Citation: Han XU, Zhao-Rui PAN. A Metal-organic Framework Constructed from a Rare Rod-shaped Secondary Building Unit and Its Highly Efficient Photocatalytic Activity[J]. Chinese Journal of Structural Chemistry, ;2020, 39(8): 1475-1482. doi: 10.14102/j.cnki.0254–5861.2011–2605 shu

A Metal-organic Framework Constructed from a Rare Rod-shaped Secondary Building Unit and Its Highly Efficient Photocatalytic Activity

Han XU ^a ,
Zhao-Rui PAN ^b,,

a.
School of Chemistry and Chemical Engineering, Key Laboratory of Inorganic Functional Materials, Huangshan University, Huangshan 245041, China
b.
School of Environmental Science, Nanjing Xiaozhuang University, Nanjing 211171, China

Corresponding author: Zhao-Rui PAN, pzr_2006@163.com
Received Date: 21 August 2019
Accepted Date: 6 December 2019

Fund Project: Key Projects of Natural Science Research in Universities of Anhui Province KJ2018A0409National Undergraduate Training Programs for Innovation and Entrepreneurship 201810375012National Undergraduate Training Programs for Innovation and Entrepreneurship 201810375039

Figures(11)

A new Cu(II) coordination polymer, {[Cu₃(oba)₂(μ³-OH)₂(H₂O)₂]⋅6H₂O}_n (H₂oba = 4, 4΄-oxydibenzoic acid), was synthesized by the solvothermal route and characterized by IR, TGA and XRD. The complex crystallizes in the monoclinic system, space group P2₁/c with a = 5.957(6), b = 29.746(3), c = 9.351(7) Å, β = 125.709(4)º, V = 1345.4(2) Å³, Z = 2, C₂₈H₃₆Cu₃O₂₀, M_r= 883.09, D_c = 1.913 g/cm³, F(000) = 782, μ = 2.427 mm^-1, R = 0.0780 and wR= 0.1688 for 3120 observed reflections with I > 2σ(I). The complex forms a 3D framework based on rare infinite rod-shaped secondary building units (SBUs), and C–H···π interactions play an important role in stabilizing the 3D supramolecular architecture. It shows excellent catalytic activities for the degradation of safranin O (SO) and methylene blue (MB) dyes in aqueous solution under UV light irradiation. Furthermore, the apparent rate constants have also been investigated.
- Jahn Teller effect,
- dye degradation,
- photocatalytic activity,
- fenton oxidation
1. [1]
  Jennifer, S. J.; Jana, A. K. Influence of pyrazine/piperazine based guest molecules in the crystal structures of uranyl thiophene dicarboxylate coordination polymers: structural diversities and photocatalytic activities for the degradation of organic dye. Cryst. Growth Des. 2017, 17, 5318−5329. doi: 10.1021/acs.cgd.7b00826
2. [2]
  Han, L. J.; Kong, Y. J.; Yan, T. J.; Fan, L. T.; Zhang, Q.; Zhao, H. J.; Zheng, H. G. A new five-coordinated copper compound for efficient degradation of methyl orange andcongo red in the absence of UV-visible radiation. Dalton Trans. 2016, 45, 18566−18571. doi: 10.1039/C6DT03273G
3. [3]
  Maspoch, D.; Domingo, N.; Ruiz, M. D.; Wurst, K.; Hernandez, J. M.; Vaughan, G.; Rovira, C.; Lloret, F.; Tejada, J.; Veciana, J. Coexistence of ferroand antiferromagnetic interactions in a metal-organic radical-based (6, 3)-helical network with large channels. Chem. Commun. 2005, 40, 5035−5037.
4. [4]
  Li, H. H.; Shi, W.; Xu, N.; Zhang, Z. J.; Niu, Z.; Han, T.; Cheng, P. Structural diversity of four metal-organic frameworks based on linear homo/heterotrinuclear nodes with furan-2, 5-dicarboxylic acid: structures and luminescent and magnetic properties. Cryst. Growth Des. 2012, 12, 2602−2612. doi: 10.1021/cg300196w
5. [5]
