 10.14102/j.cnki.0254–5861.2011–2748 shu

Insights into the H₂O/V₂O₅ Interface Structure for Optimizing Water-splitting

Bing-Kai ZHANG ^{a, b} ,
Zeng-Zhu LI ^a ,
Qiong LI ^a ,
Zhan LIN ^a,, ,
Jing LIU ^c,, ,
Feng PAN ^b,,

a.
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China
b.
School of Advanced Materials, Peking University, Shenzhen Graduate School, Shenzhen 518055, China
c.
State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China

Corresponding author: Zhan LIN, zhanlin@gdut.edu.cn Jing LIU, liujing@mail.hust.edu.cn Feng PAN, panfeng@pkusz.edu.cn
Received Date: 25 January 2020
Accepted Date: 3 February 2020

Fund Project: startup R&D funding from the One-Hundred Young Talents Program of Guangdong University of Technology 22041331901National Key R&D Program of China 2016YFB0700600Soft Science Research Project of Guangdong Province 2017B030301013Shenzhen Science and Technology Research Grant ZDSYS201707281026184

Figures(10)

The interaction of water (H₂O) with metal oxide surfaces is of fundamental importance to various fields of science, ranging from batteries to catalysis. In particular, vanadium pentoxide (V₂O₅) has been widely used as electrode materials for aqueous-battery and catalysts. Herein, theoretical (density functional theory) study gives atomic-scale insights into water monolayers in V₂O₅ and single-molecule adsorption and dissociation at three low-index surfaces and oxygen-vacancy V₂O₅(001) surface. The H₂O/V₂O₅ interface structure was identified. The results show that H₂O is adsorbed on the stoichiometric V₂O₅(001) surface with physisorption mechanism, and the dissociation hardly occurs. Water adsorbs as an intact monomer with a computed binding energy of 0.75 eV. The formation of ordered water overlayers has been observed on V₂O₅(001) surface, suggesting a locally ordered superstructure of molecular water. The molecular H₂O adsorption on oxygen-vacancy V₂O₅(001) surface is stronger than that on the stoichiometric V₂O₅(001) surface, and H₂O can undergo dissociative chemisorption to form a surface hydroxyl group and a H adatom. V₂O₅ can take the oxygen from H₂O, which is consistent with the experimental results.
- V₂O₅,
- interface structure,
- adsosption,
- dissociation,
- density functional calculations
References
1. [1]
  Verdaguer, A.; Sacha, G. M.; Bluhm, H.; Salmeron, M. Molecular structure of water at interfaces: wetting at the nanometer scale. Chem. Rev. 2006, 106, 1478–1510. doi: 10.1021/cr040376l
2. [2]
  Henderson, M. A. The interaction of water with solid surfaces: fundamental aspects revisited. Surf. Sci. Rep. 2002, 46, 1–308. doi: 10.1016/S0167-5729(01)00020-6
3. [3]
  Fujishima, A.; Honda, K. Electrochemical photolysis of water at a semiconductor electrode. Nature 1972, 238, 37–38. doi: 10.1038/238037a0
4. [4]
  Chen, X.; Wang, L.; Li, H.; Cheng, F.; Chen, J. Porous V₂O₅ nanofibers as cathode materials for rechargeable aqueous zinc-ion batteries. J. Energy Chem. 2019, 38, 20–25. doi: 10.1016/j.jechem.2018.12.023
5. [5]
  Geng, H.; Cheng, M.; Wang, B.; Yang, Y.; Zhang, Y.; Li, C. C. Electronic structure regulation of layered vanadium oxide via interlayer doping strategy toward superior high-rate and low-temperature zinc-ion batteries. Adv. Funct. Mater. 2019, 1907684.
6. [6]
  Zhang, B.; Liu, J.; Dai, G.; Chang, M.; Zheng, C. Insights into the mechanism of heterogeneous mercury oxidation by HCl over V₂O₅/TiO₂ catalyst: periodic density functional theory study. P. Combust. Inst. 2015, 35, 2855–2865. doi: 10.1016/j.proci.2014.06.051
