Citation: Wei-Guang YANG, Zhi-Wei GONG, Yan-Ning CHEN, Ru-Ru CHEN, Dong-Li MENG, Min-Na CAO. Nitrogen Doped Carbon as Efficient Catalyst toward Oxygen Reduction Reaction[J]. Chinese Journal of Structural Chemistry, ;2020, 39(2): 287-293. doi: 10.14102/j.cnki.0254–5861.2011–2446 shu

Nitrogen Doped Carbon as Efficient Catalyst toward Oxygen Reduction Reaction

Wei-Guang YANG ^{a, b} ,
Zhi-Wei GONG ^{a, b} ,
Yan-Ning CHEN ^{a, b} ,
Ru-Ru CHEN ^{a, b} ,
Dong-Li MENG ^b ,
Min-Na CAO ^{a, b,,}

a.
College of Chemistry, Fuzhou University, Fuzhou 350108, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Min-Na CAO, mncao@fjirsm.ac.cn
Received Date: 6 May 2019
Accepted Date: 22 July 2019

Fund Project: the National Key R & D Program 2017YFA0206800the National Key R & D Program of China 2017YFA0700100the NSFC 21573238the NSFC 21571177the NSFC 21520102001Key Research Program of Frontier Science, CAS QYZDJ-SSW-SLH045"Strategic Priority Research Program" of the Chinese Academy of Sciences XDB20000000

Figures(7)