  Wang, J.; Gao, L. L.; Zhang, J.; Zhao, L.; Wang, X. Q.; Niu, X. Y.; Fan, L. M.; Hu, T. M. Syntheses, gas adsorption, and sensing properties of solvent controlled Zn(II) pseudo-supramolecular isomers and Pb(II) supramolecular isomers. Cryst. Growth Des. 2019, 19, 630−637. doi: 10.1021/acs.cgd.8b01077
6. [6]
  Rao, P. C.; Mandal, S. Europium-based metal-organic framework as a dual luminescence sensor for the selective detection of phosphate anion and Fe³⁺ ion in aqueous media. Inorg. Chem. 2018, 57, 11855−11858. doi: 10.1021/acs.inorgchem.8b02017
7. [7]
  Chen, C.; Zhang, M. X.; Zhang, W. W.; Bai, J. F. Stable amide-functionalized metal-organic framework with highly selective CO₂ adsorption. Inorg. Chem. 2019, 58, 2729−2735. doi: 10.1021/acs.inorgchem.8b03308
8. [8]
  Wang, Q.; Bai, J. F.; Lu, Z. Y.; Pan, Y.; You, X. Z. Finely tuning MOFs towards high-performance post-combustion CO₂ capture materials. Chem. Commun. 2016, 52, 443−452. doi: 10.1039/C5CC07751F
9. [9]
  Du, L. T.; Lu, Z. Y.; Zheng, K. Y.; Wang, J. Y.; Zheng, X.; Pan, Y.; You, X. Z.; Bai, J. F. Fine-tuning pore size by shifting coordination sites of ligands and surface polarization: a porous coordination polymer of metal-organic frameworks to sharply enhance the selectivity for CO₂. J. Am. Chem. Soc. 2013, 135, 562−565. doi: 10.1021/ja309992a
10. [10]
  Ding, Y.; Chen, Y. P.; Zhang, X.; Chen, L.; Dong, Z.; Jiang, H. L.; Xu, H.; Zhou, H. C. Controlled intercalation and chemical exfoliation of layered metal-organic frameworks using a chemically labile intercalating agent. J. Am. Chem. Soc. 2017, 139, 9136−9149. doi: 10.1021/jacs.7b04829
11. [11]
  He, P.; Yu, X. Y.; Lou, X. W. Carbon-incorporate nickel-cobalt mixed metal phosphide nanoboxes with enhanced electro-catalytic activity for oxygen evolution. Angew. Chem., Int. Ed. 2017, 56, 3897−3900. doi: 10.1002/anie.201612635
12. [12]
  Huang, Y. B.; Liang, J.; Wang, X. S.; Cao, R. Multifunctional metal-organic framework catalyst: synergistic catalysis and tandem reations. Chem. Soc. Rev. 2017, 46, 126−157.
13. [13]
  Roy, M.; Sengupta, S.; Bala, S.; Bhattcharya, S.; Mondal, R. Systematic study of mutually inclusive influences of temperature and substitution on the coordination geometry Co(II) in a series of coordination polymers and their properties. Cryst. Growth Des. 2016, 16, 3170−3179. doi: 10.1021/acs.cgd.5b01835
14. [14]
  Qin, L.; Chen, H. Z.; Lei, J.; Wang, Y. Q.; Ye, T. Q.; Zheng, H. G. Photodegradation of some organic dyes over two metal-organic frameworks with especially high efficiency for safranine T. Cryst. Growth Des. 2017, 17, 1293−1298. doi: 10.1021/acs.cgd.6b01690
15. [15]
  Chen, Y. Q.; Li, G. R.; Qu, Y. K.; Zhang, Y. H.; He, K. H.; Gao, Q.; Bu, X. H. Water-insoluble heterometal-oxide-based photocatalysts effective for the photo-decomposition of methyl organge. Cryst. Growth Des. 2013, 13, 901−907. doi: 10.1021/cg3016244
16. [16]
  Wang, Z. J.; Han, L. J.; Gao, X. J.; Zheng, H. G. Three Cd(II) MOFs with different functional groups: selective CO₂ capture and metal ions detection. Inorg. Chem. 2018, 57, 5232−5239. doi: 10.1021/acs.inorgchem.8b00272
17. [17]
  Sheldrick, G. M. SHELXL-97, Program for X-ray Crystal Structure Refinement. University of Göttingen, Germany 1997.
18. [18]
  Spek. A. L. PLATON SQUEEZE: a tool for the calculation of the disordered solvent contribution to the calculate structure factors. Actacrystallogr. Sect. C: Struct. Chem. 2015, 71, 9−18. doi: 10.1107/S2053229614024929
19. [19]