7. [7]
  Busca, G.; Ramis, G.; Lorenzelli, V. FT-IR study of the surface properties of polycrystalline vanadia. J. Mol. Catal. 1989, 50, 231–240. doi: 10.1016/0304-5102(89)85066-7
8. [8]
  Topsøe, N. Y. Characterization of the nature of surface sites on vanadia-titania catalysts by FTIR. J. Catal. 1991, 128, 499–511. doi: 10.1016/0021-9517(91)90307-P
9. [9]
  Costa, A. D.; Mathieu, C.; Barbaux, Y.; Poelman, H.; Dalmai-Vennik, G.; Fiermans, L. Observation of the V₂O₅(001) surface using ambient atomic force microscopy. Surf. Sci. 1997, 370, 339–344. doi: 10.1016/S0039-6028(96)00956-9
10. [10]
  Moshfegh, A. Z.; Ignatiev, A. A temperature programmed desorption study of the H₂O/V₂O₅ system. Surf. Sci. 1992, 275, L650–L654. doi: 10.1016/0039-6028(92)90636-K
11. [11]
  Sadovskaya, E. M.; Goncharov, V. B.; Gulyaeva, Y. K.; Popova, G. Y.; Andrushkevich, T. V. Kinetics of the H₂¹⁸O/H₂¹⁶O isotope exchange over vanadia-titania catalyst. J. Mol. Catal. A: Chem. 2010, 316, 118–125. doi: 10.1016/j.molcata.2009.10.009
12. [12]
  Lee, E. L.; Wachs, I. E. In situ raman spectroscopy of SiO₂-supported transition metal oxide catalysts: an isotopic ¹⁸O−¹⁶O exchange study. J. Phys. Chem. C 2008, 112, 6487–6498. doi: 10.1021/jp076485w
13. [13]
  Ma, J. B.; Zhao, Y. X.; He, S. G.; Ding, X. L. Experimental and theoretical study of the reactions between vanadium oxide cluster cations and water. J. Phys. Chem. A 2012, 116, 2049–2054. doi: 10.1021/jp300279u
14. [14]
  Goclon, J.; Grybos, R.; Witko, M.; Hafner, J. Oxygen vacancy formation on clean and hydroxylated low-index V₂O₅ surfaces: a density functional investigation. Phys. Rev. B 2009, 79, 075439. doi: 10.1103/PhysRevB.79.075439
15. [15]
  Yin, X.; Fahmi, A.; Han, H.; Endou, A.; Ammal, S. S. C.; Kubo, M.; Teraishi, K.; Miyamoto, A. Adsorption of H₂O on the V₂O₅(010) surface studied by periodic density functional calculations. J. Phys. Chem. B 1999, 103, 3218–3224. doi: 10.1021/jp9833395
16. [16]
  Hejduk, P.; Szaleniec, M.; Witko, M. Molecular and dissociative adsorption of water at low-index V₂O₅ surfaces: DFT studies using cluster surface models. J. Mol. Catal. A: Chem. 2010, 325, 98–104. doi: 10.1016/j.molcata.2010.04.004
17. [17]
  Segall, M. D.; Lindan, P. J. D.; Probert, M. J.; Pickard, C. J.; Hasnip, P. J.; Clark, S. J.; Payne, M. C. First-principles simulation: ideas, illustrations and the CASTEP code. J. Phys. : Condens. Matter. 2002, 14, 2717–2744. doi: 10.1088/0953-8984/14/11/301
18. [18]
  Perdew, J. P.; Burke, K.; Ernzerhof, M. Generalized gradient approximation made simple. Phys. Rev. Lett. 1996, 77, 3865–3868. doi: 10.1103/PhysRevLett.77.3865
19. [19]
  Perdew, J. P.; Burke, K.; Wang, Y. Generalized gradient approximation for the exchange-correlation hole of a many-electron system. Phys. Rev. B 1996, 54, 16533–16539. doi: 10.1103/PhysRevB.54.16533
20. [20]
  Vanderbilt, D. Soft self-consistent pseudopotentials in a generalized eigenvalue formalism. Phys. Rev. B 1990, 41, 7892–7895. doi: 10.1103/PhysRevB.41.7892
21. [21]
  Chadi, D. J. Special points for Brillouin-zone integrations. Phys. Rev. B 1977, 16, 1746–1747. doi: 10.1103/PhysRevB.16.1746
22. [22]
  Enjalbert, R.; Galy, J. A refinement of the structure of V₂O₅. Acta Crystallogr., Sect. C. 1986, 42, 1467–1469. doi: 10.1107/S0108270186091825
23. [23]
  Halgren, T. A.; Lipscomb, W. N. The synchronous-transit method for determining reaction pathways and locating molecular transition states. Chem. Phys. Lett. 1977, 49, 225–232. doi: 10.1016/0009-2614(77)80574-5
