Advanced Search

Citation: Heng-Dong LAI, Qi-Pu LIN. Synthesis, Crystal Structure and Magnetic Properties of Two Ribbon-shaped Chalcogenidometalate Complexes (Butyl-Sn)4S8M2(TEPA)2 (M = Mn, Ni)[J]. Chinese Journal of Structural Chemistry, ;2020, 39(8): 1503-1508. doi: 10.14102/j.cnki.0254–5861.2011–2625 shu

Synthesis, Crystal Structure and Magnetic Properties of Two Ribbon-shaped Chalcogenidometalate Complexes (Butyl-Sn)4S8M2(TEPA)2 (M = Mn, Ni)

  • a.

    State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

  • b.

    College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China

  • Corresponding author: Qi-Pu LIN, linqipu@fjirsm.ac.cn
  • Received Date: 27 September 2019
    Accepted Date: 19 November 2019

    Fund Project: the Natural Science Foundation of Fujian Province 2017J01039

Figures(6)

  • Under solvothermal conditions, two ribbon-shaped chalcogenidometalate coordination compounds, (butyl-Sn)4S8M2(TEPA)2 (M = Mn (1), Ni (2), TEPA = tetraethylenepentamine), have been synthesized and characterized by elemental analysis, energy dispersive X-ray, infrared/ultraviolet-visible spectroscopy, thermo-gravimetric analysis, single-crystal and powder X-ray diffraction. Complexes 1 and 2 crystallize in the triclinic space group P\begin{document}$ \overline 1 $\end{document} with a = 13.999(3), b = 14.658(4), c = 16.150(4) Å, α = 68.78(3)°, β = 69.12(3)°, γ = 72.07(3)°, V = 2825.0(14) Å3, Z = 2, Mr = 1448.28, μ = 2.503 mm‑1, F(000) = 1444, GOOF = 1.001, R = 0.0629 and wR = 0.1286 for 12855 observed reflections with I > 2σ(I) for 1; and a = 11.029(3), b = 11.858(2), c = 11.888(3) Å, α = 87.27(2)°, β = 69.10(2)°, γ = 83.63(2)°, V = 1443.6(6) Å3, Z = 1, Mr = 1455.78, μ = 2.660 mm‑1, F(000) = 728, GOOF = 1.017, R = 0.0464 and wR = 0.1185 for 9267 observed reflections with I > 2σ(I) for 2, respectively. Both 1 and 2 are composed of linear hexamer {Sn4M2} (M = Mn for 1, and Ni for 2) with 8 μ2-S2- bridges and 2 TEPA terminal ligands. Despite the quite large inter-paramagnetic-cation spacing (dMn-S-Sn-S-Sn-S-Sn-S-Sn-S-Mn = 13.485 Å, dNi-S-Sn-S-Sn-S-Sn-S-Sn-S-Ni = 14.078 Å), two samples exhibit distinct ferromagnetic-like behaviors with the intradimer coupling constant (J) and Weiss (θ) values up to 6.8 cm-1 and 8.5 K for 1 and 17.2 cm-1 and 21.1 K for 2 calculated from the temperature dependence of the magnetic susceptibility.
  • 加载中
    1. [1]

      Liu, D. L.; Liu, Y.; Huang, P.; Zhu, C.; Kang, Z. H.; Shu, J.; Chen, M. Z.; Zhu, X.; Guo, J.; Zhuge, L. J.; Bu, X. H.; Feng, P. Y.; Wu, T. Highly tunable heterojunctions from multimetallic sulfide nanoparticles and silver nanowires. Angew. Chem. Int. Ed. 2018, 57, 5374–5378.  doi: 10.1002/anie.201800848

    2. [2]

      Wang, K. Y.; Feng, M. L.; Li, J. R.; Huang, X. Y. [NH3CH3]4[In4SbS9SH]: a novel methylamine-directed indium thioantimonate with Rb+ ion-exchange property. J. Mater. Chem. A 2013, 1, 1709–1705.  doi: 10.1039/C2TA00710J

