Citation: Geng XUE, Xin CHEN, Chuan-Xin ZHENG, Guo-Qiang WANG, Ling-Yun LI. Color-tunable Upconversion Properties of Tb³⁺/Er³⁺/Yb³⁺ Tri-doped Na₅Gd(WO₄)₄ Crystals[J]. Chinese Journal of Structural Chemistry, ;2020, 39(2): 301-309. doi: 10.14102/j.cnki.0254–5861.2011–2422 shu

Color-tunable Upconversion Properties of Tb³⁺/Er³⁺/Yb³⁺ Tri-doped Na₅Gd(WO₄)₄ Crystals

a.
College of Civil Engineering, Fuzhou University, Fuzhou 350108, China
b.
Key Laboratory of Eco-materials Advanced Technology, College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, China

Corresponding author: Guo-Qiang WANG, gqwang@fzu.edu.cn Ling-Yun LI, lilingyun@fzu.edu.cn
Received Date: 22 April 2019
Accepted Date: 22 July 2019

Fund Project: the Natural Science Foundation of Fujian Province 2017J01746

Figures(9)

In this work, novel phosphors Na₅Gd(WO₄)₄: Tb³⁺/Yb³⁺ and Na₅Gd(WO₄)₄: Tb³⁺/Er³⁺/Yb³⁺ phosphors were synthesized by the solid state reaction method. The photoluminescence properties were investigated. The introduction of Er³⁺ to NGW: Tb³⁺/Yb³⁺ was used to modify the chromaticity coordinates, then providing a good color tunable property. The change in the chromaticity coordinates induces the shift of emission color from yellow-green to blue-green for NGW: Tb³⁺/Er³⁺/Yb³⁺ as the temperature increases. All the results indicate that the NGW: Er³⁺/Tb³⁺/Yb³⁺ phosphors may be used as optical temperature sensing materials.
- Na₅Gd(WO₄)₄: Tb³⁺/Er³⁺/Yb³⁺ phosphor,
- upconversion luminescence,
- color-tunable
1. [1]
  Dong, B.; Cao, B. S.; He, Y. Y.; Liu, Z.; Li, Z. P.; Feng, Z. Q. Temperature sensing and in vivo imaging by molybdenum sensitized visible upconversion luminescence of rare-earth oxides. Adv. Mater. 2012, 24, 1987-1993. doi: 10.1002/adma.201200431
2. [2]
  Wang, X. D.; Wolfbeis, O. S.; Meier, R. J. Luminescent probes and sensors for temperature. Chem. Soc. Rev. 2013, 42, 7834-7869. doi: 10.1039/c3cs60102a
3. [3]
  McLaurin, E. J.; Bradshaw, L. R.; Gamelin, D. R. Dual-emitting nanoscale temperature sensors. Chem. Mater. 2013, 25, 1283-1292. doi: 10.1021/cm304034s
4. [4]
  Alencar, M. A. R. C.; Maciel, G. S.; de Araújo, C. B.; Patra, A. Er³⁺-doped BaTiO₃ nanocrystals for thermometry: influence of nanoenvironment on the sensitivity of a fluorescence based temperature sensor. Appl. Phys. Lett. 2004, 84, 4753-4755. doi: 10.1063/1.1760882
5. [5]
  Xu, W.; Gao, X. Y.; Zheng, L. J.; Zhang, Z. G.; Cao, W. W. Shortwavelength upconversion emissions in Ho³⁺/Yb³⁺ codoped glass ceramic and the optical thermometry behavior. Opt. Express 2012, 20, 18127-18137. doi: 10.1364/OE.20.018127
6. [6]
  Xing, L. L.; Yang, W. Q.; Ma, D. C.; Wang, R. Effect of crystallinity on the optical thermometry sensitivity of Tm³⁺/Yb³⁺ codoped LiNbO₃ crystal. Sens. Actuators B 2015, 221, 458-462. doi: 10.1016/j.snb.2015.06.132
7. [7]
  Mahata, M. K.; Koppe, T.; Mondal, T.; Brusewitz, C.; Kumar, K.; Rai, V. K.; Hofsäss, H.; Vetter, U. Incorporation of Zn²⁺ Ions into BaTiO₃: Er³⁺/Yb³⁺ nanophosphor: an effective way to enhance upconversion, defect luminescence and temperature sensing. Phys. Chem. Chem. Phys. 2015, 17, 20741-20753. doi: 10.1039/C5CP01874A
8. [8]
  Liu, S.; Ming, H.; Cui, J.; Liu, S.; You, W.; Ye, X.; Yang, Y.; Nie, H.; Wang, R. Color-tunable upconversion luminescence and multiple temperature sensing and optical heating properties of Ba₃Y₄O₉: Er³⁺/Yb³⁺ phosphors. J. Phys. Chem. C 2018, 122, 16289-16303. doi: 10.1021/acs.jpcc.8b04180
9. [9]