24. [24]
  Zhang, B.; Liu, J.; Shen, F. Heterogeneous mercury oxidation by HCl over CeO₂ catalyst: density functional theory study. J. Phys. Chem. C 2015, 119, 15047–15055. doi: 10.1021/acs.jpcc.5b00645
25. [25]
  Zhang, B.; Liu, J.; Yang, Y.; Chang, M. Oxidation mechanism of elemental mercury by HCl over MnO₂ catalyst: insights from first principles. Chem. Eng. J. 2015, 280, 354–362. doi: 10.1016/j.cej.2015.06.056
26. [26]
  Ranea, V. A.; Vicente, J. L.; Mola, E. E.; Uyewa Mananu, R. A theoretical study of water chemisorption on the (001) plane of V₂O₅. Surf. Sci. 1999, 442, 498–506. doi: 10.1016/S0039-6028(99)00874-2
27. [27]
  He, Y.; Tilocca, A.; Dulub, O.; Selloni, A.; Diebold, U. Local ordering and electronic signatures of submonolayer water on anatase TiO₂(101). Nat Mater. 2009, 8, 585–589. doi: 10.1038/nmat2466
28. [28]
  Goclon, J.; Grybos, R.; Witko, M.; Hafner, J. Relative stability of low-index V₂O₅ surfaces: a density functional investigation. J. Phys. : Condens. Matter. 2009, 21, 095008. doi: 10.1088/0953-8984/21/9/095008
1. [1]
  Verdaguer, A.; Sacha, G. M.; Bluhm, H.; Salmeron, M. Molecular structure of water at interfaces: wetting at the nanometer scale. Chem. Rev. 2006, 106, 1478–1510. doi: 10.1021/cr040376l
2. [2]
  Henderson, M. A. The interaction of water with solid surfaces: fundamental aspects revisited. Surf. Sci. Rep. 2002, 46, 1–308. doi: 10.1016/S0167-5729(01)00020-6
3. [3]
  Fujishima, A.; Honda, K. Electrochemical photolysis of water at a semiconductor electrode. Nature 1972, 238, 37–38. doi: 10.1038/238037a0
4. [4]
  Chen, X.; Wang, L.; Li, H.; Cheng, F.; Chen, J. Porous V₂O₅ nanofibers as cathode materials for rechargeable aqueous zinc-ion batteries. J. Energy Chem. 2019, 38, 20–25. doi: 10.1016/j.jechem.2018.12.023
5. [5]
  Geng, H.; Cheng, M.; Wang, B.; Yang, Y.; Zhang, Y.; Li, C. C. Electronic structure regulation of layered vanadium oxide via interlayer doping strategy toward superior high-rate and low-temperature zinc-ion batteries. Adv. Funct. Mater. 2019, 1907684.
6. [6]
  Zhang, B.; Liu, J.; Dai, G.; Chang, M.; Zheng, C. Insights into the mechanism of heterogeneous mercury oxidation by HCl over V₂O₅/TiO₂ catalyst: periodic density functional theory study. P. Combust. Inst. 2015, 35, 2855–2865. doi: 10.1016/j.proci.2014.06.051
7. [7]
  Busca, G.; Ramis, G.; Lorenzelli, V. FT-IR study of the surface properties of polycrystalline vanadia. J. Mol. Catal. 1989, 50, 231–240. doi: 10.1016/0304-5102(89)85066-7
8. [8]
  Topsøe, N. Y. Characterization of the nature of surface sites on vanadia-titania catalysts by FTIR. J. Catal. 1991, 128, 499–511. doi: 10.1016/0021-9517(91)90307-P
9. [9]
  Costa, A. D.; Mathieu, C.; Barbaux, Y.; Poelman, H.; Dalmai-Vennik, G.; Fiermans, L. Observation of the V₂O₅(001) surface using ambient atomic force microscopy. Surf. Sci. 1997, 370, 339–344. doi: 10.1016/S0039-6028(96)00956-9
10. [10]
  Moshfegh, A. Z.; Ignatiev, A. A temperature programmed desorption study of the H₂O/V₂O₅ system. Surf. Sci. 1992, 275, L650–L654. doi: 10.1016/0039-6028(92)90636-K
11. [11]
  Sadovskaya, E. M.; Goncharov, V. B.; Gulyaeva, Y. K.; Popova, G. Y.; Andrushkevich, T. V. Kinetics of the H₂¹⁸O/H₂¹⁶O isotope exchange over vanadia-titania catalyst. J. Mol. Catal. A: Chem. 2010, 316, 118–125. doi: 10.1016/j.molcata.2009.10.009
12. [12]
  Lee, E. L.; Wachs, I. E. In situ raman spectroscopy of SiO₂-supported transition metal oxide catalysts: an isotopic ¹⁸O−¹⁶O exchange study. J. Phys. Chem. C 2008, 112, 6487–6498. doi: 10.1021/jp076485w
