Citation: Jiu-Fu LU, Juan ZHAO, Cai-Bin ZHAO, Xiao-Hu YU, Kumar Roy SOUMENDRA, Si-Yu YUE, Li LI, Ke ZHOU, Ling-Xia JIN, Hong-Guang GE. A Chinese Lantern-like 2D Cu(Ⅱ) Coordination Polymer Constructed by Bis-imidazole and Dicarboxylate Co-ligands: Synthesis, Crystal Structure and Photocatalytic Activity[J]. Chinese Journal of Structural Chemistry, ;2020, 39(2): 321-328. doi: 10.14102/j.cnki.0254–5861.2011–2339 shu

A Chinese Lantern-like 2D Cu(Ⅱ) Coordination Polymer Constructed by Bis-imidazole and Dicarboxylate Co-ligands: Synthesis, Crystal Structure and Photocatalytic Activity

Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology, Hanzhong 723001, China

Corresponding author: Ling-Xia JIN, jinlx@snut.edu.cn Hong-Guang GE, gehg@snut.edu.cn
Received Date: 2 February 2019
Accepted Date: 21 October 2019

Fund Project: the team of syngas catalytic conversion of Shaanxi University of Technology, the National Natural Science Foundation of China 21373132the team of syngas catalytic conversion of Shaanxi University of Technology, the National Natural Science Foundation of China 21603133Key scientific research project of education department of Shaanxi province 18JS023Shaanxi provincial science and technology department project 2018JM2043Shaanxi provincial science and technology department project 2019JQ149Shaanxi provincial science and technology department project 2019JM471the Science Foundation of Shaanxi University of Technology SLGQD2017-14

Figures(9)

