Citation: Yunhui Huang. Probing Structural Evolution of High-capacity Layered Oxide Cathode[J]. Chinese Journal of Structural Chemistry, ;2022, 41(10): 221000. doi: 10.14102/j.cnki.0254-5861.2022-0164 shu

Probing Structural Evolution of High-capacity Layered Oxide Cathode

Yunhui Huang ^1,,

1.
School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 330074, China

Corresponding author: Yunhui Huang, huangyh@hust.edu.cn
Received Date: 2 July 2022
Accepted Date: 10 July 2022
Available Online: 11 July 2022

Figures(2)

LMR materials contain two structures (i.e., LiTMO₂ and Li₂MnO₃) that exhibit different electrochemical behaviors during charging/discharging. Limited by characterization techniques, this process is difficult to observe. The LiTMO₂ and Li₂MnO₃ domains share a coherent lattice at the nanoscale but exhibit differentiated electrochemical activities due to different redox chemistries. By probing the origin of structural instability, it is suggested that the lattice strain observed not only affects the electrochemical performance of LMR, but also has implication in other layered cathode materials for Li-ion batteries.
1. [1]
  Liu, T. C.; Liu, J. J.; Li, L. X.; Yu, L.; Diao, J. C.; Zhou, T.; Li, S. N.; Dai, A.; Zhao, W. G.; Xu, S. Y.; Ren, Y.; Wang, L. G.; Wu, T. P.; Qi, R.; Xiao, Y. G.; Zheng, J. X.; Cha, W.; Harder, R.; Robinson, I.; Wen, J. G.; Lu, J.; Pan, F.; Amine, K. Origin of structural degradation in Li-rich layered oxide cathode. Nature 2022, 606, 305-312. doi: 10.1038/s41586-022-04689-y
2. [2]
  Huang, W. Y.; Lin, C.; Qiu, J. M.; Li, S. N.; Chen, Z. F.; Chen, H. B.; Zhao, W. G.; Ren, G. X.; Li, X. Y.; Zhang, M. J.; Pan, F. Delocalized Li@Mn₆ superstructure units enable layer stability of high-performance Mn-rich cathode materials. Chem Doi: 10.1016/j.chempr.2022.04.012(2022).
3. [3]
  Huang, W. Y.; Yang, L. Y.; Chen, Z. F.; Liu, T. C.; Ren, G. X.; Shan, P. Z.; Zhang, B. W.; Chen, S. M.; Li, S. N.; Li, J. Y.; Lin, C.; Zhao, W. G.; Qiu, J. M.; Fang, J. J.; Zhang, M. J.; Dong, C.; Li, F.; Yang, Y.; Sun, C. J.; Ren, Y., Q. Z.; Hou, G. J.; Dou, S. X.; Lu, J.; Amine, K.; Pan, F. Elastic lattice enabling reversible tetrahedral Li storage sites in high-capacity manganese oxide cathode. Adv. Mater. Doi: 10.1002/adma.202202745(2022).
1. [1]
  Yan-Jiang Li , Shu-Lei Chou , Yao Xiao . Detecting dynamic structural evolution based on in-situ high-energy X-ray diffraction technology for sodium layered oxide cathodes. Chinese Chemical Letters, 2025, 36(2): 110389-. doi: 10.1016/j.cclet.2024.110389
2. [2]
  Yongjian Li , Xinyu Zhu , Chenxi Wei , Youyou Fang , Xinyu Wang , Yizhi Zhai , Wenlong Kang , Lai Chen , Duanyun Cao , Meng Wang , Yun Lu , Qing Huang , Yuefeng Su , Hong Yuan , Ning Li , Feng Wu . Unraveling the chemical and structural evolution of novel Li-rich layered/rocksalt intergrown cathode for Li-ion batteries. Chinese Chemical Letters, 2024, 35(12): 109536-. doi: 10.1016/j.cclet.2024.109536
3. [3]
  Qiang Wu , Baofeng Wang . Exploring synthetic strategy for stabilizing nickel-rich layered oxide cathodes through structural design. Chinese Chemical Letters, 2024, 35(12): 110089-. doi: 10.1016/j.cclet.2024.110089
4. [4]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
5. [5]
  Jinqiang Gao , Haifeng Yuan , Xinjuan Du , Feng Dong , Yu Zhou , Shengnan Na , Yanpeng Chen , Mingyu Hu , Mei Hong , Shihe Yang . Methanol steam mediated corrosion engineering towards high-entropy NiFe layered double hydroxide for ultra-stable oxygen evolution. Chinese Chemical Letters, 2025, 36(1): 110232-. doi: 10.1016/j.cclet.2024.110232
6. [6]