13. [13]
  Ma, J. B.; Zhao, Y. X.; He, S. G.; Ding, X. L. Experimental and theoretical study of the reactions between vanadium oxide cluster cations and water. J. Phys. Chem. A 2012, 116, 2049–2054. doi: 10.1021/jp300279u
14. [14]
  Goclon, J.; Grybos, R.; Witko, M.; Hafner, J. Oxygen vacancy formation on clean and hydroxylated low-index V₂O₅ surfaces: a density functional investigation. Phys. Rev. B 2009, 79, 075439. doi: 10.1103/PhysRevB.79.075439
15. [15]
  Yin, X.; Fahmi, A.; Han, H.; Endou, A.; Ammal, S. S. C.; Kubo, M.; Teraishi, K.; Miyamoto, A. Adsorption of H₂O on the V₂O₅(010) surface studied by periodic density functional calculations. J. Phys. Chem. B 1999, 103, 3218–3224. doi: 10.1021/jp9833395
16. [16]
  Hejduk, P.; Szaleniec, M.; Witko, M. Molecular and dissociative adsorption of water at low-index V₂O₅ surfaces: DFT studies using cluster surface models. J. Mol. Catal. A: Chem. 2010, 325, 98–104. doi: 10.1016/j.molcata.2010.04.004
17. [17]
  Segall, M. D.; Lindan, P. J. D.; Probert, M. J.; Pickard, C. J.; Hasnip, P. J.; Clark, S. J.; Payne, M. C. First-principles simulation: ideas, illustrations and the CASTEP code. J. Phys. : Condens. Matter. 2002, 14, 2717–2744. doi: 10.1088/0953-8984/14/11/301
18. [18]
  Perdew, J. P.; Burke, K.; Ernzerhof, M. Generalized gradient approximation made simple. Phys. Rev. Lett. 1996, 77, 3865–3868. doi: 10.1103/PhysRevLett.77.3865
19. [19]
  Perdew, J. P.; Burke, K.; Wang, Y. Generalized gradient approximation for the exchange-correlation hole of a many-electron system. Phys. Rev. B 1996, 54, 16533–16539. doi: 10.1103/PhysRevB.54.16533
20. [20]
  Vanderbilt, D. Soft self-consistent pseudopotentials in a generalized eigenvalue formalism. Phys. Rev. B 1990, 41, 7892–7895. doi: 10.1103/PhysRevB.41.7892
21. [21]
  Chadi, D. J. Special points for Brillouin-zone integrations. Phys. Rev. B 1977, 16, 1746–1747. doi: 10.1103/PhysRevB.16.1746
22. [22]
  Enjalbert, R.; Galy, J. A refinement of the structure of V₂O₅. Acta Crystallogr., Sect. C. 1986, 42, 1467–1469. doi: 10.1107/S0108270186091825
23. [23]
  Halgren, T. A.; Lipscomb, W. N. The synchronous-transit method for determining reaction pathways and locating molecular transition states. Chem. Phys. Lett. 1977, 49, 225–232. doi: 10.1016/0009-2614(77)80574-5
24. [24]
  Zhang, B.; Liu, J.; Shen, F. Heterogeneous mercury oxidation by HCl over CeO₂ catalyst: density functional theory study. J. Phys. Chem. C 2015, 119, 15047–15055. doi: 10.1021/acs.jpcc.5b00645
25. [25]
  Zhang, B.; Liu, J.; Yang, Y.; Chang, M. Oxidation mechanism of elemental mercury by HCl over MnO₂ catalyst: insights from first principles. Chem. Eng. J. 2015, 280, 354–362. doi: 10.1016/j.cej.2015.06.056
26. [26]
  Ranea, V. A.; Vicente, J. L.; Mola, E. E.; Uyewa Mananu, R. A theoretical study of water chemisorption on the (001) plane of V₂O₅. Surf. Sci. 1999, 442, 498–506. doi: 10.1016/S0039-6028(99)00874-2
27. [27]
  He, Y.; Tilocca, A.; Dulub, O.; Selloni, A.; Diebold, U. Local ordering and electronic signatures of submonolayer water on anatase TiO₂(101). Nat Mater. 2009, 8, 585–589. doi: 10.1038/nmat2466
28. [28]
  Goclon, J.; Grybos, R.; Witko, M.; Hafner, J. Relative stability of low-index V₂O₅ surfaces: a density functional investigation. J. Phys. : Condens. Matter. 2009, 21, 095008. doi: 10.1088/0953-8984/21/9/095008
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Insights into the H₂O/V₂O₅ Interface Structure for Optimizing Water-splitting