A new Cu(Ⅱ) coordination polymer, {[Cu(1, 3-BIP)(TFBDC)]·DMF}_n (1, 1, 3-BIP is a 1, 3-bis(imidazole)propane, and H₂TFBDC is 2, 3, 5, 6-tetrafluoroterephthalic acid) was prepared under solvothermal conditions and characterized by single-crystal and powder X-ray diffraction, IR spectra, thermogravimetric analyses and elemental analyses. The single-crystal X-ray diffraction reveals that metal coordination polymer 1 (MCP 1) shows a two-dimensional sheet layer structure, which is further reinforced through strong intermolecular hydrogen bonding to form a 3D supramolecular framework. Furthermore, the photocatalytic experiment result indicates the degradation ratios of methyl orange (MO) reach 83.4% within 180 minutes when MCP 1 acts as catalyst.
- solvothermal synthesis,
- crystal structure,
- Cu(Ⅱ) coordination polymer,
- photocatalytic activity
1. [1]
  Hao, H. J.; Sun, D.; Liu, F. J.; Huang, R. B.; Zheng, L. S. Dicarboxylate-controlled three Zn(Ⅱ) coordination polymers incorporating flexible 1, 2-bis(imidazol-10-yl)ethane ligand: syntheses, structures, thermal stabilities and photoluminescent properties. J. Mol. Struct. 2012, 1012, 131–136. doi: 10.1016/j.molstruc.2011.12.030
2. [2]
  Li, P. X.; Lu, J. F. A novel 3D twofold Zn(Ⅱ) coordination polymer constructed by mixed flexible ligands: synthesis, crystal structure and fluorescence property. Chin. J. Struct. Chem. 2017, 36, 303–309.
3. [3]
  Kamal, K. B.; Yadagiri, R.; Bhavesh, P.; Eringathodi, S. Mixed ligand coordination polymers with flexible bis-imidazole linker and angular sulfonyldibenzoate: crystal structure, photoluminescence and photocatalytic activity. J. Solid State Chem. 2014, 213, 43−51. doi: 10.1016/j.jssc.2014.02.007
4. [4]
  Kamal, K. B.; Yadagiri, R.; Bhavesh, P.; Bhavesh, P.; Eringathodi, S. Structural and functional studies on ternary coordination polymers from 5-bromoisophthalate and imidazole based flexible linker. RSC Adv. 2014, 4, 7352−7360. doi: 10.1039/c3ra45411h
5. [5]
  Wang, C. C.; Li, J. R.; Lv, X. L.; Zhang, Y. Q.; Guo, G. S. Photocatalytic organic pollutants degradation in metal-organic frameworks. Energy Environ. Sci. 2014, 7, 2831−2867. doi: 10.1039/C4EE01299B
6. [6]
  Tranchemontagne, D. J.; Ni, Z.; O'Keeffe, M.; Yaghi, O. Reticular chemistry of metal-organic polyhedra. Angew. Chem. Int. Ed. 2008, 47, 5136−5147. doi: 10.1002/anie.200705008
7. [7]
  Leong, W. L.; Vittal, J. J. One-dimensional coordination polymers: complexity and diversity in structures, properties, and applications. Chem. Rev. 2011, 111, 688−764. doi: 10.1021/cr100160e
8. [8]
  Renata, L.; Halina, G.; Liliana, M.; Bogdan, T.; Vasyl, K.; Alexander, M. K. Structural diversity of alkali metal coordination polymers driven by flexible biphenyl-4, 4΄-dioxydiacetic acid. J. Solid State Chem. 2018, 265, 92−99. doi: 10.1016/j.jssc.2018.05.022
9. [9]
  Osta, R. E.; Frigoli, M.; Marrot, J.; Medina, M. E.; Walton, R. I.; Millange, F.; Fei, H.; Liu, X.; Li, Z.; Feng, W. Synthesis, structure, and crystallization study of a layered lithium thiophene-dicarboxylate. Cryst. Growth Des. 2012, 12, 1531−1539. doi: 10.1021/cg201587u
10. [10]
  Qiao, Y.; Ren, S. S.; Liu, L. H.; Guan, W. S. Adsorption and photocatalytic properties of transition metal zinc(Ⅱ) complex based on 5-(4-(tetrazol-5-yl)phenyl)isophthalic acid. J. Mol. Struct. 2018, 1161, 238−254. doi: 10.1016/j.molstruc.2018.02.049
11. [11]
  Kitagawa, S.; Kitaura, R.; Noro, S. I. Functional porous coordination polymers. Angew. Chem. Int. Ed. 2004, 43, 2334−2375. doi: 10.1002/anie.200300610
12. [12]
  Zhang, Z. J.; Shi, W.; Niu, Z.; Li, H. H.; Zhao, B.; Cheng, P.; Liao, D. Z.; Yan, S. P. A new type of polyhedron-based metal-organic frameworks with interpenetrating cationic and anionic nets demonstrating ion exchange, adsorption and luminescent properties. Chem. Commun. 2001, 47, 6425−6427.
13. [13]
  Lu, J. F.; Min, S. T.; Ge, H. G. Synthesis, crystal structures and properties of two-dimensional complexes constructed by dicarboxylate and bis(imidazole) co-ligands. J. Chem. Res. 2014, 38, 726−730. doi: 10.3184/174751914X14176001751990
14. [14]
  Lu, J. F.; Liu, J.; Ge, H. G.; Jiang, M. Synthesis, structure and luminescent property of a 2D Cd(Ⅱ) coordination polymer based on mixed ligands of 1, 3-bis(imidazol)propane and pyridine-3, 5-dicarboxylic acid. Chin. J. Struct. Chem. 2015, 34, 248−252.
15. [15]
  Lu, J. F.; Xu, Y. H.; Li, P. A.; Jin, L. X.; Zhao, C. B.; Guo, X. H.; Ge, H. G. Synthesis, crystal structure, and luminescent properties of Ag(Ⅰ) coordination polymer with tricarboxylic acid and flexible N-donor ligand. Crystallogr. Rep. 2017, 2, 1046−1050.
16. [16]
  Wang, Z. J.; Qin, L.; Zhang, X.; Chen, J. X.; Zheng, H. G. Syntheses, characterizations, luminescent properties, and controlling interpenetration of five metal-organic frameworks based on bis(4-(pyridine-4-yl)phenyl)amine. Cryst. Growth Des. 2015, 44, 4670–4679.
