Citation: Shi Cheng, Qianqian Xiong, Chengxiao Zhao, Xiaofei Yang. Synergism of 1D CdS/2D Modified Ti₃C₂T_x MXene Heterojunctions for Boosted Photocatalytic Hydrogen Production[J]. Chinese Journal of Structural Chemistry, ;2022, 41(8): 220805. doi: 10.14102/j.cnki.0254-5861.2022-0151 shu

Synergism of 1D CdS/2D Modified Ti₃C₂T_x MXene Heterojunctions for Boosted Photocatalytic Hydrogen Production

1.
College of Science, Nanjing Forestry University, Nanjing 210037, China

Corresponding author: Chengxiao Zhao, chengxiaozhao@njfu.edu.cn Xiaofei Yang, xiaofei.yang@njfu.edu.cn
Received Date: 9 June 2022
Accepted Date: 1 July 2022
Available Online: 5 July 2022

Figures(6)

Rational design and controllable synthesis of visible-light-responsive photocatalysts that exhibit both good hydrogen-producing efficiency and stability in the water splitting reaction are undoubtedly a challenge. Here we report an integrated CdS nanorod/oxygen-terminated Ti₃C₂T_x MXene nanosheet heterojunction with a high catalytic hydrogen evolution reaction (HER) activity. By incorporating one-dimensional (1D) CdS nanorods onto annealed ultrathin two-dimensional (2D) MXene nanosheets, the mixed-dimensional 1D/2D heterojunction achieved a hydrogen-evolving rate of 8.87 mmol⋅g^-1⋅h^-1, much higher than that of bulk CdS and CdS/unmodified MXene hybrid catalysts. The enhanced HER activity and stability of the designed heterojunction catalyst are attributed to the presence of oxygen-containing terminal groups on the surface of thermally treated Ti₃C₂T_x MXene, extended light absorption spectra as well as the precisely constructed intimate Schottky contact, implying an accelerated interfacial charge transfer and efficient, long-term photocatalytic hydrogen production performance. The results demonstrate that oxygen-terminated 2D MXene can be well utilized as a functional platform for the development of novel heterojunction photocatalysts.
- CdS,
- MXene,
- heterojunction,
- water splitting,
- hydrogen evolution reaction
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Synergism of 1D CdS/2D Modified Ti3C2Tx MXene Heterojunctions for Boosted Photocatalytic Hydrogen Production

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通讯作者: 陈斌, bchen63@163.com

Synergism of 1D CdS/2D Modified Ti₃C₂T_x MXene Heterojunctions for Boosted Photocatalytic Hydrogen Production