Citation: Bu-Tong LI, Lu-Lin LI, Jia-Xin HE. Looking for High Energy Density Molecules in the Nitro-substituted Derivatives of Pyridazine[J]. Chinese Journal of Structural Chemistry, ;2020, 39(5): 849-854. doi: 10.14102/j.cnki.0254–5861.2011–2531 shu

Looking for High Energy Density Molecules in the Nitro-substituted Derivatives of Pyridazine

School of Chemistry and Materials Science, Guizhou Education University, Guiyang 550018, China

Corresponding author: Bu-Tong LI, libutong@hotmail.com
Received Date: 15 July 2019
Accepted Date: 18 September 2019

Fund Project: the Foundation of Natural Science of Guizhou Education University 14BS017

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A series of derivatives of pyridazine were designed through substituting hydrogens on the pyridazine ring with nitro groups. To explore the thermal stability of the title molecules, heats of formation, bond dissociation energies, and bond orders were calculated at the B3PW91/6-311+G(d, p) level. To confirm the potential usage as high energy density compounds, the detonation pressure and detonation velocity were predicted by using the empirical Kamlet-Jacobs (K-J) equation. Based on our calculated results, both thermal and kinetic stabilities of the title molecules are confirmed with good detonation characters. Especially, 3, 4, 5-trinitropyridazide and 3, 4, 6-trinitropyridazide represent excellent detonation parameters better than 1, 3, 5-trinitro-1, 3, 5-triazacyclohexane (RDX) and are screened out as potential high energy density compounds.
- quantum chemistry,
- high energy density compounds,
- density functional theory,
- Kamlet-Jacobs equation
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