17. [17]
  Zhang, Z. H.; Yang, X. S.; Guo, W.; Chen, S. C.; He, M. Y.; Chen, Q. Positional isomeric effect on Cu^Ⅱ and Cd^Ⅱ complexes based on perfluorinated dicarboxylate ligands and bipyridyl co-tectons. Polyhedron 2016, 117, 695–702. doi: 10.1016/j.poly.2016.07.015
18. [18]
  Li, X. Y.; Han, C. X.; Yue, K. F.; Liu, Y. L.; Zhou, C. S.; Hou, Y. F.; He, T.; Yan, T. Syntheses, structures and properties of three 4-fold interpenetration coordination polymers based on two different dia interpenetrating modes. Polyhedron 2015, 87, 156–162. doi: 10.1016/j.poly.2014.11.019
19. [19]
  Perry, J. J.; Perman, J. A.; Zaworotko, M. J. Design and synthesis of metal-organic frameworks using metal-organic polyhedra as supermolecular building blocks. Chem. Soc. Rev. 2009, 38, 1400−1417. doi: 10.1039/b807086p
20. [20]
  Ji, X. H.; Zhao, J.; Lu, J. F.; Ji, L. X.; Ge, H. G. Synthesis, Crystal Structure and Biological Activity of 1-(3-Amino-4-morpholino-1H-indazole-1-carbonyl)-N-(4-fluorophenyl)cyclopropane-1-carboxamide. Chin. J. Struct. Chem. 2019, 38, 1889−1894.
21. [21]
  Li, H. J.; He, Y. L.; Zhao, W. L.; Li, Q. Q.; Xu, Z. Q.; Wang, Y. Designing different functional frameworks from 0D to 3D for exploring structural correlation with photocatalytic activity. Polyhedron 2017, 133, 412−418. doi: 10.1016/j.poly.2017.05.009
22. [22]
  Yu, Q.; Ren, S. S.; Liu, L. H.; Guan, W. S. Adsorption and photocatalytic properties of transition metal zinc(Ⅱ) complex based on 5-(4-(tetrazol-5-yl)phenyl)isophthalic acid. J. Mol. Struct. 2018, 1161, 238−245. doi: 10.1016/j.molstruc.2018.02.049
23. [23]
  Sheldrick, G. M. SHELXS-97, Program for the Solution of Crystal Structures. University of Göttingen, Germany 1997.
24. [24]
  Sheldrick, G. M. SHELXL-97, Program for the Refinement of Crystal Structures. University of Göttingen, Germany 1997.
25. [25]
  Zhao, S.; Zheng, T. R.; Shi, L. L.; Li, K.; Li, B. L.; Li, H. Y. Two intriguing hydroxy-copper(Ⅱ) coordination polymers with bis(triazole) and bicarboxylate ligands: syntheses, structures and photocatalytic degradation of organic dyes. J. Mol. Struct. 2017, 1143, 146−152. doi: 10.1016/j.molstruc.2017.04.087
26. [26]
  Wang, F.; Liu, Z. S.; Yang, H.; Tan, Y. X.; Zhang, J. Hybrid zeolitic imidazolate frameworks with catalytically active TO₄ building blocks. Angew. Chem. Ed. Int. 2011, 50, 450−453. doi: 10.1002/anie.201005917
27. [27]
  Lu, J. F.; Wang, M. Z.; Liu, Z. H. Two novel coordination polymers constructed by the same mixed ligands of 1, 3-bip and H₂bpdc: syntheses, structures and catalytic properties. J. Mol. Struct. 2015, 1098, 41−46. doi: 10.1016/j.molstruc.2015.05.030
28. [28]
  Lu, J. F.; Jin, L. X.; Song, J.; Zhao, C. B.; Yue, S. Y.; Li, L.; Yang, H. T.; Cao, X. Y.; Ge, H. G. A novel 3D metal coordination polymer based on tetranuclear cobalt cluster building blocks: synthesis, crystal structure and photocatalytic property. Chin. J. Struct. Chem. 2018, 37, 1814−1820.
1. [1]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
2. [2]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
3. [3]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
4. [4]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
5. [5]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
6. [6]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
7. [7]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
8. [8]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
9. [9]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
10. [10]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
11. [11]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
12. [12]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
13. [13]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
14. [14]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
15. [15]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
16. [16]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
17. [17]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
18. [18]
  Xiaofen GUAN , Yating LIU , Jia LI , Yiwen HU , Haiyuan DING , Yuanjing SHI , Zhiqiang WANG , Wenmin WANG . Synthesis, crystal structure, and DNA-binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2486-2496. doi: 10.11862/CJIC.20240122
19. [19]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
20. [20]
  Jing REN , Ruikui YAN , Xiaoli CHEN , Huali CUI , Hua YANG , Jijiang WANG . Synthesis and fluorescence sensing of a highly sensitive and multi-response cadmium coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 574-586. doi: 10.11862/CJIC.20240287

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(287)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142