Citation: Man-Ling ZHOU, Shi-Ting ZHANG, Yan-Bin WU, Yang LIU. Two Three-fold Interpenetrating Co/Cd Architectures Based on Right- and Left-helical Chains[J]. Chinese Journal of Structural Chemistry, ;2020, 39(8): 1483-1488. doi: 10.14102/j.cnki.0254–5861.2011–2613 shu

Two Three-fold Interpenetrating Co/Cd Architectures Based on Right- and Left-helical Chains

Key Laboratory of Functional Organometallic Materials, Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008, China

Corresponding author: Yang LIU, liuyang@hynu.edu.cn
Received Date: 23 September 2019
Accepted Date: 1 December 2019

Figures(5)

Two Cd(II) and Co(II)-based complexes formulated as [Cd(bimh)(L)]·2H₂O (1) and [Co(bimh)-(L)]·2H₂O (2) (bimh = 1, 6-bis(imidazole-1-yl)hexane, H₂L = 4, 4΄-(methylenebis(oxy))dibenzoic acid) have been successfully prepared under hydrothermal conditions. Single-crystal X-ray diffraction analysis indicates that the two complexes are isostructural and crystallize in Pbca space group. The whole three-dimensional (3D) architecture is based on three-fold interpenetrated layers containing double helical chains. In addition, the IR, TG and photoluminescence properties were also investigated.
- crystal structure,
- helical,
- interpenetrating,
- photoluminescence
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