Citation: Ning WANG, Meng-Shu ZHOU, Ting LI, Hong-Ru FU, Fei-Fei LI. Synthesis and Detection of Pesticides of Luminescent Metal-organic Framework Based on Carboxyl-decorating Tetraphenylethylene[J]. Chinese Journal of Structural Chemistry, ;2020, 39(8): 1496-1502. doi: 10.14102/j.cnki.0254–5861.2011–2623 shu

Synthesis and Detection of Pesticides of Luminescent Metal-organic Framework Based on Carboxyl-decorating Tetraphenylethylene

Ning WANG ^{a, b} ,
Meng-Shu ZHOU ^{a, b} ,
Ting LI ^b ,
Hong-Ru FU ^b,, ,
Fei-Fei LI ^a,,

a.
College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo 454000, China
b.
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China

Corresponding author: Hong-Ru FU, hongrufu2015@163.com Fei-Fei LI, lifeifei@hpu.edu.cn
Received Date: 25 September 2019
Accepted Date: 20 April 2020

Fund Project: Supporting Plan for Scientific and Technological Innovative Talents in Universities of Henan Province 20HASTIT006

Figures(7)

A water-stable porous anionic metal-organic framework (MOF), [(CH₃)₂NH₂][In(TCPP)_4/3]_n· (2DMF)_n(3H₂O)_n (1, TCPP = 1, 1, 2, 2-tetra(4-carboxylbiphenyl)ethylene), was synthesized. Here, compound 1 showed extremely high sensitivity and selectivity to current general-purpose pesticide 2, 6-dichloro-4-nitroaniline (DCN) in aqueous solution. The fluorescence intensity of compound 1 could be decreased as much as 80% by 6 μL DCN, and it was almost completely quenched only with 20 μL DCN. The results indicate that compound 1 can act as a fluorescent probe for DCN.
- metal-organic framework,
- tetraphenylethylene,
- DCN detection
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