  Grzyb, T.; Gruszeczka, A.; Wigluszb, R. J.; Lis, S. The effects of down- and up-conversion on dual-mode green luminescence from Yb³⁺- and Tb³⁺-doped LaPO₄ nanocrystals. J. Mater. Chem. C 2013, 1, 5410-5418. doi: 10.1039/c3tc31100g
10. [10]
  Wang, G. Q.; Li, L. Y.; Feng, Y. N.; Yu, H.; Zheng, X. H. Tb³⁺- and Yb³⁺-doped novel KBaLu(MoO₄)₃ crystals with disordered chained structure showing down- and up-conversion luminescence. CrystEngComm. 2018, 20, 3657-3665. doi: 10.1039/C8CE00461G
11. [11]
  Geng, D.; Li, G.; Shang, M.; Yang, D.; Zhang, Y.; Cheng, Z.; Lin, J. Color tuning via energy transfer in Sr₃In(PO₄)₃: Ce³⁺/Tb³⁺/Mn²⁺ phosphors. J. Mater. Chem. C 2012, 22, 14262-14271. doi: 10.1039/c2jm32392c
12. [12]
  Sun, J.; Lai, J.; Xia, Z.; Zhang, X.; Liu, H.; Du, H. Luminescence properties and energy transfer in Ba₂Y(BO₃)₂Cl: Ce³⁺, Tb³⁺ phosphors. Appl. Phys. B 2012, 107, 827-831. doi: 10.1007/s00340-012-4961-5
13. [13]
  Sillén, L. G.; Sundvall, H. Double molybdates and tungstates of alkali metals with lanthanum or bismuth. Ark. Kemi Mineral Geol. 1943, A17, 1-18.
14. [14]
  Hong, H. Y. P.; Dwight, K. Crystal structure and fluorescence lifetime of a laser material NdNa₅(WO₄)₄. Mat. Res. Bull. 1974, 9, 775-780. doi: 10.1016/0025-5408(74)90112-3
15. [15]
  Pan, J.; Yau, L.; Chen, L.; Zhao, G.; Zhou, G.; Guo, C. Studies on spectra properties of Na₅Eu(WO₄)₄ luminescent crystal. J. Lumin. 1988, 40, 856-857.
16. [16]
  Huang, D.; Zhou, Y.; Xu, W.; Yang, Z.; Liu, Z.; Hong, M.; Lin, Y.; Yu, J. Photoluminescence properties of M³⁺ (M³⁺ = Bi³⁺, Sm³⁺) activated Na₅Eu(WO₄)₄ red-emitting phosphors for white LEDs. J. Alloys Compd. 2013, 554, 312-318. doi: 10.1016/j.jallcom.2012.11.172
17. [17]
  Wang, G. Q.; Lin, Y. P.; Ye, R.; Feng, Y. N.; Li, L. Y. Pr³⁺ and Tb³⁺ coactivated Na₅Gd(WO₄)₄ showing tunable luminescence with high thermostability via modulation of excitation and temperature. J. Alloys Compd. 2019, 779, 41-48. doi: 10.1016/j.jallcom.2018.11.223
18. [18]
  Perets, S.; Tseitlin, M.; Shneck, R. Z.; Mogilyanski, D.; Kimmel, G.; Burshtein, Z. Sodium gadolinium tungstate NaGd(WO₄)₂: growth, crystallography, and some physical properties. J. Cryst. Growth 2007, 305, 257-264. doi: 10.1016/j.jcrysgro.2007.03.058
19. [19]
  Shannon, R. D. T.; Prewitt, C. T. Effective ionic radii in oxides and fluorides. Acta Crystallogr. B 1969, 25, 925-946. doi: 10.1107/S0567740869003220
20. [20]
  Cavalli, E.; Boutinaud, P.; Mahiou, R.; Bettinelli, M.; Dorenbos, P. Luminescence dynamics in Tb³⁺-doped CaWO₄ and CaMoO₄ crystals. Inorg. Chem. 2010, 49, 4916-4921. doi: 10.1021/ic902445c
21. [21]
  Annadurai, G.; Jayachandiran, M.; Kennedy, S. M. M.; Sivakumar, V. Synthesis and photoluminescence properties of Ba₂CaZn₂Si₆O₁₇: Tb³⁺ green phosphor. Mat. Sci. Eng. B 2016, 208, 47-52. doi: 10.1016/j.mseb.2016.02.008
22. [22]
  Auzel, F. Upconversion processes in coupled ion systems. J. Lumin. 1990, 45, 341-345. doi: 10.1016/0022-2313(90)90189-I
23. [23]
  Salley, G. M.; Valiente, R.; Guedel, H. U. Luminescence upconversion mechanisms in Yb³⁺–Tb³⁺ systems. J. Lumin. 2001, s94-95, 305-309.
24. [24]
  Gao, Y.; Huang, F.; Lin, H.; Zhou, J.; Xu, J.; Wang, Y. A novel optical thermometry strategy based on diverse thermal response from two intervalence charge transfer states. Adv. Funct. Mater. 2016, 26, 3139-3145. doi: 10.1002/adfm.201505332
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沈阳化工大学材料科学与工程学院沈阳 110142

Color-tunable Upconversion Properties of Tb3+/Er3+/Yb3+ Tri-doped Na5Gd(WO4)4 Crystals

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通讯作者: 陈斌, bchen63@163.com

Color-tunable Upconversion Properties of Tb³⁺/Er³⁺/Yb³⁺ Tri-doped Na₅Gd(WO₄)₄ Crystals