Citation: Xiao-Ming SHI, Li-Na XIAO, Shu-Jing LI, Xiao-Zeng LI. Synthesis and Characterization of Heterobimetallic Zigzag Chains with a Close-packed Structure Based on Macrocyclic Metalloligands[J]. Chinese Journal of Structural Chemistry, ;2020, 39(8): 1465-1474. doi: 10.14102/j.cnki.0254–5861.2011–2603 shu

Synthesis and Characterization of Heterobimetallic Zigzag Chains with a Close-packed Structure Based on Macrocyclic Metalloligands

a.
College of Chemistry and Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, China
b.
Department of Chemistry, School of Science, Tianjin University, and Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China

Corresponding author: Xiao-Ming SHI, lixiaozeng321@tju.edu.cn Xiao-Zeng LI, shixiaoming2019@163.com
Received Date: 16 September 2019
Accepted Date: 2 December 2019

Fund Project: the Natural Science Foundation of He'nan Educational Committee of China 17A150056the National Natural Science Foundation of China 21501203the Funds of Basic and Advanced Technology Research Project of Henan Province of China 192012310497the Research Fund for the Doctoral Program of Higher Education of China ZKNUB2013003the Funds of Zhoukou Normal University ZKNUB115202

Figures(9)

Two new heterobimetallic coordination polymers {[Co(NiL)(H₂O)₃]·4H₂O}_n (1) and {[Cu(NiL)(H₂O)₃]·4H₂O}_n (2) were synthesized based on metalloligand under the same self-assembly conditions. X-ray diffraction analyses reveal that the two compounds involve close-packed zigzag chains, which expand into various three-dimensional supramolecular frameworks through the second interactions such as hydrogen bonds and π∙∙∙π stacking interactions. In these two compounds, NiL as a bridging ligand chelates the metal ion nodes via two oxamido carbonyls and carboxylate oxygen atom. The central Co(II) and Cu(II) ions in 1 and 2 both exhibit distorted octahedral coordination geometry. They are bridged by macrocyclic oxamido metalloligands fusing the zigzag chains with a ''head-to-tail'' arrangement. The Ni(II) ion in metalloligand is coordinated by four nitrogen atoms with the [NiN4] chromophore exhibiting distorted planarity. The two investigated compounds were further characterized by thermogravimetric analysis and FT-IR spectroscopy. The fluorescent properties of 1 and 2 in the solid state were also investigated.
- zigzag chain,
- heterobimetallic,
- metalloligand,
- crystal structure,
- fluorescence
1. [1]
  Furukawa, H.; Cordova, K. E.; Keeffe, M. O'; Yaghi, O. M. The chemistry and applications of metal-organic frameworks. Science 2013, 431, 974–986.
2. [2]
  Gascon, J.; Corma, A.; Kapteijn, F.; Llabrés, I.; Xamena, F. X. Metal organic framework catalysis: Quo vadis? ACS Catal. 2014, 4, 361–378. doi: 10.1021/cs400959k
3. [3]
  Tao, B.; Jiang, X.; Li, X. W.; Zhu, Y. F.; Xia, H. A two-dimensional coordination polymer with a brick wall structure: synthesis, crystal structure, and properties of a nickel(II) hexaazamacrocyclic complex with azido ligand. J. Mol. Struct. 2011, 1003, 111–114. doi: 10.1016/j.molstruc.2011.07.047
4. [4]
  Amiria, N.; Hajji, M.; Taheur, F. B.; Chevreux, S.; Roisnel, T.; Lemercier, G.; Nasri, H. Two novel magnesium(II) meso-tetraphenylporphyrin-based coordination complexes: syntheses, combined experimental and theoretical structures elucidation, spectroscopy, photophysical properties and antibacterial activity. J. Solid State Chem. 2018, 258, 477–484. doi: 10.1016/j.jssc.2017.11.018