  Wang, A. L.; Zhou, D.; Chen, Y. N.; Li, J. J.; Zhang, H. X.; Zhao, Y. L.; Chu, H. B. Crystal structure and photoluminescence of europium, terbium and samarium compounds with halogen-benzoate and 2, 4, 6-tri(2-pyridyl)-s-triazine. J. Lumin. 2016, 177, 22−30. doi: 10.1016/j.jlumin.2016.04.024
20. [20]
  Xu, W. T.; Chen, L.; Jiang, F. L.; Hong, M. C. Synthesis, crystal structure and properties of a nanotubular metal-organic framework (MOFs) based on Cu(II) oxide chains and benzenedicarboxylates. Chin. J. Struct. Chem. 2012, 3, 321−326.
21. [21]
  Li, X.; Chen, D. Y.; Lin, J. L.; Li, Z. F.; Zheng, Y. Q. Di-, tetra-, and hexanuclear hydroxy-bridged copper(II) cluster compounds: syntheses, structures, and properties. Cryst. Growth Des. 2008, 8, 2853−2861. doi: 10.1021/cg701150q
22. [22]
  Veselska, O.; Cai, L. W.; Podbevšek, D.; Ledoux, G.; Guillou, N.; Pilet, G.; Fateeva, A.; Demessence, A. Structural diversity of coordination polymers based on a heterotopic ligand: Cu(II)-carboxylate vs Cu(I)-thiolate. Inorg. Chem. 2019, 58, 2736−2743. doi: 10.1021/acs.inorgchem.8b03310
23. [23]
  Tomar, K.; Verma, A.; Bharadwaj, P. K. Exploiting dimensional variability in Cu paddle-wheel secondary building unit based mixed valence Cu(II)/Cu(I) frameworks from a bispyrazole ligand by solvent/pH variation. Cryst. Growth Des. 2018, 18, 2397−2404. doi: 10.1021/acs.cgd.8b00002
24. [24]
  Rosi, N. L.; Kim, J.; Eddaoudi, M.; Chenm B. L.; O'Keeffe, M.; Yaghi, O. M. Rod packings and metal-organic frameworks constructed from rod-shaped secondary building units. J. Am. Chem. Soc. 2005, 127, 1504−1518 doi: 10.1021/ja045123o
25. [25]
  Li, N.; Chen, L.; Lian, F. Y.; Jiang, F. L.; Hong, M. C. Syntheses and crystal structures of three novel Zn^Ⅱ-sulfonyldibenzoilatecoordination polymers. Chin. J. Struct. Chem. 2009, 28, 1417−1426.
26. [26]
  Zhang, C. H.; Ai, L. H.; Jiang, J. Graphene hybridized photoactive iron terephthalate with enhanced photocatalytic activity for the degradation of rhodamine B under visible light. J. Ind. Eng. Chem. Res. 2015, 54, 153−163. doi: 10.1021/ie504111y
27. [27]
  Akhtar, S.; Bala, S.; De, A.; Das, K. S.; Adhikary, A.; Jyotsna, S.; Poddar, P.; Mondal, R. Designing multifunctional MOFs using the inorganic motif [Cu₃(μ₃-OH)(μ-pyz)] as an SBU and their properties. Cryst. Growth Des. 2019, 19, 992−1004. doi: 10.1021/acs.cgd.8b01540
28. [28]
  Pham, N.; Xing, G.; Miller, C.; Waite, T. D. Fenton-like copper redox chemistry revisited: hydrogen peroxide and superoxide mediation of copper-catalyzed oxidant production. J. Catal. 2013, 301, 54−64. doi: 10.1016/j.jcat.2013.01.025
29. [29]
  Gray, R. D. Kinetic of oxidation of copper(I) by molecular oxygen in perchloric by the Cu²⁺-2, 2΄-bipyridyl complex. J. Am. Chem. Soc. 1969, 91, 56−62. doi: 10.1021/ja01029a012
30. [30]
  Wang, C. K.; Xing, F. F.; Bai, Y. L.; Zhao, Y. M.; Li, M. X.; Zhu, S. R. Synthesis and structure of semirigid tetracarboxylate copper(II) porous coordination polymers and their versatile high-efficiency catalytic dye degradation in neutral aqueous solution. Cryst. Growth Des. 2016, 16, 2277−2288. doi: 10.1021/acs.cgd.6b00065
31. [31]
  Bala, S.; Bhattacharya, S.; Goswami, A.; Adhikary, A.; Konar, S. Designing functional metal-organic frameworks by imparting a hexanuclear copper-based secondary building unit specific properties: structural correlation with magnetic and photocatalytic activity. Cryst. Growth Des. 2014, 14, 6391−6398. doi: 10.1021/cg501226v
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