Citation: Xiao-Ming SHI, Li-Na XIAO, Shu-Jing LI, Xiao-Zeng LI. Synthesis and Characterization of Heterobimetallic Zigzag Chains with a Close-packed Structure Based on Macrocyclic Metalloligands[J]. Chinese Journal of Structural Chemistry, ;2020, 39(8): 1465-1474. doi: 10.14102/j.cnki.0254–5861.2011–2603 shu

Synthesis and Characterization of Heterobimetallic Zigzag Chains with a Close-packed Structure Based on Macrocyclic Metalloligands

a.
College of Chemistry and Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, China
b.
Department of Chemistry, School of Science, Tianjin University, and Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China

Corresponding author: Xiao-Ming SHI, lixiaozeng321@tju.edu.cn Xiao-Zeng LI, shixiaoming2019@163.com
Received Date: 16 September 2019
Accepted Date: 2 December 2019

Fund Project: the Natural Science Foundation of He'nan Educational Committee of China 17A150056the National Natural Science Foundation of China 21501203the Funds of Basic and Advanced Technology Research Project of Henan Province of China 192012310497the Research Fund for the Doctoral Program of Higher Education of China ZKNUB2013003the Funds of Zhoukou Normal University ZKNUB115202

Figures(9)

Two new heterobimetallic coordination polymers {[Co(NiL)(H₂O)₃]·4H₂O}_n (1) and {[Cu(NiL)(H₂O)₃]·4H₂O}_n (2) were synthesized based on metalloligand under the same self-assembly conditions. X-ray diffraction analyses reveal that the two compounds involve close-packed zigzag chains, which expand into various three-dimensional supramolecular frameworks through the second interactions such as hydrogen bonds and π∙∙∙π stacking interactions. In these two compounds, NiL as a bridging ligand chelates the metal ion nodes via two oxamido carbonyls and carboxylate oxygen atom. The central Co(II) and Cu(II) ions in 1 and 2 both exhibit distorted octahedral coordination geometry. They are bridged by macrocyclic oxamido metalloligands fusing the zigzag chains with a ''head-to-tail'' arrangement. The Ni(II) ion in metalloligand is coordinated by four nitrogen atoms with the [NiN4] chromophore exhibiting distorted planarity. The two investigated compounds were further characterized by thermogravimetric analysis and FT-IR spectroscopy. The fluorescent properties of 1 and 2 in the solid state were also investigated.
- zigzag chain,
- heterobimetallic,
- metalloligand,
- crystal structure,
- fluorescence
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