Citation: Feng GUO. Synthesis, Crystal Structure and Catalytic Properties of a Novel Ni(II) MOF with a Rare [3+3+3] Nine Fold Interpenetrated Network[J]. Chinese Journal of Structural Chemistry, ;2020, 39(8): 1489-1495. doi: 10.14102/j.cnki.0254–5861.2011–2620 shu

Synthesis, Crystal Structure and Catalytic Properties of a Novel Ni(II) MOF with a Rare [3+3+3] Nine Fold Interpenetrated Network

Feng GUO ^,

Chongqing Key Laboratory of Inorganic Special Functional Materials, College of Chemistry and Chemical Engineering, Yangtze Normal University, Fuling, Chongqing 408100, China

Corresponding author: Feng GUO, guofeng1510@yeah.net
Received Date: 25 September 2019
Accepted Date: 11 December 2019

Figures(3)

Metal-organic frameworks are a sort of rapid development crystal solids, which have greatly attracted a large amount of attention in recent decades. The construction of 3D [Ni(bcp)(bpp)]_n (namely complex 1) displays a rare [3+3+3] nine-fold interpenetrated diamond topology, which can be successfully synthesized by a mixed strategy of 1, 3-bis(4-carboxyphenoxy) propane (H₂bcp) and 1, 4-bis(4-pyridylmethyl) piperazine (bpp). The interpenetrated network may be ascribed to these flexible bridging linkers to facilitate the penetration degree. In addition, the resultant sample was adequately characterized by elemental analysis, single-crystal X-ray diffraction, powder X-ray diffraction, and thermal gravimetric analysis. Furthermore, the as-synthesized sample can be used as catalysis for chemical fixation of CO₂ and epoxide to carbonate.
- Ni(II)-organic framework,
- interpenetrated structure,
- CO₂,
- catalysis
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