5. [5]
  Cador, O.; Mathonière, C.; Kahn, O. Optical absorption spectroscopy of the tetranuclear compound [Mn{Cu(oxpn)}₃](ClO₄)₂·2H₂O (oxpn = N, N΄-bis(3-aminopropyl)oxamide): complementarity with magnetic properties. Inorg. Chem. 1997, 36, 1923–1928. doi: 10.1021/ic960857q
6. [6]
  Wu, H.; Yang, J.; Liu, Y. Y.; Ma, J. F. pH-controlled assembly of two unusual entangled motifs based on a tridentate ligand and octamolybdate clusters: 1D + 1D → 3D poly-pseudorotaxane and 2D → 2D → 3D polycatenation. Cryst. Growth Des. 2012, 12, 2272–2276. doi: 10.1021/cg201555f
7. [7]
  Ramaswamy, P.; Wong, N. E.; Shimizu, G. K. H. MOFs as proton conductors-challenges and opportunities. Chem. Soc. Rev. 2014, 43, 5913–5932. doi: 10.1039/C4CS00093E
8. [8]
  Madalan, A. M.; Avarvari, N.; Andruh, M. Rational design of supramolecular gridlike layers and zigzag chains through a unique interplay of d¹⁰-d¹⁰ and π-π stacking interactions. Cryst. Growth Des. 2006, 06, 1671–1675. doi: 10.1021/cg060131x
9. [9]
  Arellano, C. R. D.; Escrivà, E.; Gómez-García, C. J.; Espallargas, G. M.; Ballesterosa R.; Abarcaa, B. Hydrogen bonding versus π-stacking in ferromagnetic interactions. Studies on a copper triazolopyridine complex. CrystEngComm. 2013, 15, 1836–1839. doi: 10.1039/c2ce26654g
10. [10]
  Kounavi, K. A.; Moushi, E. E.; Manos, M. J.; Papatrianta-fyllopoulou, C.; Tasiopoulosb, A. J.; Nastopoulos, V. Supramolecular patterns of cationic and neutral Ni(II) complexes from the interplay of hydrogen-bonding, stacking interactions and metal-coordination motifs. CrystEngComm. 2012, 14, 6492–6502. doi: 10.1039/c2ce25704a
11. [11]
  Zhu, L. N.; Xu, N.; Zhang, W.; Liao, D. Z.; Yoshimura, K.; Mibu, K.; Jiang, Z. H.; Yan, S. P.; Cheng, P. Heteronuclear complexes of macrocyclic oxamide with co-ligands: syntheses, crystal structures, and magnetic properties. Inorg. Chem. 2007, 46, 1297–1304. doi: 10.1021/ic061792m
12. [12]
  Li, X. Z.; Hao, P. P.; Wang, D.; Zhu, L. N. Analysis of factors governing the formation of single-stranded helical coordination polymers from a macrocyclic metalloligand and Ca²⁺, Mn²⁺, Fe²⁺, Co²⁺, Ni²⁺, Cu²⁺, Zn²⁺ and Pb²⁺. CrystEngComm. 2013, 15, 2800–2803. doi: 10.1039/c3ce40124c
13. [13]
  Li, X. Z.; Hao, P. P.; Wang, D.; Zhang, W. Q.; Zhu, L. N. New metalloligands suitable for the construction of polynuclear complexes and coordination polymers with exposed metal sites. CrystEngComm. 2012, 14, 366–369. doi: 10.1039/C1CE06273E
14. [14]
  Ou, G. C.; Liao, Y.; Xiang, Y. F.; Yuan, X. Y.; Li, Z. Z. Syntheses and structures of three hybrid materials using vanadium polyoxoanions and macrocyclic copper complex as building blocks. Chin. J. Struct. Chem. 2017, 36, 135–142.
15. [15]
  Chen, B.; Xiang, S.; Qian, G. Metal-organic frameworks with functional pores for recognition of small molecules. Acc. Chem. Res. 2010, 43, 1115–1124. doi: 10.1021/ar100023y
16. [16]
  Sun, Y. Q.; Fan, L. L.; Gao, D. Z.; Wang, Q. L.; Du, M.; Liao, D. Z.; Zhang, C. X. Polynuclear complexes of macrocyclic oxamide with 5-sulfosalicylate: syntheses, crystal structures and magnetic properties. Dalton Trans. 2010, 39, 9654–9661. doi: 10.1039/c0dt00082e
17. [17]
  Sun, Y. Q.; Liu, S. Y.; Wang, J. Heterometallic trinuclear Ni₂Zn and Ni₂Mn complexes of macrocyclic oxamide: synthesis and crystal structures. Chin. J. Struct. Chem. 2013, 32, 39–44.
18. [18]
