Citation: Xinlong Yao, Zhenchao Zhao, Guangjin Hou. Development of In Situ MAS NMR and Its Applications in Material Synthesis and Heterogeneous Catalysis[J]. Chinese Journal of Structural Chemistry, ;2022, 41(10): 221004. doi: 10.14102/j.cnki.0254-5861.2022-0166 shu

Development of In Situ MAS NMR and Its Applications in Material Synthesis and Heterogeneous Catalysis

Xinlong Yao ^{1, 2} ,
Zhenchao Zhao ^3,, ,
Guangjin Hou ^1,,

1.
State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, 2011-Collaborative Innovation Center of Chemistry for Energy Materials, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, China

Author Bio: Xinlong Yao received his B.S. degree in chemistry from Jilin University in 2018, and he is currently a Ph.D. candidate under the supervision of Prof. Guangjin Hou at Dalian Institute of Chemical Physics (DICP), Chinese Academy of Sciences (CAS). His current research interest focuses on the in situ NMR spectroscopy and its applications in material science and heterogeneous catalysis

Guangjin Hou received his Ph.D. from National Centre for Magnetic Resonance in Wuhan, Chinese Academy of Sciences (CAS), in 2007. After two postdoctoral research experiences respectively at Max-Planck Institute for Polymer Research and University of Delaware, he began his independent research career as a senior NMR scientist at the University of Delaware in 2012. Currently, he is a professor at Dalian Institute of Chemical Physics (DICP), CAS, and heading the solid-state NMR research group. Prof. Hou's research focuses on the methodology development of solid-state NMR spectroscopy and its applications in catalysis, energy storage, macromolecules, and biology systems
Corresponding author: Zhenchao Zhao, zhaoenc@zjnu.edu.cn Guangjin Hou, ghou@dicp.ac.cn
Received Date: 8 July 2022
Accepted Date: 5 August 2022
Available Online: 12 August 2022

Figures(9)

High-resolution magic angle spinning (MAS) NMR can afford both qualitative and quantitative information of the solid, liquid and gas phase at atomic level, and such information obtained at in situ/operando conditions is of vital importance for understanding the crystallization process of material as well as the reaction mechanism of catalysis. To meet the requirement of experimental conditions for material synthesis and catalytic reactions, in situ MAS NMR techniques have been continuously developed for using at higher temperatures and pressures with high sensitivity. Herein, we will briefly outline the development of this technology and discuss its detailed applications in understanding material synthesis and heterogeneous catalysis.
- in situ NMR,
- high-temperature high-pressure,
- material synthesis,
- heterogeneous catalysis,
- molecular sieves
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沈阳化工大学材料科学与工程学院沈阳 110142