    3. [3]

      Nie, L. N.; Xie, J.; Liu, G. F.; Hao, S. J.; Xu, Z. C. J.; Xu, R.; Zhang, Q. C. Crystalline In–Sb–S framework for highly-performed lithium/sodium storage. J. Mater. Chem. A 2017, 5, 14198–14205.  doi: 10.1039/C7TA03334F

    4. [4]

      Feng, M. L.; Sarma, D.; Qi, X. H.; Du, K. Z.; Huang, X. Y.; Kanatzidis, M. G. Efficient removal and recovery of uranium by a layered organic-inorganic hybrid thiostannate. J. Am. Chem. Soc. 2016, 138, 12578–12875.  doi: 10.1021/jacs.6b07351

    5. [5]

      Rosemann, N. W.; Eußner, J. P.; Dornsiepen, E.; Chatterjee, S.; Dehnen, S. Organotetrel chalcogenide clusters: between strong second-harmonic and white-light continuum generation. J. Am. Chem. Soc. 2016, 138, 16224–16227.  doi: 10.1021/jacs.6b10738

    6. [6]

      Chi, Y.; Sun, J.; Guo, S. P. Synthesis, crystal structure and magnetic property of ternary neodymium zirconium sulfide, Nd2ZrS5. Chin. J. Struct. Chem. 2016, 35, 713–717.

    7. [7]

      Shen, N. N.; Hu, B.; Cheng, C. C.; Zou, G. D.; Hu, Q. Q.; Du, C. F.; Li, J. R.; Huang, X. Y. Discrete supertetrahedral T3 InQ clusters (Q = S, S/Se, Se, Se/Te): ionothermal syntheses and tunable optical and photodegradation properties. Cryst. Growth & Des. 2018, 18, 962–968.

    8. [8]

      Liu, F.; Wulan, G.; Da, L.; Bao, Y. S.; Baiyin, M. Syntheses and structural characterization of multi-component chalcogenide compounds based on pyridine/1, 2-ethanedithiol solvent. Chin. J. Struct. Chem. 2016, 35, 946–952.

    9. [9]

      Wang, Y.; Shi, Y. F.; Li, X. B.; Zou, X. C.; He, Y. C.; Wang, X. Structure and luminescent property of a tetrahedral silver(I) cluster complex based on phosphor and sulphur mixed-ligand system. Chin. J. Struc. Chem. 2019, 38, 1216–1222.

    10. [10]

      Du, K. Z.; Qi, X. H.; Feng, M. L.; Li, J. R.; Wang, X. Z.; Du, C. F.; Zou, G. D.; Wang, M.; Huang, X. Y. Synthesis, structure, band gap, and near-infrared photosensitivity of a new chalcogenide crystal, (NH4)4Ag12Sn7Se22. Inorg. Chem. 2016, 55, 5110–5112.  doi: 10.1021/acs.inorgchem.6b00803

    11. [11]

      Jiao, X. C.; Chen, Z. W.; Li, X. D.; Sun, Y. F.; Gao, S.; Yan, W. S.; Wang, C. M.; Zhang, Q.; Lin, Y.; Luo, Y.; Xie, Y. Defect-mediated electron-hole separation in one-unit-cell ZnIn2S4 layers for boosted solar-driven CO2 reduction. J. Am. Chem. Soc. 2017, 139, 7586–7594  doi: 10.1021/jacs.7b02290

    12. [12]

      Jiao, X. C.; Li, X. D.; Jin, X. Y.; Sun, Y. F.; Xu, J. Q.; Liang, L.; Ju, H. X.; Zhu, J. F.; Pan, Y.; Yan, W. S.; Lin, Y.; Xie, Y. Partially oxidized SnS2 atomic layers achieving efficient visible-light-driven CO2 reduction. J. Am. Chem. Soc. 2017, 139, 18044–18051.  doi: 10.1021/jacs.7b10287