  Guangchang Yang , Shenglong Yang , Jinlian Yu , Yishun Xie , Chunlei Tan , Feiyan Lai , Qianqian Jin , Hongqiang Wang , Xiaohui Zhang . Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode. Chinese Chemical Letters, 2024, 35(9): 109722-. doi: 10.1016/j.cclet.2024.109722
7. [7]
  Yuhan Wu , Qing Zhao , Zhijie Wang . Layered vanadium oxides: Promising cathode materials for calcium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(5): 100271-100271. doi: 10.1016/j.cjsc.2024.100271
8. [8]
  Bing Jiang , Gang Zou , Bi Luo , Yan Guo , Jingru Li , Wendi Zhang , Qianxiao Fan , Lehao Liu , Lihua Chu , Qiaobao Zhang , Meicheng Li . Enhanced electrochemical performance of lithium-rich layered oxide materials: Exploring advanced coating strategies. Chinese Chemical Letters, 2025, 36(4): 109801-. doi: 10.1016/j.cclet.2024.109801
9. [9]
  Yunfei Shen , Long Chen . Gradient imprinted Zn metal anodes assist dendrites-free at high current density/capacity. Chinese Journal of Structural Chemistry, 2024, 43(10): 100321-100321. doi: 10.1016/j.cjsc.2024.100321
10. [10]
  Huixin Chen , Chen Zhao , Hongjun Yue , Guiming Zhong , Xiang Han , Liang Yin , Ding Chen . Unraveling the reaction mechanism of high reversible capacity CuP₂/C anode with native oxidation PO_x component for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109650-. doi: 10.1016/j.cclet.2024.109650
11. [11]
  Li Li , Fanpeng Chen , Bohang Zhao , Yifu Yu . Understanding of the structural evolution of catalysts and identification of active species during CO₂ conversion. Chinese Chemical Letters, 2024, 35(4): 109240-. doi: 10.1016/j.cclet.2023.109240
12. [12]
  Mengjun Zhao , Yuhao Guo , Na Li , Tingjiang Yan . Deciphering the structural evolution and real active ingredients of iron oxides in photocatalytic CO2 hydrogenation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100348-100348. doi: 10.1016/j.cjsc.2024.100348
13. [13]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
14. [14]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
15. [15]
  Zhongxiong Sun , Haili Song , Mei-Huan Zhao , Yijie Zeng , Man-Rong Li . Structural determination and exotic resistive behaviour of α-RuI3 under high-pressure. Chinese Journal of Structural Chemistry, 2025, 44(2): 100429-100429. doi: 10.1016/j.cjsc.2024.100429
16. [16]
  Long Li , Kang Yang , Chenpeng Xi , Mengchao Li , Borong Li , Gui Xu , Yuanbin Xiao , Xiancai Cui , Zhiliang Liu , Lingyun Li , Yan Yu , Chengkai Yang . Highly-chlorinated inert and robust interphase without mineralization of oxide enhancing high-rate Li metal batteries. Chinese Chemical Letters, 2024, 35(6): 108814-. doi: 10.1016/j.cclet.2023.108814
17. [17]
  Yue Wang , Caixia Xu , Xingtao Tian , Siyu Wang , Yan Zhao . Challenges and Modification Strategies of High-Voltage Cathode Materials for Li-ion Batteries. Chinese Journal of Structural Chemistry, 2023, 42(10): 100167-100167. doi: 10.1016/j.cjsc.2023.100167
18. [18]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
19. [19]
  Xiaoxing Ji , Xiaojuan Li , Chenggang Wang , Gang Zhao , Hongxia Bu , Xijin Xu . Ni_xB/rGO as the cathode for high-performance aqueous alkaline zinc-based battery. Chinese Chemical Letters, 2024, 35(10): 109388-. doi: 10.1016/j.cclet.2023.109388
20. [20]
  Lingjiang Kou , Yong Wang , Jiajia Song , Taotao Ai , Wenhu Li , Mohammad Yeganeh Ghotbi , Panya Wattanapaphawong , Koji Kajiyoshi . Mini review: Strategies for enhancing stability of high-voltage cathode materials in aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 110368-. doi: 10.1016/j.cclet.2024.110368

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(597)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return