Citation: Dan WU, Yun-Long ZHONG, Shao-Yan LU, Chun-Juan GAO, Ze-Jiang WANG, Xi-Ping HUANG. Synthesis via Precursor Method and Shape Evolution of Basic Magnesium Carbonate[J]. Chinese Journal of Structural Chemistry, ;2020, 39(3): 543-550. doi: 10.14102/j.cnki.0254–5861.2011–2456 shu

Synthesis via Precursor Method and Shape Evolution of Basic Magnesium Carbonate

Institute of Tianjin Seawater Desalination and Multipurpose Utilization, Ministry of Natural Resources, Tianjin 300192, China

Corresponding author: Dan WU, wudan_jay@126.com
Received Date: 14 May 2019
Accepted Date: 11 November 2019

Fund Project: Special Funds for Central Public Welfare Scientific Research Institutes K-JBYWF-2017-T06Tianjin Science and Technology Supports Key Projects 18YFZCSF00350

Figures(10)

Basic magnesium carbonate (4MgCO₃·Mg(OH)₂·4H₂O) with spherical-like structure was synthesized through precursors thermal decomposition. The precursor of magnesium carbonate trihydrates (MgCO₃·3H₂O) was synthesized by brine and ammonium bicarbonate, and the thermal decomposition conditions were investigated in detail. The obtained particulate was characterized using SEM, XRD and laser particle analyzer. The result showed that it was easy to obtain spherical-like 4MgCO₃·Mg(OH)₂·4H₂O by precursor thermal decomposition at 80~100 ℃ with thermal decomposition time 90 min, stirring time 15 min and the liquid initial concentration 0.1 mol/L, while rod-like 4MgCO₃·Mg(OH)₂·4H₂O with a surface of "house of card" structure was more likely to be obtained at low temperature (55 ℃), and rosette-like products were obtained at a little higher temperature (80 ℃) by direct synthesis.
- precursor,
- basic magnesium carbonate,
- thermal decomposition,
- brine
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