    13. [13]

      Bu, X. H.; Zheng, N. F.; Feng, P. Y. Tetrahedral chalcogenide clusters and open frameworks. Chem. -Eur. J. 2004, 10, 3356–3362.  doi: 10.1002/chem.200306041

    14. [14]

      Feng, P. Y.; Bu, X. H.; Zheng, N. F. The interface chemistry between chalcogenide clusters and open framework chalcogenides. Acc. Chem. Res. 2005, 38, 293–303.  doi: 10.1021/ar0401754

    15. [15]

      Huang, S. L.; He, L.; Chen, E. X.; Lai, H. D.; Zhang, J.; Lin, Q. P. A wide pH-range stable crystalline framework based on the largest tin-oxysulfide cluster [Sn20O10S34]. Chem. Commun. 2019, 55, 11083–11086.  doi: 10.1039/C9CC05736F

    16. [16]

      Liang, J. J.; Chen, J. F.; Zhao, J.; Pan, Y. L.; Zhang, Y.; Jia, D. X. Effects of lanthanide metal size and amino ligand denticity on the solvothermal systems Ln/Sn/Se/en and Ln/Sn/Se/dien (Ln = lanthanide). Dalton Trans. 2011, 40, 2631–2637.  doi: 10.1039/c0dt01424a

    17. [17]

      Hilbert, J.; Näther, C.; Weihrich, R.; Bensch, W. Room-temperature synthesis of thiostannates from {[Ni(tren)]2[Sn2S6]}n. Inorg. Chem. 2016, 55, 7859–7865.  doi: 10.1021/acs.inorgchem.6b00625

  • 加载中
    1. [1]

      Xinyu Liu , Jialin Yang , Zonglin He , Jiaoyan Ai , Lina Song , Baohua Liu . Linear polyurethanes with excellent comprehensive properties from poly(ethylene carbonate) diol. Chinese Chemical Letters, 2025, 36(1): 110236-. doi: 10.1016/j.cclet.2024.110236

    2. [2]

      Xianzheng Zhang ,  Yana Chen ,  Zhiyong Ye ,  Huilin Hu ,  Ling Lei ,  Feng You ,  Junlong Yao ,  Huan Yang ,  Xueliang Jiang . Magnetic field-assisted microbial corrosion construction iron sulfides incorporated nickel-iron hydroxide towards efficient oxygen evolution. Chinese Journal of Structural Chemistry, 2024, 43(1): 100200-100200. doi: 10.1016/j.cjsc.2023.100200

    3. [3]

      Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269

    4. [4]

      Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009

    5. [5]

      Shengwen Guan , Zhaotong Wei , Ningxu Han , Yude Wei , Bin Xu , Ming Wang , Junjuan Shi . Construction of metallo-complexes with 2,2′:6′,2″-terpyridine substituted triphenylamine in different modified positions and their photophysical properties. Chinese Chemical Letters, 2024, 35(7): 109348-. doi: 10.1016/j.cclet.2023.109348

    6. [6]

      Chaochao Jin , Kai Li , Jiongpei Zhang , Zhihua Wang , Jiajing Tan . N,O-Bidentated difluoroboron complexes based on pyridine-ester enolates: Facile synthesis, post-complexation modification, optical properties, and applications. Chinese Chemical Letters, 2024, 35(9): 109532-. doi: 10.1016/j.cclet.2024.109532

    7. [7]

      Shenhao QIU , Qingquan XIAO , Huazhu TANG , Quan XIE . First-principles study on electronic structure, optical and magnetic properties of rare earth elements X (X=Sc, Y, La, Ce, Eu) doped with two-dimensional GaSe. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2250-2258. doi: 10.11862/CJIC.20240104

    8. [8]

      Huiju Cao , Lei Shi . sp1-Hybridized linear and cyclic carbon chain. Chinese Chemical Letters, 2025, 36(4): 110466-. doi: 10.1016/j.cclet.2024.110466

