Citation: Jiu-Fu LU, Juan ZHAO, Cai-Bin ZHAO, Xiao-Hu YU, Kumar Roy SOUMENDRA, Si-Yu YUE, Li LI, Ke ZHOU, Ling-Xia JIN, Hong-Guang GE. A Chinese Lantern-like 2D Cu(Ⅱ) Coordination Polymer Constructed by Bis-imidazole and Dicarboxylate Co-ligands: Synthesis, Crystal Structure and Photocatalytic Activity[J]. Chinese Journal of Structural Chemistry, ;2020, 39(2): 321-328. doi: 10.14102/j.cnki.0254–5861.2011–2339 shu

A Chinese Lantern-like 2D Cu(Ⅱ) Coordination Polymer Constructed by Bis-imidazole and Dicarboxylate Co-ligands: Synthesis, Crystal Structure and Photocatalytic Activity

Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology, Hanzhong 723001, China

Corresponding author: Ling-Xia JIN, jinlx@snut.edu.cn Hong-Guang GE, gehg@snut.edu.cn
Received Date: 2 February 2019
Accepted Date: 21 October 2019

Fund Project: the team of syngas catalytic conversion of Shaanxi University of Technology, the National Natural Science Foundation of China 21373132the team of syngas catalytic conversion of Shaanxi University of Technology, the National Natural Science Foundation of China 21603133Key scientific research project of education department of Shaanxi province 18JS023Shaanxi provincial science and technology department project 2018JM2043Shaanxi provincial science and technology department project 2019JQ149Shaanxi provincial science and technology department project 2019JM471the Science Foundation of Shaanxi University of Technology SLGQD2017-14

Figures(9)

A new Cu(Ⅱ) coordination polymer, {[Cu(1, 3-BIP)(TFBDC)]·DMF}_n (1, 1, 3-BIP is a 1, 3-bis(imidazole)propane, and H₂TFBDC is 2, 3, 5, 6-tetrafluoroterephthalic acid) was prepared under solvothermal conditions and characterized by single-crystal and powder X-ray diffraction, IR spectra, thermogravimetric analyses and elemental analyses. The single-crystal X-ray diffraction reveals that metal coordination polymer 1 (MCP 1) shows a two-dimensional sheet layer structure, which is further reinforced through strong intermolecular hydrogen bonding to form a 3D supramolecular framework. Furthermore, the photocatalytic experiment result indicates the degradation ratios of methyl orange (MO) reach 83.4% within 180 minutes when MCP 1 acts as catalyst.
- solvothermal synthesis,
- crystal structure,
- Cu(Ⅱ) coordination polymer,
- photocatalytic activity
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