Citation: Da-Dong LIANG, Yu-Ling YANG, Qing-Hua ZHOU, Jun-Bo LIU, Shan-Shan TANG. Incorporation of Isopolyoxometalate into the Crystal and Membrane of ZIF-8[J]. Chinese Journal of Structural Chemistry, ;2020, 39(8): 1395-1404. doi: 10.14102/j.cnki.0254–5861.2011–2622 shu

Incorporation of Isopolyoxometalate into the Crystal and Membrane of ZIF-8

Da-Dong LIANG ^{a, b} ,
Yu-Ling YANG ^b ,
Qing-Hua ZHOU ^b ,
Jun-Bo LIU ^b,, ,
Shan-Shan TANG ^{a, c,,}

a.
Key Laboratory of Straw Biology and Utilization, The Ministry of Education, Jilin Agricultural University, Changchun 130118, China
b.
College of Resources and Environment, Jilin Agricultural University, Changchun 130118, China
c.
College of Life Sciences, Jilin Agricultural University, Jilin 130118, China

Corresponding author: Jun-Bo LIU, liujb@mail.ccut.edu.cn Shan-Shan TANG, tangshanshan81@163.com
Received Date: 25 September 2019
Accepted Date: 27 November 2019

Fund Project: the Science and Technology Research Projects for Education Department of Jilin Province 2016170

Figures(8)

With the aim of designing and preparing the materials based on polyoxometalates (POMs) and themetal-organic frameworks (MOFs) toward desired applications, a facile approach was developed to incorporate theclusters of Mo₇O₂₄^6- (Mo₇), a representative isopolyoxometalate, into the vacant cages of ZIF-8. Through theso-called strategy of building MOF bottles around the POM ships, the powdered crystals and crystalline membraneof Mo₇@ZIF-8 were synthesized, respectively. The products were characterized by IR, PXRD, N₂ adsorption, andSEM. The Mo₇@ZIF-8 crystals could effectively adsorb malachite green (MG) from water, and the maximumadsorption capacity reached 1963 mg·g^-1. The Mo₇@ZIF-8 crystals could also be used for selectively adsorbing MGfrom the mixed dye solution containing MG and methyl orange (MO). Moreover, the Mo₇@ZIF-8 membraneexhibited the proton conductivity of 9.5 × 10^-2 S·cm^-1 at 75 ℃ under 98% relative humidity.
- metal-organic framework,
- ZIF-8,
- polyoxometalate,
- functionalization,
- isopolyoxometalate
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