    9. [9]

      Di ZHANG , Tianxiang XIE , Xu HE , Wanyu WEI , Qi FAN , Jie QIAO , Gang JIN , Ningbo LI . Construction and antitumor activity of pH/GSH dual-responsive magnetic nanodrug. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 786-796. doi: 10.11862/CJIC.20240329

    10. [10]

      Xiaoyu Chen , Jiahao Hu , Jingyi Lin , Haiyang Huang , Changqing Ye , Hongli Bao . Biisoindolylidene solvatochromic fluorophores: Synthesis and photophysical properties. Chinese Chemical Letters, 2025, 36(2): 109923-. doi: 10.1016/j.cclet.2024.109923

    11. [11]

      Yadan SUN , Xinfeng LI , Qiang LIU , Oshio Hiroki , Yinshan MENG . Structures and magnetism of dinuclear Co complexes based on imine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2212-2220. doi: 10.11862/CJIC.20240131

    12. [12]

      Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411

    13. [13]

      Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215

    14. [14]

      Mengyuan Li , Xitong Ren , Yanmei Gao , Mengyao Mu , Shiping Zhu , Shufang Tian , Minghua Lu . Constructing bifunctional magnetic porous poly(divinylbenzene) polymer for high-efficient removal and sensitive detection of bisphenols. Chinese Chemical Letters, 2024, 35(12): 109699-. doi: 10.1016/j.cclet.2024.109699

    15. [15]

      Zhao-Bo Hu , Ling-Ao Gui , Long-He Li , Tong-Tong Xiao , Adam T. Hand , Pagnareach Tin , Mykhaylo Ozerov , Yan Peng , Zhongwen Ouyang , Zhenxing Wang , Zi-Ling Xue , You Song . CoⅡ single-ion magnet and its multi-dimensional aggregations: Influence of the structural rigidity on magnetic relaxation process. Chinese Chemical Letters, 2025, 36(2): 109600-. doi: 10.1016/j.cclet.2024.109600

    16. [16]

      Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214

    17. [17]

      Yanjie Li , Chaoqun Qu , Siqi Meng , Jiaqi Hu , Ze Gao , Hongji Xu , Rui Gao , Ming Feng . Revealing electronic state evolution of Co(Ⅱ)/Co(Ⅲ) in CoO (111) plane during OER process through magnetic measurement. Chinese Chemical Letters, 2025, 36(3): 109872-. doi: 10.1016/j.cclet.2024.109872

    18. [18]

      Xiao-Fang Lv , Xiao-Yun Ran , Yu Zhao , Rui-Rui Zhang , Li-Na Zhang , Jing Shi , Ji-Xuan Xu , Qing-Quan Kong , Xiao-Qi Yu , Kun Li . Combing NIR-Ⅱ molecular dye with magnetic nanoparticles for enhanced photothermal theranostics with a 95.6% photothermal conversion efficiency. Chinese Chemical Letters, 2025, 36(4): 110027-. doi: 10.1016/j.cclet.2024.110027

    19. [19]

      Zhihao Gu , Jiabo Le , Hehe Wei , Zehui Sun , Mahmoud Elsayed Hafez , Wei Ma . Unveiling the intrinsic properties of single NiZnFeOx entity for promoting electrocatalytic oxygen evolution. Chinese Chemical Letters, 2024, 35(4): 108849-. doi: 10.1016/j.cclet.2023.108849

    20. [20]

      Wenzhong Zhang , Zirui Yan , Lingcheng Chen , Yi Xiao . Sn-fused perylene diimides: Synthesis, mechanism, and properties. Chinese Chemical Letters, 2024, 35(10): 109582-. doi: 10.1016/j.cclet.2024.109582

Get Citation
PDF
XML
Metrics
  • PDF Downloads(1)
  • Abstract views(304)
  • HTML views(14)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return