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Citation: Yan-Ning CHEN, Jing-Jun LI, Wei-Guang YANG, Shui-Ying GAO. Fabrication and Catalytic Properties of Films Based on Metal Ion-ligand Interaction between K2PdCl4 and 3-Amino-3-(4-pyridinyl)-propionitrile[J]. Chinese Journal of Structural Chemistry, ;2020, 39(3): 526-534. doi: 10.14102/j.cnki.0254–5861.2011–2427 shu

Fabrication and Catalytic Properties of Films Based on Metal Ion-ligand Interaction between K2PdCl4 and 3-Amino-3-(4-pyridinyl)-propionitrile

  • a.

    College of Chemistry, Fuzhou University, Fuzhou 350002, China

  • b.

    State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

  • Corresponding author: Shui-Ying GAO, gaosy@fjirsm.ac.cn
  • Received Date: 24 April 2019
    Accepted Date: 4 September 2019

    Fund Project: National Key Research and Development Program of China 2017YFA0700100the NSFC 21520102001the NSFC 51572260the NSFC 21571177Strategic Priority Research Program of the Chinese Academy of Sciences XDB20000000Key Research Program of the Chinese Academy of Sciences QYZDJ-SSW-SLH045

Figures(8)

  • This work presents a highly active and reusable heterogeneous film catalytic assembly for hydrogenation reduction of aromatic nitro compounds. The multilayer structures of PEI-(K2PdCl4-P1)n-film (PEI = polyethylenmine, P1 = 3-amino-3-(4-pyridinyl)-propionitrile) bound to quartz slides were fabricated by layer-by-layer (LbL) self-assembly method. Various characterization techniques including X-ray photoelectron spectroscopy (XPS), inductively coupled plasma OES spectrometer (ICP), UV-vis spectroscopy and atomic force microscopy (AFM) were employed to reveal the growth process of the resulting LbL multilayers in detail. Subsequent in situ reduction by H2 produced Pd nanoparticles embedded in such films were used as catalyst for the hydrogenation of nitroarenes. The catalytic performance test shows that the thin film catalyst can be applied to the hydrogenation reaction of various substituted nitroaromatics, and exhibits good catalytic activity and good catalyst stability. It is worth mentioning that our catalytic films can be easily removed from the reaction system in any time during the reaction, and the catalytic activity could be fully recovered when reused directly in another catalytic cycle for five times.
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