  Baron, V.; Gillon, B.; Plantevin, O.; Cousson, A.; Mathonière, C.; Kahn, O.; Grand, A.; Öhrström, L.; Delley, B. Spin-density maps for an oxamido-bridged Mn(II) Cu(II) binuclear compound. Polarized neutron diffraction and theoretical studies. J. Am. Chem. Soc. 1996, 118, 11822–11830. doi: 10.1021/ja961545p
19. [19]
  Shi, X. M.; Li, X. Z.; Ding, B. B.; Zhu, L. N. Synthesis, structures, and properties of new discrete hetero-tetranuclear metallocycle complexes based on macrocyclic oxamide metalloligands. Z. Anorg. Allg. Chem. 2013, 639, 592–599. doi: 10.1002/zaac.201200411
20. [20]
  Black, D. S. C.; Moss, G. I. Metal template reactions. XXIII. Synthesis of macrocyclic amide and ester complexes via 1, 1΄-oxalylbisisatin. Aust. J. Chem. 1987, 40, 129–142. doi: 10.1071/CH9870129
21. [21]
  Sheldrick, G. M. SHELXS-97, Program for Crystal Structure Solution. University of Göttingen, Germany 1997.
22. [22]
  Sheldrick, G. M. SHELXL-97, Program for the Refinement of Crystal Structure. University of Göttingen, Germany 1997.
23. [23]
  Felices, L. S.; Vitoria, P.; Gutiérrez-Zorrilla, J. M.; Lezama, L.; Reinoso, S. Hybrid inorganic-metalorganic compounds containing copper(II)-monosubstituted keggin polyanions and polymeric copper(I) complexes. Inorg. Chem. 2006, 45, 7748–7757. doi: 10.1021/ic060762g
24. [24]
  Wang, D.; Niu, C. J.; Li, X. Z.; Zhu, L. N.; Hao, P. P. Syntheses, crystal structures and properties of lanthanide complexes featuring infinite molecular rectangle strands constructed from a new macrocyclic metalloligand. Inorg. Chem. Acta 2012, 391, 20–27. doi: 10.1016/j.ica.2012.05.005
25. [25]
  Meng, F.; Zhang, M.; Shen, K.; Li, Y.; Zheng, H. A series of MOFs based on a triangular tri(4-pyridylphenyl)amine ligand combined with carboxylate or nitrate auxiliary ligands. Dalton Trans. 2015, 44, 1412–1419. doi: 10.1039/C4DT02811B
26. [26]
  Sun, J. Y.; Wang, L.; Zhang, D. J.; Li, D.; Cao, Y.; Zhang, L. Y.; Zeng, S. L.; Pang, G. S.; Fan, Y.; Xu, J. N.; Song, T. Y. Construction of metal-organic coordination polymers derived from 4-substituted tetrazole-benzoate ligands: synthesis, structure, luminescence, and magnetic behaviors. CrystEngComm. 2013, 15, 3402–3411. doi: 10.1039/c2ce26793d
27. [27]
  Cui, P.; Chen, Z.; Gao, D.; Zhao, B.; Shi, W.; Cheng, P. Syntheses, structures, and photoluminescence of a series of three-dimensional Cd(II) frameworks with a flexible ligand, 1, 5-bis(5-tetrazolo)-3-oxapentane. Cryst. Growth Des. 2010, 10, 4370–4378. doi: 10.1021/cg100467p
28. [28]
  Chen, B. L.; Yang, Y.; Zapata, F.; Qian, G. D.; Luo, Y. S.; Zhang, J. H.; Lobkovsky, E. B. Enhanced near-infrared-luminescence in an erbium tetrafluoroterephthalate framework. Inorg. Chem. 2006, 45, 8882–8886. doi: 10.1021/ic060568u
29. [29]
  Fabbrizzi, L.; Licchelli, M.; Pallavicini, P.; Perotti, A.; Sacchi, D. An anthracene-based fluorescent sensor for transition meal ions. Angew. Chem. Int. Ed. Engl. 1994, 33, 1975–1977. doi: 10.1002/anie.199419751
30. [30]
  Rurack, K. Flipping the light switch 'ON'-the design of sensor molecules that show cation-induced fluorescence enhancement with heavy and transition metal ions. Spectrochim. Acta A 2001, 57, 2161–2195. doi: 10.1016/S1386-1425(01)00492-9
31. [31]
  Wang, C.; Niu, J.; Li, J.; Ma, X. X. Synthesis, characterization, structures and Suzuki coupling reaction of Cu(II) complexes derived from N and O-containing organic ligand. Inorg. Chem. Acta 2017, 464, 81–87. doi: 10.1016/j.ica.2017.04.061
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