Citation: Han XU, Zhao-Rui PAN. A Metal-organic Framework Constructed from a Rare Rod-shaped Secondary Building Unit and Its Highly Efficient Photocatalytic Activity[J]. Chinese Journal of Structural Chemistry, ;2020, 39(8): 1475-1482. doi: 10.14102/j.cnki.0254–5861.2011–2605 shu

A Metal-organic Framework Constructed from a Rare Rod-shaped Secondary Building Unit and Its Highly Efficient Photocatalytic Activity

Han XU ^a ,
Zhao-Rui PAN ^b,,

a.
School of Chemistry and Chemical Engineering, Key Laboratory of Inorganic Functional Materials, Huangshan University, Huangshan 245041, China
b.
School of Environmental Science, Nanjing Xiaozhuang University, Nanjing 211171, China

Corresponding author: Zhao-Rui PAN, pzr_2006@163.com
Received Date: 21 August 2019
Accepted Date: 6 December 2019

Fund Project: Key Projects of Natural Science Research in Universities of Anhui Province KJ2018A0409National Undergraduate Training Programs for Innovation and Entrepreneurship 201810375012National Undergraduate Training Programs for Innovation and Entrepreneurship 201810375039

Figures(11)

A new Cu(II) coordination polymer, {[Cu₃(oba)₂(μ³-OH)₂(H₂O)₂]⋅6H₂O}_n (H₂oba = 4, 4΄-oxydibenzoic acid), was synthesized by the solvothermal route and characterized by IR, TGA and XRD. The complex crystallizes in the monoclinic system, space group P2₁/c with a = 5.957(6), b = 29.746(3), c = 9.351(7) Å, β = 125.709(4)º, V = 1345.4(2) Å³, Z = 2, C₂₈H₃₆Cu₃O₂₀, M_r= 883.09, D_c = 1.913 g/cm³, F(000) = 782, μ = 2.427 mm^-1, R = 0.0780 and wR= 0.1688 for 3120 observed reflections with I > 2σ(I). The complex forms a 3D framework based on rare infinite rod-shaped secondary building units (SBUs), and C–H···π interactions play an important role in stabilizing the 3D supramolecular architecture. It shows excellent catalytic activities for the degradation of safranin O (SO) and methylene blue (MB) dyes in aqueous solution under UV light irradiation. Furthermore, the apparent rate constants have also been investigated.
- Jahn Teller effect,
- dye degradation,
- photocatalytic activity,
- fenton oxidation
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