Citation: Xin-Qi ZHANG. Synthesis and Characterization of Highly Efficient Photoluminescence Gd doping Hexagonal CePO₄ One-dimensional Nanowires[J]. Chinese Journal of Structural Chemistry, ;2020, 39(8): 1515-1521. doi: 10.14102/j.cnki.0254–5861.2011–2624 shu

Synthesis and Characterization of Highly Efficient Photoluminescence Gd doping Hexagonal CePO₄ One-dimensional Nanowires

Xin-Qi ZHANG ^,

Instrumentation Analysis and Research Center, Fuzhou University, Fuzhou 350108, China

Corresponding author: Xin-Qi ZHANG, xinqi79@126.com
Received Date: 27 September 2019
Accepted Date: 27 December 2019

Fund Project: the Natural Science Foundation of Fujian Province 2017J01688

Figures(5)

Rare earth phosphates have been used extensively in luminescent phosphors. Hexagonal Ce_1-xGd_xPO₄ with crystal field manipulation was successfully synthesized using a hydrothermal method. The photoluminescence emission intensity of hexagonal CePO₄ was obviously enhanced by the crystal structure manipulation with gadolinium ions codoping. Compared to pure CePO₄, the intensity photoluminescence was enhanced about 15 folds with x = 0.05. The effect of gadolinium doping was systematically investigated by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy and photoluminescence spectroscopy. Crystal field asymmetry can be effectively tuned by different amount of Gd³⁺ codoping, and the crystal field asymmetry is conductive to electron population of high energy level of Ce³⁺ ions. This material has potential applications in optics, electronics fields, and so on. Meanwhile, the method can be extended to another kind of high performance photoluminescence materials preparation.
- rare earth,
- hydrothermal,
- photoluminescence,
- gadolinium dopant,
- crystal field
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Characterization of Highly Efficient Photoluminescence Gd doping Hexagonal CePO4 One-dimensional Nanowires

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Characterization of Highly Efficient Photoluminescence Gd doping Hexagonal CePO₄ One-dimensional Nanowires