Citation: Heng-Dong LAI, Qi-Pu LIN. Synthesis, Crystal Structure and Magnetic Properties of Two Ribbon-shaped Chalcogenidometalate Complexes (Butyl-Sn)4S8M2(TEPA)2 (M = Mn, Ni)[J]. Chinese Journal of Structural Chemistry, ;2020, 39(8): 1503-1508. doi: 10.14102/j.cnki.0254–5861.2011–2625 shu

Synthesis, Crystal Structure and Magnetic Properties of Two Ribbon-shaped Chalcogenidometalate Complexes (Butyl-Sn)4S8M2(TEPA)2 (M = Mn, Ni)

  • Corresponding author: Qi-Pu LIN, linqipu@fjirsm.ac.cn
  • Received Date: 27 September 2019
    Accepted Date: 19 November 2019

    Fund Project: the Natural Science Foundation of Fujian Province 2017J01039

Figures(6)

  • Under solvothermal conditions, two ribbon-shaped chalcogenidometalate coordination compounds, (butyl-Sn)4S8M2(TEPA)2 (M = Mn (1), Ni (2), TEPA = tetraethylenepentamine), have been synthesized and characterized by elemental analysis, energy dispersive X-ray, infrared/ultraviolet-visible spectroscopy, thermo-gravimetric analysis, single-crystal and powder X-ray diffraction. Complexes 1 and 2 crystallize in the triclinic space group P\begin{document}$ \overline 1 $\end{document} with a = 13.999(3), b = 14.658(4), c = 16.150(4) Å, α = 68.78(3)°, β = 69.12(3)°, γ = 72.07(3)°, V = 2825.0(14) Å3, Z = 2, Mr = 1448.28, μ = 2.503 mm‑1, F(000) = 1444, GOOF = 1.001, R = 0.0629 and wR = 0.1286 for 12855 observed reflections with I > 2σ(I) for 1; and a = 11.029(3), b = 11.858(2), c = 11.888(3) Å, α = 87.27(2)°, β = 69.10(2)°, γ = 83.63(2)°, V = 1443.6(6) Å3, Z = 1, Mr = 1455.78, μ = 2.660 mm‑1, F(000) = 728, GOOF = 1.017, R = 0.0464 and wR = 0.1185 for 9267 observed reflections with I > 2σ(I) for 2, respectively. Both 1 and 2 are composed of linear hexamer {Sn4M2} (M = Mn for 1, and Ni for 2) with 8 μ2-S2- bridges and 2 TEPA terminal ligands. Despite the quite large inter-paramagnetic-cation spacing (dMn-S-Sn-S-Sn-S-Sn-S-Sn-S-Mn = 13.485 Å, dNi-S-Sn-S-Sn-S-Sn-S-Sn-S-Ni = 14.078 Å), two samples exhibit distinct ferromagnetic-like behaviors with the intradimer coupling constant (J) and Weiss (θ) values up to 6.8 cm-1 and 8.5 K for 1 and 17.2 cm-1 and 21.1 K for 2 calculated from the temperature dependence of the magnetic susceptibility.
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