A kind of nitrogen-doped carbon (NC) nanomaterials was prepared via calcining the nitrogen-rich organic molecular glycoluril under nitrogen atmosphere. Elemental analysis result indicates the N content of the obtained NC is 13.9 wt.%. Electrochemical measurement demonstrated that the obtained NC catalyst is an efficient ORR electrocatalyst in alkaline electrolyte. The process of ORR is dominated by a four-electron transfer pathway with the most efficient catalytic activity. In addition, the NC catalyst exhibits excellent stability and good resistance to methanol poisoning. After 10000 s of chronoamperometric durability test, the relative current of NC catalyst retained as high as 95%. This work provides a new strategy for the preparation of cost-effective ORR catalysts with high catalytic performance.
- nitrogen-doped carbon,
- oxygen reduction reaction,
- electrochemical catalysis
1. [1]
  Jacobson, M. Z. Review of solutions to global warming, air pollution, and energy security. Energy Environ. Sci. 2009, 2, 148–173. doi: 10.1039/B809990C
2. [2]
  Yuan, K.; Sfaelou, S.; Qiu, M.; Lutzenkirchen-Hecht, D.; Zhuang, X. D.; Chen, Y. W.; Yuan, C.; Feng, X. L.; Scherf, U. Synergetic contribution of boron and Fe–N_x species in porous carbons toward efficient electrocatalysts for oxygen reduction reaction. ACS Energy Lett. 2017, 3, 252–260.
3. [3]
  Chen, Y. J.; Ji, S. F.; Wang, Y. G.; Dong, J. C.; Chen, W. X.; Li, Z.; Shen, R. A.; Zheng, L. R.; Zhuang, Z. B.; Wang, D. S.; Li, Y. D. Isolated single iron atoms anchored on N-doped porous carbon as an efficient electrocatalyst for the oxygen reduction reaction. Angew. Chem. Int. Ed. 2017, 56, 6937–6941. doi: 10.1002/anie.201702473
4. [4]
  Lee, J. S.; Cao, R.; Choi, N. S.; Liu, M.; Lee, K. T. Metal-air batteries with high energy density: Li-air versus Zn-air. Adv. Energy Mater. 2011, 1, 34–50. doi: 10.1002/aenm.201000010
5. [5]
  Nie, Y.; Li, L.; Wei, Z. D. Recent advancements in Pt and Pt-free catalysts for oxygen reduction reaction. Chem. Soc. Rev. 2015, 44, 2168–2201. doi: 10.1039/C4CS00484A
6. [6]
  Sheng, T.; Tian, N.; Zhou, Z. Y.; Lin, W. F.; Sun, S. G. Designing Pt-based electrocatalysts with high surface energy. ACS Energy Lett. 2017. 2. 1892–1900.
7. [7]
  Gewirth, A. A.; Varnell, J. A.; DiAscro, A. M. Nonprecious metal catalysts for oxygen reduction in heterogeneous aqueous systems. Chem. Rev. 2018, 118, 2313–2339. doi: 10.1021/acs.chemrev.7b00335
8. [8]
  Gong, K. P.; Du, F.; Xia, Z. H.; Durstock, M.; Dai, L. M. Nitrogen-doped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction. Science 2009, 323, 760–764. doi: 10.1126/science.1168049
9. [9]
  Wang, Y.; Li, J.; Wei, Z. D. Recent progress of carbon-based materials in oxygen reduction reaction catalysis. ChemElectroChem. 2018, 5, 1764–1774. doi: 10.1002/celc.201701335
10. [10]
  Yasuda, S.; Yu, L.; Kim, J.; Murakoshi, K. Selective nitrogen doping in graphene for oxygen reduction reactions. Chem. Commun. 2013, 49, 9627–9629. doi: 10.1039/c3cc45641b
11. [11]
  Mao, Y.; Duan, H.; Xu, B.; Zhang, L.; Hu, Y. S.; Zhao, C. C.; Wang, Z. X.; Chen, L. Q.; Yang, Y. S. Lithium storage in nitrogen-rich mesoporous carbon materials. Energy Environ. Sci. 2012, 5, 7950–7955. doi: 10.1039/c2ee21817h
12. [12]
  Ma, X.; Zhao, X.; Huang, J. S.; Sun, L. T.; Li, Q.; Yang, X. R. Fine Co nanoparticles encapsulated in a N-doped porous carbon matrix with superficial N-doped porous carbon nanofibers for efficient oxygen reduction. ACS Appl. Mater. Inter. 2017, 9, 21747–21755. doi: 10.1021/acsami.7b02490
13. [13]
  Ismagilov, Z. R.; Shalagina, A. E.; Podyacheva, O. Y.; Ischenko, A. V.; Kibis, L. S.; Boronin, A. I.; Chesalov, Y. A.; Kochubey, D. I.; Romanenko, A. I.; Anikeeva, O. B.; Buryakov, T. I.; Tkachev, E. N. Structure and electrical conductivity of nitrogen-doped carbon nanofibers. Carbon 2009, 47, 1922–1929. doi: 10.1016/j.carbon.2009.02.034
14. [14]
  White, R. J.; Yoshizawa, N.; Antonietti, M.; Titirica, M. M. A sustainable synthesis of nitrogen-doped carbon aerogels. Green Chem. 2011, 13, 2428–2434. doi: 10.1039/c1gc15349h
15. [15]
  Jurewicz, K.; Babeł, K.; Pietrzak, R.; Delpeux, S.; Wachowska, H. Capacitance properties of multi-walled carbon nanotubes modified by activation and ammoxidation. Carbon 2006, 44, 2368–2375. doi: 10.1016/j.carbon.2006.05.044
16. [16]
  Zhang, L. J.; Wang, X. Y.; Wang, R. H.; Hong, M. C. Structural evolution from metal-organic framework to hybrids of nitrogen-doped porous carbon and carbon nanotubes for enhanced oxygen reduction activity. Chem. Mater. 2015, 27, 7610–7618. doi: 10.1021/acs.chemmater.5b02708
17. [17]
  Zhong, S.; Zhan, C. X.; Cao, D. P. Zeolitic imidazolate framework-derived nitrogen-doped porous carbons as high performance supercapacitor electrode materials. Carbon 2015, 85, 51–59. doi: 10.1016/j.carbon.2014.12.064
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